A comparative assessment of air pollutants of smog in wagah border and other sites in Lahore, Pakistan

Smog has become the fifth season of Pakistan especially in Lahore city. Increased level of air pollutants (primary and secondary) are thought to be responsible for the formation of smog in Lahore. Therefore, the current study was carried out for the evaluation of air pollutants (primary and secondary) of smog in Wagah border particularly and other sites (Jail road, Gulburg) Lahore. For this purpose, baseline data on winter smog from March to December on primary and secondary air pollutants and meteorological parameters was collected from Environmental Protection Department and Pakistan Meteorological Department respectively. Devices being used in both departments for analysis of parameters were also studied. Collected data was further statistically analyzed to determine the correlation of parameters with meteorological conditions and was subjected to air quality index. According to results, PM 10 and PM 2.5 were found very high above the NEQS. NOx concentrations were also high above the permissible limits whereas SO2 and O3 were found below the NEQS thus have no roles in smog formation. Air Quality Index (AQI) of pollutants was PM 2.5(86-227), PM 10 (46-332), NOx (26-110), O3 (19-84) and SO2 (10-95). AQI of PM 2.5 remained between moderate to very unhealthy levels. AQI of PM 10 remained between good to hazardous levels. AQI of NOx remained between good to unhealthy for sensitive groups’ levels. AQI of O3 and SO2 remained between good to moderate levels. Pearson correlation showed that every pollutant has a different relation with different or same parameters in different areas. It is concluded from the present study that particulate matter was much more responsible for smog formation. Although NOx also played role in smog formation. So there is need to reduce sources of particulate matter and NOx specifically in order to reduce smog formation in Lahore.

Fundamental Study on Ammonia Low-NOx Combustion Using Two-Stage Combustion by Parallel Air Jets

Ammonia, which has advantages over hydrogen in terms of storage and transportation, is increasingly expected to become a carbon-free fuel. However, the reduction of fuel NOx emitted from ammonia combustion is an unavoidable challenge. There is the report that two-stage combustion with parallel independent jets could achieve Low-NOx combustion under ammonia/methane co-firing conditions. In order to further improve NOx reduction, we experimentally evaluated the effects of secondary air nozzle parameters, such as nozzle diameter and nozzle locations, on combustion characteristics in two-stage combustion of ammonia/natural gas co-firing using parallel independent jets. As a result of the experiments under various secondary air nozzle conditions, it was found that under the conditions where NOx was significantly reduced, the peak temperature in the furnace was observed at 300–500 mm in the axial direction from the burner, and then the temperature decreased toward the downstream of the furnace. We assumed that this temperature distribution reflected the mixing conditions of the fuel and secondary air and estimated the combustion conditions in the furnace. It was confirmed that the two-stage combustion was effective in reducing NOx by forming a fuel rich region near the downstream of the burner, and the lean combustion of the unburned portion of the first stage combustion with secondary air. We confirmed that the low NOx effects could be achieved by two-stage combustion using independent jets from the same wall under appropriate combustion and air nozzle conditions.

CFD MODELING OF VORTEX AFTERBURNING OF BIOMASS GASIFICATION PRODUCTS IN A FLUIDIZED BED FURNACE

CFD modeling of the afterburning of biomass gasification products in a fluidized bed furnace with a vortex supply of secondary air has been carried out. The effect of secondary air heating on the ecological characteristics of flue gases has been determined. Modeling has shown that gasification products swirl in the primary chamber with the formation of a central vortex, which obeys the law of solid-body rotation. An increase in the temperature of the secondary air leads to an increase in its tangential velocity and, as a consequence, to an increase in centrifugal mass forces. Calculations have shown that with an increase in the secondary air temperature, the maximum of the kinetic energy of turbulence shifts to the periphery and increases in absolute value. This results in more efficient mixing of the central (producer gas) and peripheral (secondary air) streams. As a result, this leads to a more complete combustion. The influence of secondary air heating on the ecological characteristics of the furnace has been determined. As a result of air heating from 30° C to 300° C, the concentration of carbon monoxide decreases by more than 1.5 times. The concentration of nitrogen oxides practically does not change and amounts to 3.5 mg /nm3.

Measurement report: High contributions of halocarbon and aromatic compounds to atmospheric volatile organic compounds in an industrial area

Volatile organic compounds (VOCs) are key components of tropospheric chemistry. We investigated ambient VOCs in an industrial area in Nanjing, China, between July 2018 and May 2020. The sum of the suite of measured total VOC (TVOC) concentrations was 59.8 ± 28.6 ppbv (part per billion by volume) during the investigation period. About twice the TVOC concentrations were observed in the autumn (83 ± 20 ppbv) and winter (77.5 ± 16.8 ppbv) seasons compared to those in spring (39.6 ± 13.1 ppbv) and summer (38.8 ± 10.2 ppbv). In previous studies in Nanjing, oxygenated VOCs (OVOCs) and halocarbons were not measured, and the current TVOC concentration without halocarbons and OVOCs was similar to the previous investigation in the same study area. However, it was twofold higher than the one reported in the nonindustrial suburban area of Nanjing. Due to the industrial influence, the halocarbons VOC group (14.3 ± 7.3 ppbv, 24 %) was the second-largest contributor to the TVOCs after alkanes (21 ± 7 ppbv, 35 %), which is in contrast with the previous studies in Nanjing and also in almost all other regions in China. Relatively high proportions of halocarbons and aromatics were observed in autumn (25.7 % and 19.3 %, respectively) and winter (25.8 % and 17.6 %, respectively) compared to those in summer (20.4 % and 11.8 %, respectively) and spring (20.3 % and 13.6 %, respectively). According to the potential source contribution function (PSCF), short-distance transport from the surrounding industrial areas and cities was the main reason for the high VOC concentrations in the study area. According to positive matrix factorization (PMF) model results, vehicle-related emissions (33 %–48 %) contributed to the major portion of the ambient VOC concentrations. Aromatics, followed by alkenes, were the top contributors to the loss rate of OH radicals (LOH; 37 % and 32 %, respectively). According to the empirical kinetic modelling approach (EKMA) and relative incremental reactivity (RIR) analysis, the study area was in the VOC-sensitive regime for ozone (O3) formation during all measurement seasons. Therefore, alkenes and aromatics emissions from automobiles need to be decreased to reduce secondary air pollution formation in the study area.

Influence of Uneven Secondary Air Supply and Burner Tilt on Flow Pattern, Heat Transfer, and NOx Emissions in a 500 MWe Tangential-Firing Coal Boiler

Tangential-firing boilers develop large swirling fireballs by using pulverized coal and air from the corners of the burner zone. During operation, however, the boiler may experience an uneven air supply between corners; this deforms the fireball, raising various issues concerning performance and structural safety. This study investigated the characteristic boiler performance and the role of burner tilting in a 500 MWe boiler with secondary air (SA) in two corners that are up to 1.9 times larger than those in the other corners. Computational fluid dynamics simulations with advanced coal combustion sub-models were employed with the following two sets of cases: (i) six cases of actual operation to validate the modeling and (ii) sixteen cases for the parametric study of SA flow ratio and burner tilt between −15° and +26°. The results showed that the uneven SA supply deteriorated the boiler performance in various aspects and the burner tilt can be used to alleviate its impact. With a larger SA supply from the left wind box, the mass flow, heat absorption, and O2 concentration were larger in the right half of the heat exchanger sections owing to the rotating flow. The corresponding imbalance in the reaction stoichiometry increased the peak temperature entering the tube bundles by up to 60 °C and NO emissions by 6.7% as compared with normal operations. The wall heat absorption was up to 19% larger on the right and front walls. The high burner tilt of +26° helped alleviate the impact of uneven SA supply on the heat distribution and uniformity of the flow pattern and temperature, whereas a +15° burner tilt was the least favorable.

Oscillating Combustion—Primary Measure to Reduce Nitrogen Oxide in a Grate Furnace–Experiments and Simulations

The emission from industries and the mobility sector is under strong legal regulations in many countries worldwide. In Germany, the amendment to the 17th BlmSchV (Federal pollution control ordinance), which has been in force for waste incineration plants since 2013, has given rise to a new limit for nitrogen oxides of 150 mg/m3 as the daily mean level from 2019 on. A similar focus is on biomass-fired plants. According to the MCP (medium combustion plant) guideline of the EU, as a consequence, existing plants are required to either increase their consumption of ammonia water for nitrogen oxide reduction (SNCR process) or back fit SCR catalysts as secondary measures, which is a costly procedure. This paper presents a novel two-stage process in which an oscillating supply of secondary air allows nitrogen oxides to be reduced by approx. 50% at a good burnout level, which may obviate the need for secondary measures. Besides experimental investigations in a fixed bed reactor, CFD simulations confirm a high potential for reduction of nitrogen oxides. Together with the company POLZENITH, this process is under development for scale-up in a biomass incineration plant as a next step.

Thrust Vectoring of a Fixed Axisymmetric Supersonic Nozzle Using the Shock-Vector Control Method

The application of the Shock Vector Control (SVC) approach to an axysimmetric supersonic nozzle is studied numerically. SVC is a Fluidic Thrust Vectoring (FTV) strategy that is applied to fixed nozzles in order to realize jet-vectoring effects normally obtained by deflecting movable nozzles. In the SVC method, a secondary air flow injection close to the nozzle exit generates an asymmetry in the wall pressure distribution and side-loads on the nozzle, which are also lateral components of the thrust vector. SVC forcing of the axisymmetric nozzle generates fully three-dimensional flows with very complex structures that interact with the external flow. In the present work, the experimental data on a nozzle designed and tested for a supersonic cruise aircraft are used for validating the numerical tool at different flight Mach numbers and nozzle pressure ratios. Then, an optimal position for the slot is sought and the fully 3D flow at flight Mach number M∞=0.9 is investigated numerically for different values of the SVC forcing.

Gas-Solid Flow in a Fluidized-Particle Tubular Solar Receiver: Off-Sun Experimental Flow Regimes Characterization

The fluidized particle-in-tube solar receiver concept is promoted as an attractive solution for heating particles at high temperature in the context of the next generation of solar power tower. Similar to most existing central solar receivers, the irradiated part of the system, the absorber, is composed of tubes in which circulate the fluidized particles. In this concept, the bottom tip of the tubes is immersed in a fluidized bed generated in a vessel named the dispenser. A secondary air injection, called aeration, is added at the bottom of the tube to stabilize the flow. Contrary to risers, the particle mass flow rate is controlled by a combination of the overpressure in the dispenser and the aeration air velocity in the tube. This is an originality of the system that justifies a specific study of the fluidization regimes in a wide range of operating parameters. Moreover, due to the high value of the aspect ratio, the particle flow structure varies along the tube. Experiments were conducted with Geldart Group A particles at ambient temperature with a 0.045 m internal diameter and 3 m long tube. Various temporal pressure signal processing methods, applied in the case of classical risers, are applied. Over a short acquisition time, a cross-reference of the results is necessary to identify and characterize the fluidization regimes. Bubbling, slugging, turbulent and fast fluidization regimes are encountered and the two operation modes, without and with particle circulation, are compared.