energetic characterization
Recently Published Documents


TOTAL DOCUMENTS

78
(FIVE YEARS 18)

H-INDEX

17
(FIVE YEARS 3)

2022 ◽  
Vol 52 (2) ◽  
Author(s):  
Luiz Augusto da Silva Correia ◽  
Janduir Egito da Silva ◽  
Guilherme Quintela Calixto ◽  
Dulce Maria de Araújo Melo ◽  
Renata Martins Braga

ABSTRACT: This research valorized Pachira aquatica Aubl.’s fruit shells (PAS) through its energetic characterization and flash pyrolysis for biofuels or chemicals production. The characterization was performed through proximate and ultimate analysis, bulk density, higher heating value (HHV), hemicellulose, cellulose and lignin content, thermogravimetric analysis and absorption spectra in the infrared region obtained by Fourier-transform infrared spectroscopy technique (FTIR). The analytical flash pyrolysis was performed at 500°C in a Py-5200 HP-R coupled to a gas chromatograph (Py-GC/MS). The PAS biomass presents potential for thermochemical energy conversion processes due to its low moisture and ash content, 76.90% of volatile matter, bulk density of 252.6 kg/m3 and HHV of 16.24 MJ/kg. Flash pyrolysis products are mostly phenols or light organic acids derived from the decomposition of polysaccharides. Results confirmed the potential of PAS to produce bio-phenolics, such as 4-methoxyphenol which is an important active ingredient for skin depigmentation used in drugs and cosmetics, and as phenolic extract that can be used as a precursor to resins, applications that convert this forest waste into bio products for industry into a green circular economy.


Author(s):  
Sebastian Yocca ◽  
Matthias Zeller ◽  
Edward Byrd ◽  
Davin Piercey

5-amino-1-benzyloxytetrazole was aminated with O-tosylhydroxylamine. The diaminobenzyloxytetrazolium intermediate was debenzylated to yield the highly energetic 1,5-diaminotetrazole-4N-oxide (SYX-9). The molecule underwent both chemical and energetic characterization, including 15N NMR spectroscopy and...


Robotica ◽  
2021 ◽  
pp. 1-25
Author(s):  
Andrea Calanca ◽  
Tom Verstraten

Abstract The energetic advantages of series and parallel elastic actuators have been characterized in the literature considering different elastic systems and different tasks. These characterizations usually determine the energy consumption of a specific system during a specific task and generalize poorly. This paper proposes an energetic characterization of elastic actuators, following an analytical approach, rather than a data-driven one. In particular, this work analyzes the energy consumption of elastic actuators during resonant motion and introduces a novel efficiency index. This index characterizes energy consumption as a function of inherent actuator parameters only, generalizing over the specific tasks. The proposed analysis is validated using simulations and experiments, demonstrating its coherence with analytical results.


Author(s):  
Mayara de Oliveira Lessa ◽  
Guilherme Quintela Calixto ◽  
Bruna Maria Emerenciano das Chagas ◽  
Emerson Moreira Aguiar ◽  
Marcus Antônio de Freitas Melo ◽  
...  

Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4400
Author(s):  
Luca Ferraris ◽  
Fausto Franchini ◽  
Emir Pošković ◽  
Marco Actis Grande ◽  
Róbert Bidulský

In recent years, innovative magnetic materials have been introduced in the field of electrical machines. In the ambit of soft magnetic materials, laminated steels guarantee good robustness and high magnetic performance but, in some high-frequency applications, can be replaced by Soft Magnetic Composite (SMC) materials. SMC materials allow us to reduce the eddy currents and to design innovative 3D magnetic circuits. In general, SMCs are characterized at room temperature, but as electrical machines operate at high temperature (around 100 °C), an investigation analysis of the temperature effect has been carried out on these materials; in particular, three SMC samples with different binder percentages and process parameters have been considered for magnetic and energetic characterization.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Paula Gabriella Surdi de Castro ◽  
Vinícius Resende de Castro ◽  
Antonio José Vinha Zanuncio ◽  
José Cola Zanuncio ◽  
Angélica de Cássia Oliveira Carneiro ◽  
...  

AbstractThe use of wood panel residues as biomass for energy production is feasible. Heat treatments can improve energy properties while minimizing the emission of toxic gases due to thermoset polymers used in Medium Density Fiberboard (MDF) panels. Torrefaction or pre-carbonization, a heat treatment between 200 and 300 °C with low oxygen availability accumulates carbon and lignin, decreases hygroscopicity, and increases energy efficiency. The objective of this work was to evaluate the energy parameters (immediate, structural, and elementary chemical composition, moisture content, and yield) and density in torrefied MDF panels. The torrefaction improved the energetic features of coated MDF, decreasing the moisture content, volatile matter, and consequently, concentrating the carbon with better results in the samples torrefied for 40 min. The densitometric profiles of the torrefied MDF, obtained by X-ray densitometry, showed a decrease in the apparent density as torrefaction time increased. The digital X-ray images in gray and rainbow scale enabled the most detailed study of the density variation of MDF residues.


Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 98
Author(s):  
Volker Mauer ◽  
Christian Bläker ◽  
Christoph Pasel ◽  
Dieter Bathen

In addition to the adsorption mechanism, the heat released during exothermic adsorption influences the chemical reactions that follow during heterogeneous catalysis. Both steps depend on the structure and surface chemistry of the catalyst. An example of a typical catalyst is the faujasite zeolite. For faujasite zeolites, the influence of the Si/Al ratio and the number of Na+ and Ca2+ cations on the heat of adsorption was therefore investigated in a systematic study. A comparison between a NaX (Sodium type X faujasite) and a NaY (Sodium type Y faujasite) zeolite reveals that a higher Si/Al ratio and therefore a smaller number of the cations in faujasite zeolites leads to lower loadings and heats. The exchange of Na+ cations for Ca2+ cations also has an influence on the adsorption process. Loadings and heats first decrease slightly at a low degree of exchange and increase significantly with higher calcium contents. If stronger interactions are required for heterogeneous catalysis, then the CaNaX zeolites must have a degree of exchange above 53%. The energetic contributions show that the highest-quality adsorption sites III and III’ make a contribution to the load-dependent heat of adsorption, which is about 1.4 times (site III) and about 1.8 times (site III’) larger than that of adsorption site II.


2021 ◽  
Vol 26 (4) ◽  
Author(s):  
Iara Nobre Carmona ◽  
Juliane da Silva Sampaio ◽  
Pablo Antônio Souza Amorim da Luz ◽  
Fernando Wallase Carvalho Andrade

ABSTRACT Biomass residues originated from agroforestry systems has been demonstrating great usage potential for the pharmaceutical, textile and energy industries. In the Amazon region, the use of these materials can stimulate the sustainable economic development of extractive communities and agroforestry systems. However, for a better use of this material, it is necessary to quantify and qualify the chemical components present in these residues. Keeping that in mind, our research aimed to quantify the presence of condensed and hydrolysable tannins, and to chemically and energetically characterize the Bertholletia excelsa and Lecythis pisonis’ fruit residues, with the intent to assess the usage potential for this biomass resource in different industries. The studied material was collected from local extractives and merchants. Tannin quantification was performed through thin layer chromatography (TLC) method and the total values of extractives, lignin and holocellulose were also quantified. The energy potential was determined by the variables of apparent density, gravimetric yield, superior calorific power and charcoal’s immediate chemistry (the charcoal was produced at 450 ºC). The associations between variables were determined by a linear correlation. The TLC for condensed tannin was positive for B. excelsa. As for the TLC of hydrolysable tannins, the results were negative for both materials. The high levels of lignin and extractives in fruit’s residues of both species demonstrate the energy potential of this material. Our results may favor the use of B. excelsa’s residues for the production of polymers and adhesives, as well as other non-wood residues with high content of lignin, fixed carbon and calorific power in energetic products.


Sign in / Sign up

Export Citation Format

Share Document