Vibrationally excited molecular hydrogen production from the water photochemistry

Vibrationally excited molecular hydrogen has been commonly observed in the dense photo-dominated regions (PDRs). It plays an important role in understanding the chemical evolution in the interstellar medium. Until recently, it was widely accepted that vibrational excitation of interstellar H2 was achieved by shock wave or far-ultraviolet fluorescence pumping. Here we show a further pathway to produce vibrationally excited H2 via the water photochemistry. The results indicate that the H2 fragments identified in the O(1S) + H2(X1Σg+) channel following vacuum ultraviolet (VUV) photodissociation of H2O in the wavelength range of λ = ~100-112 nm are vibrationally excited. In particular, more than 90% of H2(X) fragments populate in a vibrational state v = 3 at λ~112.81 nm. The abundance of water and VUV photons in the interstellar space suggests that the contributions of these vibrationally excited H2 from the water photochemistry could be significant and should be recognized in appropriate interstellar chemistry models.

Pickup and reactions of molecules on clusters relevant for atmospheric and interstellar processes

In this perspective, we review experiments with molecules picked up on clusters in molecular beams with the focus on the processes in atmospheric and interstellar chemistry.

Iron assisted formation of CO2 over condensed CO and its relevance to interstellar chemistry

Catalytic conversion of CO to CO2 assisted by neutral iron atoms has been investigated in ultrahigh vacuum (UHV) under cryogenic conditions (10 K).