Analysis of the NOx storage behaviour during cold start of modern SCR flow-through substrates and SCR on-filter substrates

Selective catalytic reduction (SCR) systems are the state-of-the-art technology to reduce nitrogen oxide emissions (NOx) of modern diesel engines. The system behaviour is well understood in the common temperature working area. However, the system properties below light-off temperature are less well known and offer a wide scope for further investigations. Vehicle measurements show that under specific conditions during cold start, NOx can be partially stored and converted on on-filter and flow-through SCR catalysts. The purpose of this work was in a first step to analyse the main influence parameters on the NOx storage behaviour. Therefore, synthetic gas test bench measurements have been carried out, varying the gas concentrations, temperature, and gas hourly space velocity (GHSV). These investigations showed that the NOx storage effect strongly depends on the NH3 level stored in the catalyst, GHSV, the adsorbed water (H2O) on the catalyst, and the temperature of the catalyst. Further influence parameters such as the gas composition with focus on carbon monoxide (CO), short-chain hydrocarbons and long-chain hydrocarbons have been analysed on a synthetic gas test bench. Depending on operating conditions, a significant amount of NOx can be stored on a dry catalyst during the cold start phase. The water vapor from the combustion condenses on the cold exhaust pipe during the first seconds, or up to a few minutes after a cold start. As the water vapor reaches the surface of the catalyst, it condenses and adsorbs onto it, leading to a sudden temperature rise. This exothermal reaction causes the stored NOx to be desorbed, and furthermore it is partially reduced by the NH3 stored in the catalyst.

Syngas Fermentation for the Production of Bio-Based Polymers: A Review

Increasing environmental awareness among the general public and legislators has driven this modern era to seek alternatives to fossil-derived products such as fuel and plastics. Addressing environmental issues through bio-based products driven from microbial fermentation of synthetic gas (syngas) could be a future endeavor, as this could result in both fuel and plastic in the form of bioethanol and polyhydroxyalkanoates (PHA). Abundant availability in the form of cellulosic, lignocellulosic, and other organic and inorganic wastes presents syngas catalysis as an interesting topic for commercialization. Fascination with syngas fermentation is trending, as it addresses the limitations of conventional technologies like direct biochemical conversion and Fischer–Tropsch’s method for the utilization of lignocellulosic biomass. A plethora of microbial strains is available for syngas fermentation and PHA production, which could be exploited either in an axenic form or in a mixed culture. These microbes constitute diverse biochemical pathways supported by the activity of hydrogenase and carbon monoxide dehydrogenase (CODH), thus resulting in product diversity. There are always possibilities of enzymatic regulation and/or gene tailoring to enhance the process’s effectiveness. PHA productivity drags the techno-economical perspective of syngas fermentation, and this is further influenced by syngas impurities, gas–liquid mass transfer (GLMT), substrate or product inhibition, downstream processing, etc. Product variation and valorization could improve the economical perspective and positively impact commercial sustainability. Moreover, choices of single-stage or multi-stage fermentation processes upon product specification followed by microbial selection could be perceptively optimized.

Steam gasification of municipal solid waste for hydrogen production using Aspen Plus® simulation

Approximately 50 million ton of municipal waste is generated in Pakistan per annum and most of this waste does not reach final deposit sites. In this research, Silvia gas technology for municipal solid waste (MSW) steam gasification is studied to produce high energy density product gas. A detailed simulation model is developed with the help of Aspen Plus®. Catalyst coal bottom ash along with lime (CaO) as sorbent is employed for tar reduction and improving the hydrogen (H2) yield in the product gas. The effect of gasification operating temperature and the ratio of steam to feedstock on synthetic gas composition, hydrogen (H2) yield and heating values of synthesis gas was studied. Coal bottom ash along with CaO had a substantial effect on hydrogen (H2) yield and synthesis gas production. Rise in steam–MSW ratio increased the hydrogen (H2) from 58 to 74.9% (vol.). The maximum value of hydrogen (H2) production, i.e., 74.9% by vol. was achieved at a steam–feedstock ratio of 1.9. A maximum of 79.8% by vol. hydrogen (H2) was attained at 680 °C gasification operating temperature with 1.3 ratio of steam to feedstock and coal bottom ash 0.07% by wt. High value of 13.1 MJ/Nm3 of hydrogen-rich synthetic gas was achieved at 680 °C. The acquired results lay the foundation for the economic feasibility study and pilot plant for MSW usage for hydrogen production.

Syngas Characteristics from UCG Gasification Process with Lignite and Subbituminous Coal Types

Underground Coal Gasification (UCG) is the process of converting the materials used to make synthetic gas in a feasible and economically attractive manner as a method for harnessing energy from underground coal sources. Coal gasification will produce a gas producer in the form of synthetic gas (syngas) with the main components consisting of carbon monoxide (CO), hydrogen (H2), carbon dioxide (CO2) and nitrogen (N2) and low pollutants. The highest temperature produced with MT 47 lignite coal using an oxygen velocity of 5 liters/minute was 2400 C at the 35th minute, while the lowest temperature was 950 C at the 95th minute. For Subbituminous AL 51 coal using an oxygen velocity of 5 liters/minute, the highest temperature is 3540 C at 75 minutes, while the lowest temperature is 1060 C at 130 minutes. At an oxygen velocity of 5 liters/minute the flash point / burn test is on the MT 47 lignite coal type in the 10th minute and at a temperature of 1700 C. Meanwhile, the AL 51 subbituminous coal type is in the 30th minute and at a temperature of 3130 C. Based on the discussion and analysis of data from the gasification test of lignite and subbituminous coal with variations in oxygen velocity of 5 liters/minute, the results obtained are that lignite coal burns faster (burn test) in the 10th minute at a temperature of 1700 C, in the subbituminous type it has higher temperature 3130 C and longer burn test at 30 minutes.

Synthetic gas networks for the statistical assessment of low-carbon distribution systems

Most of the simulation studies on energy networks, including gas grids, derive their results from a limited number of network models. The findings of these works are therefore affected by a substantial case-specificity, which partially limits their validity and prevents their generalisation. To overcome this limitation, the present work proposes a novel statistical-based approach for studying distribution gas networks, enabled by a generator of random gas grids with accurate technical designs and structural features. Ten-thousand random and unique networks are produced in three different tests, where increasingly tight constraints are applied to the synthetisation process for a higher control over the generated grids. The experiments verify the accuracy of the tool and highlight that substantial variations can be found in the hydraulic behaviour (pressures and gas velocities) and structural properties (pipe diameters and network volumes) of real-world gas networks. The observed 10,000 gas grids evidence the information gain offered by statistical-based approaches with respect to traditional case-specific studies. The tool opens a broad range of applications which include, but are not limited to, statistical analyses on the distributed injection of alternative gases, like hydrogen, in integrated, low-carbon, energy systems.

Swirler geometry effects (dh/do ratio) on synthetic gas flames: Part 1: Combustion and emission characteristics

Swirling flows increase combustion performance via favouring flame stability, pollutant emissions, and combustion intensity. The strength of a swirling flow is characterized by a parameter known as swirl number, which is highly related to the dh/do ratio. In this study, effects of the swirler dh/do ratio on combustion and emission characteristics of the synthetic gas flames of premixed 20%CNG/30%H2/30%CO/20%CO2 mixture were experimentally investigated in a laboratory-scale swirl stabilized combustor. For this purpose, twelve different swirl generators were designed and manufactured. dh/do ratios of these swirlers were set as 0.30 and 0.50, and the geometric swirl number was varied between the values of 0.4 and 1.4 (at 0.2 intervals). All experiments were conducted at a fuel-lean equivalence ratio (ϕ = 0.6), room temperature, and local atmospheric conditions of the city of Kayseri, Turkey. A data logger was utilized to plot axial and radial temperatures and NOx, CO, and CO2 profiles, which were exploited to assess combustion and emission performance. Results showed that the dh/do ratio had a non-monotonic effect on the behaviour of combustion and emission of the tested synthetic gas mixture. Depending on the swirl number, increments and decrements were observed in temperature and emission values.