Analysis of technological conditions for the formation and burnout of carcinogenic pahs in boiler flue gases

THE PURPOSE. The necessity of establishing emission standards for highly toxic substances with carcinogenic properties in the context of the implementation of new principles of state regulation of environmental protection activities at energy enterprises is substantiated and confirmed. The analysis of the features of the formation and burnout of carcinogenic polycyclic aromatic hydrocarbons in the flue gases of boilers during the combustion of coals in lowtemperature conditions of the furnace process is carried out. Based on the analysis, the total and partial indicators of the harmfulness of flue gases were calculated in order to assess and predict the overall toxicity of coal combustion products, taking into account the contribution of carcinogenic substances.METHODS. When calculating the overall toxicity of flue gases, a systematic analysis and generalization of experimental data on the content of carcinogenic and non-carcinogenic polycyclic aromatic hydrocarbons in the combustion products of low-power boilers was applied.RESULTS. As a result of the performed study, the contribution of carcinogenic and non-carcinogenic polycyclic hydrocarbons to the overall toxicity of boiler flue gases during the combustion of Azeysky, Mugunsky, Cheremkhovsky and Tugnuy coal was determined. It is shown that substances such as benz(a)pyrene, fluoranthene, pyrene and phenanthrene significantly affect the level of the total indicator of the harmfulness of combustion products from 38.8 to 53.6%.CONCLUSION. The obtained research results can be applied at energy enterprises at the stage of substantiating the introduction of regime-technological and environmental measures in order to develop measures to improve environmental efficiency through technological rationing of carcinogenic emissions.

The Influence of Industrial Waste on the Magnetic Properties of Salt-Affected Soils from Two Soda Ash Manufacturing Sites

The aim of this study was to characterize the impact of soda ash manufacturing on the magnetic properties of soils located in the agricultural landscape in north-central Poland. Two study sites were chosen: Mątwy (SM) and Janikowo (SJ). Highly saline soils with halophyte communities were selected in order to develop an understanding of the relationship between salinization of water–soil interface and the potential contamination risk of the environment. Basic chemical and physicochemical properties of topsoil (0–25 cm) and water (surface and groundwater) samples from five locations were characterized. The characteristics of soil contamination were based on the content of selected metals, magnetic properties and salinity indices. Potential routes of contaminant migration (air and water fluxes) were analyzed. High magnetic anomalies of technogenic origin were revealed in the studied soils. A statistically confirmed relationship between high magnetic susceptibility and the content of selected metals (Co, Ni, Cu, Zn, Ba, Pb and Mn) showed the high utility of magnetometric techniques in soil research (diagnosis of soil transformation and contamination during technogenic impact). Three potential factors influencing contaminant migration were revealed: highly saline ground and surface water, eolian transport of fine-grained mineral fractions from waste ponds and atmospheric deposition of coal combustion products.

Shotcrete using ternary binder made from coal combustion products: from lab tests to an application

The paper presents a ternary binder development and its utilization in shotcrete. The binder is made from fluidized bed combustion (FBC) fly ash, siliceous fly ash, and Ca(OH)2 addition, now available under the name Sorfix. XRD and TGA identified ettringite and C-S-H as two main hydration products. In addition, thermodynamic modeling verified robustness in terms of space-filling capabilities when varying input oxide composition. Since alkali-free accelerators produce mostly ettringite in Portland-based systems, a fraction of Portland cement was advantageously replaced with the ternary binder, forming early ettringite as well. Extensive testing led to 45% replacement of Portland cement, following J2 curve for early strength gain used commonly in shotcrete tunnel linings. The shotcrete was successfully tested in a mock-up experiment in a 2 m3 Prague served for the full-scale application, utilizing over 1000 tons of Sorfix and saving over 700 tons of CO2

Research Summary on the Processing, Mechanical and Tribological Properties of Aluminium Matrix Composites as Effected by Fly Ash Reinforcement

Fly ash is the main waste as a result of combustion in coal fired power plants. It represents about 40% of the wastes of coal combustion products (fly ash, boiler ash, flue gas desulphurization gypsum and bottom ash). Currently, coal waste is not fully utilized and waste disposal remains a serious concern despite tremendous global efforts in reducing fossil fuel dependency and shifting to sustainable energy sources. Owing to that, employment of fly ash as reinforcement particles in metallic matrix composites are gaining momentum as part of recycling effort and also as a means to improve the specifications of the materials that are added to it to form composite materials. Many studies have been done on fly ash to study composite materials wear characteristics including the effects of fly ash content, applied load, and sliding velocity. Here, particular attention is given to studies carried out on the influence FA content on physical, mechanical, and the thermal behavior of Aluminium-FA composites. Considerable changes in these properties are seen by fly ash refinement with limited size and weight fraction. The advantage of fly ash addition results in low density of composites materials, improvement of strength, and hardness. It further reduces the thermal expansion coefficient and improve wear resistance.

Preparation of Synthetic Zeolites from Coal Fly Ash by Hydrothermal Synthesis

Large amounts of coal combustion products (as solid products of thermal power plants) with different chemical and physical properties cause serious environmental problems. Even though coal fly ash is a coal combustion product, it has a wide range of applications (e.g., in construction, metallurgy, chemical production, reclamation etc.). One of its potential uses is in zeolitization to obtain a higher added value of the product. The aim of this paper is to produce a material with sufficient textural properties used, for example, for environmental purposes (an adsorbent) and/or storage material. In practice, the coal fly ash (No. 1 and No. 2) from Czech power plants was firstly characterized in detail (X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDX), particle size measurement, and textural analysis), and then it was hydrothermally treated to synthetize zeolites. Different concentrations of NaOH, LiCl, Al2O3, and aqueous glass; different temperature effects (90–120 °C); and different process lengths (6–48 h) were studied. Furthermore, most of the experiments were supplemented with a crystallization phase that was run for 16 h at 50 °C. After qualitative product analysis (SEM-EDX, XRD, and textural analytics), quantitative XRD evaluation with an internal standard was used for zeolitization process evaluation. Sodalite (SOD), phillipsite (PHI), chabazite (CHA), faujasite-Na (FAU-Na), and faujasite-Ca (FAU-Ca) were obtained as the zeolite phases. The content of these zeolite phases ranged from 2.09 to 43.79%. The best conditions for the zeolite phase formation were as follows: 4 M NaOH, 4 mL 10% LiCl, liquid/solid ratio of 30:1, silica/alumina ratio change from 2:1 to 1:1, temperature of 120 °C, process time of 24 h, and a crystallization phase for 16 h at 50 °C.