conductive fillers
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Nanomaterials ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 92
Author(s):  
Julie Regnier ◽  
Aurélie Cayla ◽  
Christine Campagne ◽  
Éric Devaux

In many textile fields, such as industrial structures or clothes, one way to detect a specific liquid leak is the electrical conductivity variation of a yarn. This yarn can be developed using melt spun of Conductive Polymer Composites (CPCs), which blend insulating polymer and electrically conductive fillers. This study examines the influence of the proportions of an immiscible thermoplastic/elastomer blend for its implementation and its water detection. The thermoplastic polymer used for the detection property is the polyamide 6.6 (PA6.6) filled with enough carbon nanotubes (CNT) to exceed the percolation threshold. However, the addition of fillers decreases the polymer fluidity, resulting in the difficulty to implement the CPC. Using an immiscible polymers blend with an elastomer, which is a propylene-based elastomer (PBE) permits to increase this fluidity and to create a flexible conductive monofilament. After characterizations (morphology, rheological and mechanical) of this blend (PA6.6CNT/PBE) in different proportions, two principles of water detection are established and carried out with the monofilaments: the principle of absorption and the short circuit. It is found that the morphology of the immiscible polymer blend had a significant role in the water detection.


Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7505
Author(s):  
Vít Černý ◽  
Grigory Yakovlev ◽  
Rostislav Drochytka ◽  
Šimon Baránek ◽  
Lenka Mészárosová ◽  
...  

Electroconductive cement-based composites are modern materials that are commonly used in many industries such as the construction industry, among others. For example, these materials can be used as sensors for monitoring changes in construction, grounding suspension, and resistance heating materials, etc. The aim of the research presented in this article is to monitor the impact of carbon particle character on cement-based electroconductive composites. Four types of graphite were analyzed. Natural and synthetic types of graphite, with different particle sizes and one with improved electrically conductive properties, were tested. For the analysis of the electrical conductivity of powder raw materials, a new methodology was developed based on the experience of working with these materials. Various types of graphite were tested in pure cement paste (80% cement, 20% graphite) as well as in a composite matrix, which consisted of cement (16.8%), a mixture of silica sand 0–4 mm (56.4%), graphite filler (20.0%) ground limestone (6.7%) and super plasticizers (0.1%). The resistivity and physical-mechanical properties of the composite material were determined. Furthermore, the resistivity of the test samples was measured with a gradual decrease in saturation. It may be concluded that graphite fillers featuring very fine particles and high specific surface are most suitable and most effective for creating electrically conductive silicate composites. The amount, shape and, in particular, the fineness of the graphite filler particles thus creates suitable conditions for the creation of an integrated internal electricity-conductive network. In the case of the use of a coarse type of graphite or purely non-conductive fillers, the presence of an electrolyte, for example, in the form of water, is necessary to achieve a low resistivity. Samples with fine types of graphite fillers achieved stable resistivity values when the sample humidity changed. The addition of graphite fillers caused a large decrease in the strength of the samples.


2021 ◽  
Vol 21 (12) ◽  
pp. 5881-5889
Author(s):  
Hyun Jin Nam ◽  
Ji-Hun Yuk ◽  
Kyu Song ◽  
Young Sun Kim ◽  
Su-Yong Nam ◽  
...  

Recently, flexible electronic device technology has evolved beyond curved devices with the development of flexible/stretchable devices that can be crumpled or stretched. Both elasticity and durability are essential for these devices, which should have high-conductivity for antennas and repeatability for sensors. In addition, electronic-skins, which can have a direct impact on the human-body, should be harmless to the human-body and should not be deformed by contact with sweat or organic matter. In this study, PDMS substrates were used to satisfy the above conditions. PDMS is used to fabricate human-friendly, flexible/stretchable substrates, and it has excellent repeat durability characteristics. To improve the adhesion of these PDMS films and electrodes, conductive paste was produced based on PDMS resins of the same properties. In addition, two types of Ag particles were selected as conductive fillers because the electrode characteristics of the antenna application requires excellent conductivity, and conductive paste were produced using flake Ag, which could affect conductivity, and Ag nanoparticles that affect stretchability and repeatability. The paste was applied using a high-efficiency printing technique. The printed electrodes were cured in a thermal oven. For higher conductivity, photonic-sintering was carried out during post-processing. As a result, 1.1117×106 (S/m) had excellent conductivity, performed well in repeated tensile-durability experiments of 30% to 100 times, and produced a bow-tie antenna for the above electrodes. As a result of tensing up to 35% through a Network-Analyzer, there was no performance change in the resonance-frequency or return-loss values, and excellent electrodes were developed that would achieve excellent performance even if they are applied in the sub-frequency area of 5G-antennas in the future.


2021 ◽  
Author(s):  
Xiao Min Zhang ◽  
Xiao-Li Yang ◽  
Bin Wang

Abstract Printable electrically conductive adhesive with high electrical conductivity and good mechanical properties has wide application prospect in electronic device. In order to explore new conductive fillers of interconnecting materials in electronic circuit and electronic packaging industries, silver nanopowders were prepared by DC arc plasma method with high pure. The silver nanopowders present a spherical structure, the particle’s diameter range from 15 to 220 nm. In this paper, a high performance electrically conductive adhesive (ECA) was prepared. This ECA was fabricated by mixing silver nanopowders with epoxy resin and was screen-printed to a required shape. It was found that the ECA can be solidified through a low temperature sintering method in the air at 150 ℃ for 10 min. The electrical and mechanical of above ECA were investigated and characterized. The ECA filled with 75% silver nanopowders exhibits excellent performances, including high electrical conductivity (9.5×10-4 Ω·cm), high bonding strength ( 8.3 MPa). Based on the performance characteristics, the ECA applications in flexible printed electrodes and interconnecting materials are demonstrated.


2021 ◽  
Vol 2065 (1) ◽  
pp. 012012
Author(s):  
R Y Zhao ◽  
Z W Zhao ◽  
Z J Weng ◽  
Y Fang ◽  
H L Jiang

Abstract The inorganic conductive network provides an essential channel for electron transport and supports the biogeochemical process in sediments, but the conductive mechanism of conductive network is not well understood. In this work, theory of circuit and electronics was applied to build a three-dimensional (3D) resistivity network simulation model for exploring the conductive mechanism and analysing the effect of the particle size on the conductive characteristic of inorganic conductive network. In order to simulate the real sediment environment, inorganic composites with silica (SiO2) particles as matrix using magnetite (Fe3O4) particles as fillers are constructed. The simulation results reveal that the electrical conductivity of these composites rises nonlinearly with the increasing volume fraction of conductive fillers, which is consistent with the percolation theory. Moreover, small-sized conductive particles or large-sized matrix particles are confirmed to exert a positive part in enhancing electrical conductivity of composites.


Polymers ◽  
2021 ◽  
Vol 13 (19) ◽  
pp. 3337
Author(s):  
Md. Abdul Alim ◽  
Mohd Zulkifly Abdullah ◽  
Mohd Sharizal Abdul Aziz ◽  
R. Kamarudin ◽  
Prem Gunnasegaran

The application of epoxy adhesive is widespread in electronic packaging. Epoxy adhesives can be integrated with various types of nanoparticles for enhancing thermal conductivity. The joints with thermally conductive adhesive (TCA) are preferred for research and advances in thermal management. Many studies have been conducted to increase the thermal conductivity of epoxy-based TCAs by conductive fillers. This paper reviews and summarizes recent advances of these available fillers in TCAs that contribute to electronic packaging. It also covers the challenges of using the filler as a nano-composite. Moreover, the review reveals a broad scope for future research, particularly on thermal management by nanoparticles and improving bonding strength in electronic packaging.


2021 ◽  
Vol 11 (18) ◽  
pp. 8452
Author(s):  
Pedro de Almeida Carísio ◽  
Yasmim Gabriela dos Santos Mendonça ◽  
Carlos Fernando Teodósio Soares ◽  
Oscar Aurelio Mendoza Reales ◽  
Eduardo de Moraes Rego Fairbairn ◽  
...  

Due to their exceptional electrical properties, carbon nanotubes (CNTs) can be applied as conductive fillers to develop self-sensing cement-based matrices. In order to obtain an adequate self-sensing response, CNTs must be evenly dispersed through the cement matrix in a volume sufficient enough to create an electric percolation network. This is challenged by the difficulty of dispersing CNTs; therefore, there is a demand for an efficient dispersing agent that can be filled by superplasticiezers, which are products of known compatibility with cement and high availability. This research explores the use of four commercial superplasticizers available in Brazil, both naphthalene and ether polycarboxylate-based, as dispersing agents for CNTs in water. Ultrasonic energy was applied to aqueous solutions containing CNTs and superplasticizers. UV–Vis spectroscopy and ξ-potential measurements were used to investigate which superplasticizer was more effective to disperse the CNTs. Cement pastes were produced with the CNT dispersions and their electrical resistivity was measured. It was found that only superplasticizers without aliphatic groups in their structure were capable of dispersing CNTs in water. It was concluded that second-generation naphthalene-based superplasticizers were more efficient dispersing agents for CNTs than third-generation ether polycarboxylate-based ones for self-sensing applications.


Materials ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 4798
Author(s):  
Ting Luo ◽  
Qiang Wang

Electrically conductive cementitious composites (ECCCs) have been widely used to complete functional and smart construction projects. Graphite, due to its low cost and wide availability, is a promising electrically conductive filler to generate electrically conductive networks in cement matrixes. Cement-based materials provide an ideal balance of safety, environmental protection, strength, durability, and economy. Today, graphite is commonly applied in traditional cementitious materials. This paper reviews previous studies regarding the effects and correlations of the use of graphite-based materials as conductive fillers on the properties of traditional cementitious materials. The dispersion, workability, cement hydration, mechanical strength, durability, and electrically conductive mechanisms of cementitious composites modified with graphite are summarized. Graphite composite modification methods and testing methods for the electrical conductivity of ECCCs are also summarized.


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