Ultrasonic Atomization: New Spray Characterization Approaches

In particle engineering, spray drying is an essential technique that depends on producing sprays, ideally made of equal-sized droplets. Ultrasonic sprays appear to be the best option to achieve it, and Faraday waves are the background mechanism of ultrasonic atomization. The characterization of sprays in this atomization strategy is commonly related to the relation between characteristic drop sizes and the capillary length produced by the forcing frequency of wavy patterns on thin liquid films. However, although this atomization approach is practical when the intended outcome is to produce sprays with droplets of the same size, drop sizes are diverse in real applications. Therefore, adequate characterization of drop size is paramount to establishing the relations between empirical approaches proposed in the literature and the outcome of ultrasonic atomization in actual operating conditions. In this sense, this work explores new approaches to spray characterization applied to ultrasonic sprays produced with different solvents. The first two introduced are the role of redundancy in drop size measurements to avoid resolution limitation in the measurement technique and compare using regular versus variable bin widths when building the histograms of drop size. Another spray characterization tool is the Drop Size Diversity to understand the limitations of characterizing ultrasonic sprays solely based on representative diameters or moments of drop size distributions. The results of ultrasonic spray characterization obtained emphasize: the lack of universality in the relation between a characteristic diameter and the capillary length associated with Faraday waves; the variability on drop size induced by both liquid properties and flow rate on the atomization outcome, namely, lower capillary lengths produce smaller droplets but less efficiently; the higher sensibility of the polydispersion and heterogeneity degrees in Drop Size Diversity when using variable bin widths to build the histograms of drop size; the higher drop size diversity for lower flow rates expressed by the presence of multiple clusters of droplets with similar characteristics leading to multimodal drop size distributions; and the gamma and log-normal mathematical probability functions are the ones that best describe the organization of drop size data in ultrasonic sprays.

Secondary Faraday waves in microgravity

Recent microgravity experiments have demonstrated that Faraday waves can arise in a secondary instability over the primary columnar patterns that develop after the frozen wave instability. While some numerical studies have investigated this phenomenon, theoretical analyses are only found in the works of Shevtsova et al. (2016) [1] and Lyubimova et al. (2019) [2]. Here, we extend these efforts by analysing the stability of a three-layer system, and derive the critical onset of Faraday waves, which appear via Hopf bifurcation. Numerical simulations — based on a model that reproduces the frozen wave mode with lowest wavenumber — are carried out to test this result and to analyse the character of the bifurcation. The predicted Hopf bifurcation is confirmed, which constitutes the first observation of modulated secondary Faraday waves. The abrupt growth of these modulated waves above onset indicates that the primary bifurcation is subcritical and is accompanied by a saddle-node bifurcation of periodic orbits that stabilises the (branch of) unstable solutions created in the subcritical Hopf bifurcation. Further above onset, these modulated waves are destroyed via a saddle-node heteroclinic bifurcation. Results for an N-layer configuration, which represents a more general frozen wave pattern, are also presented and compared with the three-layer case.

Energy spectra of Sub-Surface Velocity Fields Beneath Faraday Waves

Faraday waves form on the surface of a fluid which is subject to vertical forcing, and are researched in a large range of applications. Some examples are the formation of ordered wave patterns and the controlled walking or orbiting of droplets (Couder et al. (2005); Saylor and Kinard (2005)). Moreover, recent studies discovered the existence of a horizontal velocity field at the fluid surface, called Faraday flow, which was shown to exhibit an inverse energy cascade and thus properties of two-dimensional turbulence (von Kameke et al., 2011, 2013; Francois et al., 2013). Additionally, three-dimensionality effects have been part of recent investigations in quasi-2D flows (both electromagnetically-driven (Kelley and Ouellette, 2011; Martell et al., 2019) or produced by parametrically-excited waves (Francois et al., 2014; Xia and Francois, 2017)). Furthermore, the occurrence of an inverse cascade in thick layers is also subject of current studies on the coexistence of 2D and 3D turbulence (Biferale et al., 2012; Kokot et al., 2017; Biferale et al., 2017). By performing 2D PIV measurements at horizontal planes beneath the Faraday waves, we recently showed that pronounced three dimensional flows occur in the bulk, with much larger spatial and temporal scales than those on the surface (Colombi et al., 2021), when the system is not shallow in comparison to typical length scales of the surface flow (fluid thickness exceeding half the Faraday wavelength λF). This in turn reveals that an inverse energy cascade and aspects of a confined 2D turbulence can coexist with a three dimensional bulk flow. In this work, 2D PIV measurements of the velocity fields are carried out at a vertical cross-section xz-plane and at four distinct horizontal xy-planes at different depths in Faraday waves. The results reveal that small and fast vertical jets penetrate from the surface into the bulk with fast accelerating bursts and strong momentum transport in the z−direction. Furthermore, the fraction of flow kinetic energy in the vertical direction is found to peak inside a layer of approximately 10 mm (one Faraday wavelength) below the fluid surface.

Moulding hydrodynamic 2D-crystals upon parametric Faraday waves in shear-functionalized water surfaces

Faraday waves, or surface waves oscillating at half of the natural frequency when a liquid is vertically vibrated, are archetypes of ordering transitions on liquid surfaces. Although unbounded Faraday waves patterns sustained upon bulk frictional stresses have been reported in highly viscous fluids, the role of surface rigidity has not been investigated so far. Here, we demonstrate that dynamically frozen Faraday waves—that we call 2D-hydrodynamic crystals—do appear as ordered patterns of nonlinear gravity-capillary modes in water surfaces functionalized with soluble (bio)surfactants endowing in-plane shear stiffness. The phase coherence in conjunction with the increased surface rigidity bears the Faraday waves ordering transition, upon which the hydrodynamic crystals were reversibly molded under parametric control of their degree of order, unit cell size and symmetry. The hydrodynamic crystals here discovered could be exploited in touchless strategies of soft matter and biological scaffolding ameliorated under external control of Faraday waves coherence.

Three dimensional flows beneath a thin layer of 2D turbulence induced by Faraday waves

Faraday waves occur on a fluid being subject to vertical shaking. Although it is well known that form and shape of the wave pattern depend on driving amplitude and frequency, only recent studies discovered the existence of a horizontal velocity field at the surface, called Faraday flow. This flow exhibits attributes of two-dimensional turbulence and is replicated in this study. Despite the increasing attention towards the inverse energy flux in the Faraday flow and other not strictly two-dimensional (2D) systems, little is known about the velocity fields developing beneath the fluid surface. In this study, planar velocity fields are measured by means of particle image velocimetry with high spatio-temporal resolution on the water surface and at different depths below it. A sudden drop in velocity and turbulent kinetic energy is observed at half a Faraday wavelength below the surface revealing that the surface flow is the main source of turbulent fluid motion. The flow structures below the surface comprise much larger spatial scales than those on the surface leading to very long-tailed temporal and spatial velocity (auto-) correlation functions. The three-dimensionality of the flow is estimated by the compressibility, which increases strongly with depth while the divergence changes its appearance from intermittent and single events to a large scale pattern resembling 2D cut-planes of convection rolls. Our findings demonstrate that the overall fluid flow beneath the surface is highly three-dimensional and that an inverse cascade and aspects of a confined 2D turbulence can coexist with a three-dimensional flow. Graphic abstract