Optical Properties of InGaN/GaN QW with the Same Well-Plus-Barrier Thickness

Optical properties of wurtzite violet InGaN/GaN quantum well (QW) structures, with the same well-plus-barrier thickness, grown by metal-organic chemical vapor deposition (MOCVD) on c-plane sapphire substrates, were investigated using temperature-dependent photoluminescence (TDPL) and excitation-power-dependent photoluminescence (PDPL). Two samples were compared: one had a thicker well (InGaN/GaN 3/5 nm); the other had a thicker barrier (InGaN/GaN 2/6 nm). It was found that the GaN barrier thickness in the InGaN/GaN MQWs plays an important role in determining the optical characteristics of the MQWs. The peak energy of the two samples varied with temperature in an S-shape. The thicker-barrier sample had a higher turning point from blueshift to redshift, indicating a stronger localization effect. From the Arrhenius plot of the normalized integrated PL intensity, it was found that the activation energy of the nonradiative process also increased with a thicker barrier thickness. The radiation recombination process was dominated in the sample of the thicker barrier, while the non-radiation process cannot be negligible in the sample of the thicker well.

Laser-Induced Interdigital Structured Graphene Electrodes Based Flexible Micro-Supercapacitor for Efficient Peak Energy Storage

The rapidly developing demand for lightweight portable electronics has accelerated advanced research on self-powered microsystems (SPMs) for peak power energy storage (ESs). In recent years, there has been, in this regard, a huge research interest in micro-supercapacitors for microelectronics application over micro-batteries due to their advantages of fast charge–discharge rate, high power density and long cycle-life. In this work, the optimization and fabrication of micro-supercapacitors (MSCs) by means of laser-induced interdigital structured graphene electrodes (LIG) has been reported. The flexible and scalable MSCs are fabricated by CO2-laser structuring of polyimide-based Kapton ® HN foils at ambient temperature yielding interdigital LIG-electrodes and using polymer gel electrolyte (PGE) produced by polypropylene carbonate (PPC) embedded ionic liquid of 1-ethyl-3-methyl-imidazolium-trifluoromethansulphonate [EMIM][OTf]. This MSC exhibits a wide stable potential window up to 2.0 V, offering an areal capacitance of 1.75 mF/cm2 at a scan rate of 5.0 mV/s resulting in an energy density (Ea) of 0.256 µWh/cm2 @ 0.03 mA/cm2 and power density (Pa) of 0.11 mW/cm2 @0.1 mA/cm2. Overall electrochemical performance of this LIG/PGE-MSC is rounded with a good cyclic stability up to 10,000 cycles demonstrating its potential in terms of peak energy storage ability compared to the current thin film micro-supercapacitors.

Локализация носителей заряда в квантовых ямах InGaN/GaN, ограниченная объемным зарядом

The mechanism of carrier tunneling through the potential walls of InGaN/GaN quantum well in the p-n structures is studied by means of the deep center tunneling spectroscopy. A number of humps on the current and photocurrent tunneling spectra, as well as on the forward bias dependences of the intensity and the peak energy of photoluminescence band from the quantum well are detected. These findings allow us to propose a model of carrier localization in the quantum well that permit to relate the tunneling transparency of the potential walls of the QW to the space-charge of deep-level centers in the quantum well barriers and its changes under optical excitation and forward biasing of p-n structure.

Membranes for the Capture and Screening of Waterborne Plutonium Based on a Novel Pu-Extractive Copolymer Additive

This contribution describes the fabrication of plutonium-adsorptive membranes by non-solvent induced phase separation. The dope solution comprised poly(vinylidene fluoride) (PVDF) and a Pu-extractive copolymer additive of PVDF-g-poly(ethylene glycol methacrylate phosphate) (EGMP) in dimethylformamide (DMF). The effects of casting conditions on membrane permeability were determined for PVDF membranes prepared with 10 wt% PVDF-g-EGMP. Direct-flow filtration and alpha spectrometry showed that membranes containing the graft copolymer could recover Pu up to 59.9 ± 3.0% from deionized water and 19.3 ± 3.5% from synthetic seawater after filtering 10 mL of 0.5 Bq/mL 238Pu. SEM-EDS analysis indicated that the graft copolymer was distributed evenly throughout the entire depth of the copolymer membranes, likely attributing to the tailing observed in the alpha spectra for 238Pu. Despite the reduction in resolution, the membranes exhibited high Pu uptake at the conditions tested, and new membrane designs that promote copolymer surface migration are expected to improve alpha spectrometry peak energy resolutions. Findings from this study also can be used to guide the development of extractive membranes for chromatographic separation of actinides from contaminated groundwater sources.

Optimising peak energy reduction in networks of buildings

Buildings are amongst the world's largest energy consumers and simultaneous peaks in demand from networks of buildings can decrease electricity system stability. Current mitigation measures either entail wasteful supply-side over-specification or complex centralised demand-side control. Here, we investigate a new schema for decentralised, self-organising building-to-building load coordination that requires very little information and no direct intervention. We find that the theoretically optimal size for load-coordination networks can be surprisingly small, analogous to other complex systems such as coordination between flocks of birds. The schema outperforms existing techniques, giving substantial peak-reductions as well as being remarkably robust to changes in other system parameters such as the network topology. This not only demonstrates that significant reductions in network peaks are achievable using remarkably simple control systems but also reveals theoretical results and new insights which which will be of great interest to the complexity and network science communities.

Enhanced Properties of Extended Wavelength InGaAs on Compositionally Undulating Step-Graded InAsP Buffers Grown by Molecular Beam Epitaxy

The extended wavelength InGaAs material (2.3 μm) was prepared by introducing compositionally undulating step-graded InAsyP1−y buffers with unequal layer thickness grown by solid-source molecular beam epitaxy (MBE). The properties of the extended wavelength InGaAs layer were investigated. The surface showed ordered crosshatch morphology and a low roughness of 1.38 nm. Full relaxation, steep interface and less than one threading dislocation in the InGaAs layer were demonstrated by taking advantage of the strain compensation mechanism. Room temperature photoluminescence (PL) exhibited remarkable intensity attributed to the lower density of deep non-radiative centers. The emission peak energy with varied temperatures was in good agreement with Varshni’s empirical equation, implying high crystal quality without inhomogeneity-induced localized states. Therefore, our work shows that compositionally undulating step-graded InAsP buffers with a thinner bottom modulation layer, grown by molecular beam epitaxy, is an effective approach to prepare InGaAs materials with wavelengths longer than 2.0 μm and to break the lattice limitation on the materials with even larger mismatch.

I-mode pedestal relaxation events in the Alcator C-Mod and ASDEX Upgrade tokamaks

In some conditions, I-mode plasmas can feature pedestal relaxation events (PREs) that transiently enhance the energy reaching the divertor target plates. To shed light on their appearance, characteristics and energy reaching the divertor targets, a comparative study between two tokamaks – Alcator C-Mod and ASDEX Upgrade – is carried out. It is found that PREs appear only in a subset of I-mode discharges, mainly when the plasma is close to the H-mode transition. Also, a growing oscillating precursor before the PRE onset is observed in the region close to the separatrix in both devices, and a discussion on a possible triggering mechanism is outlined. The PRE relative energy loss from the confined region is found to increase with decreasing pedestal top collisionality ν* ped. Similarly, also the relative electron temperature drop at the pedestal top, which is related to the conductive energy loss, rises with decreasing ν* ped. Based on these relations, the PRE relative energy loss in future devices such as DEMO and ARC is estimated. Finally, the divertor peak energy fluence due to the PRE is measured on each device. Those values are then compared to the model introduced in [1] for type-I ELMs. The model is shown to provide an upper boundary for PRE energy fluence data, while a lower boundary is found by dividing the model by three. These two boundaries are used to make projections of the PRE divertor energy fluence to DEMO and ARC.

EV Charging in Case of Limited Power Resource

In the case of the widespread adoption of electric vehicles (EV), it is well known that their use and charging could affect the network distribution system, with possible repercussions including line overload and transformer saturation. In consequence, during periods of peak energy demand, the number of EVs that can be simultaneously charged, or their individual power consumption, should be controlled, particularly if the production of energy relies solely on renewable sources. This requires the adoption of adaptive and/or intelligent charging strategies. This paper focuses on public charging stations and proposes methods of attribution of charging priority based on the level of charge required and premiums. The proposed solution is based on model predictive control (MPC), which maintains total current/power within limits (which can change with time) and imparts real-time priority charge scheduling of multiple charging bays. The priority is defined in the diagonal entry of the quadratic form matrix of the cost function. In all simulations, the order of EV charging operation matched the attributed priorities for the cases of ten cars within the available power. If two or more EVs possess similar or equal diagonal entry values, then the car with the smallest battery capacitance starts to charge its battery first. The method is also shown to readily allow participation in Demand Side Response (DSR) schemes by reducing the current temporarily during the charging operation.

GRB 210121A: A Typical Fireball Burst Detected by Two Small Missions

The Chinese CubeSat Mission, Gamma Ray Integrated Detectors (GRID), recently detected its first gamma-ray burst, GRB 210121A, which was jointly observed by the Gravitational wave high-energy Electromagnetic Counterpart All-sky Monitor (GECAM). This burst is confirmed by several other missions, including Fermi and Insight-HXMT. We combined multimission observational data and performed a comprehensive analysis of the burst’s temporal and spectral properties. Our results show that the burst is relatively special in its high peak energy, thermal-like low-energy indices, and large fluence. By putting it to the E p –E γ,iso relation diagram with assumed distance, we found that this burst can be constrained at the redshift range of [0.3, 3.0]. The thermal spectral component is also confirmed by the direct fit of the physical models to the observed spectra. Interestingly, the physical photosphere model also constrained a redshift of z ∼ 0.3 for this burst, which helps us to identify a host galaxy candidate at such a distance within the location error box. Assuming that the host galaxy is real, we found that the burst can be best explained by the photosphere emission of a typical fireball with an initial radius of r 0 ∼ 3.2 × 107 cm.

Decentralised peak energy demand minimisation in networks of buildings

Simultaneous peaks in the energy demand from networks of buildings can decrease system stability and increase operational costs. However, reducing these peaks can require complicated centralised control schemes. Here, taking inspiration from biological systems, we investigate a decentralised, building-to-building load coordination schema that requires very little information and no human intervention. Using agent-based modelling, we investigate both the optimal system size and robustness of the results to changes in the system parameters. It is found that substantial reductions are readily achieved through coordination between a small number of buildings, analogous to models of coordination between flocks of birds. Strikingly, the schema significantly outperforms existing techniques and is robust to varying network topology and the inclusion of large time-constrained thermal loads. These results imply that significant reductions in network peaks are achievable through simple low-cost controllers implemented at the building level; particularly important for developing countries with fragile networks.