Development and optimization of fire-protective coating composition based on epoxypolymers

The object of research is intumescent fire retardant coatings based on epoxy resins. The research is aimed at the development of mathematical models of the dependence of the swelling rate of intumescent fire retardant coatings on their composition. Considering the complexity of the processes during the formation of a protective carbon layer, it is advisable to select the optimal ratio of the components of an intumescent fire retardant coating experimentally, followed by the construction of mathematical dependences of the swelling ratio on the coating composition. Therefore, experimental studies aimed at developing and optimizing the composition of an intumescent fire retardant coating based on epoxy polymers are an important task. The studies were carried out in accordance with the theory of planning experiments with the construction of an orthogonal compositional plan of the second order. A linear swelling factor was chosen as the response function. Compositions based on the ED-20 epoxy oligomer, cured with polyethylene polyamine and filled with ammonium polyphosphate, aluminum hydroxide, and graphite additive were used for the study. Based on the results of processing the experimental results, a regression equation was obtained and response surfaces were constructed that describe the dependence of the linear swelling coefficient Cs of an intumescent composition based on an epoxy oligomer on the content of ammonium polyphosphate, aluminum hydroxide and graphite additive. A complex relationship is shown between the content of components and the linear swelling coefficient Cs with different ratios of the components. The optimum by the linear swelling coefficient (Cs=68.1) content of the components in the epoxy polymer was determined, amounting to 20 wt. including for ammonium polyphosphate, 15 mass parts including for aluminum hydroxide and 3 mass parts for the graphite additive. However, with such a ratio, the «self-extinguishing» condition is not met (Cs=27 %). Filling the composition with ammonium polyphosphate in an amount of 26.3 mass parts including, aluminum hydroxide 25 mass parts and 3.5 mass parts including graphite additives allows to get an intumescent fire retardant coating with a swelling ratio Cs over 63 and a reduced level of flammability (Ci=31 %)

INVESTIGATION OF THE METHOD OF INTRODUCING SURFACTANTS INTO THE COMPOSITION OF WATER NON-STICK COATINGS

It is shown that the joint activation of graphite and carboxymethyl cellulose provides non-stick coatings with a higher level of properties than when this additive is introduced into the coating composition. The content of carboxymethyl cellulose should not exceed 1 wt. % by weight of graphite.

Electrical Properties of Half Heusler Coatings Depending on Spray Process

Microstructure and physicochemical properties of a thermally sprayed coating depend on the dynamics of the particles interacting with the spray jet. This is especially the case for electrical properties. In this study, different spraying processes were used to spray p-type and n-type half-Heusler powders. Thermoelectric powders, Hf20Zr75Ti05CoSb80Sn20 (p-type) and Hf60Zr40NiSn98Sb02 (n-type), were selected due to their interesting electrical properties. The spray processes were evaluated based on coating composition and mechanical property measurements. The only coatings of practical interest were those that were plasma sprayed and they were examined in detail to assess the effect of process parameters on coating properties.

PASSIVE UHF RFID TAGS WITH THERMAL-TRANSFER-PRINTED ANTENNAS

Papers for the thermal transfer printing of UHF RFID antennas were prepared by coating and calendering. Real and imaginary components of the impedance of the UHF RFID antennas depended on their design, coating composition and conditions of paper calendering. Passive UHF RFID tags were constructed from antennas and chips whose real and imaginary components of impedance in the 860–960 MHz frequency band were at approximately the same level. The communication quality of passive UHF RFID tags was evaluated by measuring the reading range using the designed UHF RFID reading unit. The reading range of experimental UHF RFID tags with printed antennas on paper and commercial UHF RFID tags with chemically etched antennas on a PET film were identical in the 860 MHz frequency.