peel adhesion
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Materials ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 246
Author(s):  
Karolina Mozelewska ◽  
Zbigniew Czech ◽  
Marcin Bartkowiak ◽  
Małgorzata Nowak ◽  
Paulina Bednarczyk ◽  
...  

In this study, syntheses of acrylate copolymers were performed based on the monomers butyl acrylate (BA), 2-ethylhexyl acrylate (2-EHA), and acrylic acid (AA) and the second-type unsaturated photoinitiator 4-acryloyloxybenzophenone (ABP). The structure of the obtained copolymers was confirmed via FT-IR spectroscopic analysis, and the viscosity and the content of non-volatile substances were determined. The adhesive films were then coated and cross-linked using ultraviolet radiation in the UV-C range at various doses (5–50 mJ/cm2). Due to the dependence of the self-adhesive properties of the adhesive layer on the basis weight, various basis weights of the layer in the range of 30–120 g/m2 were tested. Finally, the self-adhesive properties were assessed: tack, peel adhesion, shear strength (cohesion) at 20 °C and 70 °C, as well as the SAFT test and shrinkage. The aim of the study was to determine the effect of the type of monomer used, the dose of ultraviolet radiation, and the basis weight on the self-adhesive and usable properties of the obtained self-adhesive tapes.


Polymers ◽  
2021 ◽  
Vol 13 (24) ◽  
pp. 4413
Author(s):  
Marcin Bartkowiak ◽  
Zbigniew Czech ◽  
Hyun-Joong Kim ◽  
Gyu-Seong Shim ◽  
Małgorzata Nowak ◽  
...  

The use of ultraviolet radiation (UV) technology for the crosslinking of acrylic pressure-sensitive adhesives (PSA) is the one of various crosslinking methods, being the alternative to the conventional crosslinking process of solvent-based acrylic systems. It also requires a photoinitiator to absorb the impinging UV and induce photocrosslinking. As previously mentioned, a photoinitiator is one of the important and necessary components in UV-inducted crosslinking of acrylic pressure-sensitive adhesives. The activity of multifunctional conventional saturated photoinitiators of type I and type II, especially benzophenone-based in the photoreactive UV-crosslinkable acrylic PSA was described. The effect of the multifunctional type-II photoinitiators on the acrylic PSA, such as tack, peel adhesion and shear strength were summarized.


Author(s):  
Adrian Krzysztof Antosik ◽  
Karolina Mozelewska ◽  
Marta Piątek-Hnat ◽  
Zbigniew Czech ◽  
Marcin Bartkowiak

AbstractThe purpose of this work was to obtain single-sided tapes with different concentrations of kaolin and to check its impact on the self-adhesive properties of commercial adhesives. The most important self-adhesive properties were examined, such as tack, peel adhesion, shear strength, shrinkage, and thermal resistance. Tapes based on silicone PSAs with kaolin can be used in many branches of industry to bond elements operating at elevated temperatures, i.e., in aeronautics, aerospace including solar cells for satellites and space stations. There are few reports on one-sided adhesive tapes based on silicones with the addition of kaolin. However, taking into account the number of their potential applications, we did self-adhesive tests and explained how kaolin affects them. In addition, the reactivity of the crosslinking compound and silicone adhesive during the crosslinking process and the thermal effects of this process were also examined. In connection with the various applications of the obtained tapes, also the flammability and heat of combustion were tested, in accordance with applicable standards. As a result of the tests, one-sided self-adhesive tapes with new properties (increased temperature resistance, less shrinkage, and increased resistance to flammability) were obtained.


2021 ◽  
Author(s):  
Katarzyna Wilpiszewska ◽  
Zbigniew Czech

Abstract Introducing biopolymer derivative, i.e. carboxymethyl starch into pressure-sensitive adhesives for paper industry has been proposed. Obtained adhesives were transferred onto water-dispersible paper carrier giving repulpable double-sided splicing tape. The effect of carboxymethyl starch degree of substitution on essential adhesive properties: tack, peel adhesion, as well as shear strength for steel and various papers has been tested. Additionally, the solubility in water and alkaline medium has been evaluated. The highest tack and peel adhesion increase was reported for PSA containing CMS with degree of substitution DS 0.86, to fax paper. Moreover, the dynamic shear strength test imitating the shear conditions in paper processing revealed, that the highest values of this parameters exhibited the system with 15 wt.% CMS DS 0.86. For this system the shortest water-dissolving times as well as at elevated pH were noted: 314 s and 60 s, respectively.


2021 ◽  
Vol 340 ◽  
pp. 01033
Author(s):  
Ilya Antonov ◽  
Boris Tolochko ◽  
Alexandr Varand ◽  
Mikhail Mikhailenko ◽  
Ilya Eltsov ◽  
...  

Polymerization was carried out using the method of radiation initiation, for which benzyl methacrylate (BzMA) and isodecyl methacrylate (IDMA) were treated with a beam of accelerated electrons. It is shown that to obtain highly filled compositions, the most suitable method is the alternation of heating-cooling cycles with the gradual introduction of material particles. Tungsten composites were obtained with a calculated density in the range from 3 to 6.8 g / cm3. The absence of percolation conductivity in coatings with tungsten was found. Peel adhesion of the composite coating to the surface was 1 ± 0.3·10-1 MPa with volume fraction of tungsten more than 30%.


Materials ◽  
2020 ◽  
Vol 13 (22) ◽  
pp. 5151
Author(s):  
Zbigniew Czech ◽  
Janina Kabatc ◽  
Marcin Bartkowiak ◽  
Adam Licbarski ◽  
Karolina Mozelewska ◽  
...  

A new class of additionable ultraviolet photoinitiators that can be used, through addition, for modification of the acrylic polymer chain and their influence of main properties of acrylic pressure-sensitive adhesives (PSAs) is described here. The photoinitiators studied are based on benzophenone, dibenzofuran and anthraquinone chromophores. The propyleneimine carbonyl is the reactive additionable group incorporated in the photoinitiator structure. First, the solvent-borne acrylic pressure-sensitive adhesive was synthesized and characterized. Then, a photoinitiator suitable for addition to the acrylic polymer chain possessing a carboxyl group was added before UV-irradiation. A mechanism of UV-initiated cross-linking reaction of acrylic PSA with additionable photoinitiators was done as well. The influence of the concentration and type of photoinitiator, UV-crosslinking time and UV-dose on peel adhesion, shear strength and tack of solvent-borne acrylic pressure-sensitive adhesives cross-linked by UV light was studied and presented here. It was found that the tack depends on the UV-dose and photoinitiator concentration. An increase of UV dose results in an increase of shear strength of acrylic pressure-sensitive adhesive (PSA) formulations.


Author(s):  
Marjeta Čuk ◽  
◽  
Matejka Bizjak ◽  
Deja Muck ◽  
Tanja Nuša Kočevar ◽  
...  

3D printing is used to produce individual objects or to print on different substrates to produce multi-component products. In the textile industry, we encounter various 3D printing technologies in fashion design, functional apparel manufacturing (protective, military, sports, etc.), including wearable electronics, where textile material is functionalized. 3D printing enables the personalization of the product, which in the apparel industry can be transformed into the production of clothing or parts of clothing or custom accessories. Additive technology allows a more rational use of the material than traditional technologies. In the textile industry we meet different uses of it, one is the printing of flexible structures based on rigid materials, another is the printing with flexible materials and the third is the printing directly on textile substrate. All rigid, hard and soft or flexible materials can be integrated into the final design using 3D printing directly on the textile substrate. We speak of so-called multi-material objects and systems, which have many advantages, mainly in the increasing customization and functionalization of textiles or clothing. The article gives a broader overview of 3D printing on textiles and focuses mainly on the influence of different parameters of printing and woven fabric properties on the adhesion of 3D printed objects on the textile substrate. In our research we investigated the influence of twill weave and its derivate as well as different weft densities of the woven fabric on the adhesion of printed objects on textile substrate. Therefore, five samples of twill polyester/cotton fabrics were woven and their physical properties measured for this research. 3D objects were printed on textile substrates using the extrusion based additive manufacturing technique with polylactic acid (PLA) filament. Preliminary tests were carried out to define printing parameters and different methods of attaching the fabric to a printing bed were tested. T - Peel adhesion tests were performed on the Instron dynamometer to measure the adhesion between 3D printed objects and textile substrates.


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