Selective ozone activation of phenanthrene in liquid CO2

Facile phenanthrene (as a polyaromatic model compound) ozonolysis to oxygenated material precursors has been demonstrated in liquid CO2.

Photosynthesis of Physalis peruviana under different densities of photons and saline stress

Physalis peruviana L. is a solanacea that has been gaining prominence due to its fruits presenting good acceptance in the national and international market. However, several abiotic factors, such as salinity, can cause physiological disturbances in plants, and these changes may be of greater or lesser intent according to species. Therefore, the objective of the present work was to evaluate the physiological behavior of P. peruviana submitted to different fluxes of photosynthetically active photons (PPFD) and saline stress. The experimental design was a randomized block design with three saline levels (ECw) (0.5, 2.75 and 5.00 dS m-1) with four replications. Gas exchange measurements were performed with a portable infrared gas analyzer. Liquid CO2 assimilation, stomatal conductance, internal CO2 concentration, water use efficiency and instantaneous carboxylation efficiency were measured. Data were subjected to analysis of variance by F test and in cases of significance applied to regression analysis. The increase in PPFD provided reductions in stomatal conductance up to the density of approximately 400 μmol m-2s-1, being more pronounced in ECw of 2.75 and 5.0 dS m-1. The maximum CO2 assimilation rates in the three salinities are different according to the PPFD. The salinity of irrigation water reduced the quantum efficiency of photosynthesis in P. peruviana plants.

Liquid CO2 Phase-Transition Rock Fracturing: A Novel Technology for Safe Rock Excavation

In order to determine the applicability of liquid CO2 phase-transition fracturing technology in rock mass excavations, the principles of CO2 phase-transition fracturing were analyzed, and field tests of liquid CO2 phase-transition fracturing were performed. An “Unmanned Aerial Vehicle (UAV) camera shooting + Microstructure Image Processing System (MIPS) analyzing” method was used to acquire the rock mass characteristics. Further, the Hilbert–Huang Transform (HHT) energy analysis principle was adopted to analyze the characteristics of fracturing vibration waves. The experimental results showed that during the process of fracturing, there were both dynamic actions of rock breakage due to excitation stress wave impacts, and quasi-static actions of rock breakage caused by gasification expansion wedges. In semi-infinite spaces, rock-breakage zones can mainly be divided into crushing zones, fracture zones, and vibration zones. At the same time, under ideal fracturing effects and large volumes, the fracturing granularity will be in accordance with the fractal laws. For example, the larger the fractal dimensions, the higher the proportion of small fragments, and vice versa. Moreover, the vibration waves of the liquid CO2 phase-transition fracturing have short durations, fast attenuation, and fewer high-frequency components. The dominant frequency band of energy will range between 0 and 20 Hz. The liquid CO2 phase-transition fracturing technology has been observed to overcome the shortcomings of traditional explosive blasting methods and can be applied to a variety of rock types. It is a safe and efficient method for rock-breaking excavations; therefore, the above technology effectively provides a new method for the follow-up of similar engineering practices.

Capillary-gravitational waves and storage of liquid CO2 in the oceans

A theory of capillary-gravitational waves in the transition region between seawater and liquid carbon dioxide in deep oceans is proposed. It is shown that the thickness of the transition layer affects the properties of capillary-gravity waves. The question of the structure and stability of wave disturbances at the interface between seawater and liquefied carbon dioxide is essential for the safe storage of liquefied carbon dioxide in the ocean. This is an important issue on the current agenda in light of global warming.

Different Extracting Methods of Medicinal Herbs

Salvia officinalis L. is well known as an aromatic and medicinal plant in Albania. Several studies suggest that Salvia officinalis L., in addition to treating minor common illnesses, might potentially provide novel natural treatments for the relief or cure of many serious and life-threatening diseases such as depression, dementia, obesity, diabetes, lupus, heart disease, cancer or antibacterial treatments. The most common methods used for obtaining extracts of essential oils are water distillation, distillation with organic solvents such as hexane, ethanol, methanol and extraction with liquid CO2 under pressure as well. The extracts fractions obtained by these methods are of interest especially in the fields of pharmacology, cosmetic, medicine, food chemistry etc. In this study the extraction of essential oil from Salvia officinalis L is carried out by using an organic solvent (hexane) and liquid CO2 solvent under pressure at 40 0 C. The essential oil extracts are analyzed by thin layer chromatography. The amount of essential oil and the overall yield obtained by hexane distillation method is lower than that obtained by CO2 extraction method. These findings demonstrated that the amount of S. Officinalis oils obtained by CO2 extraction method is optimal, making that suitable for a possible use in pharmaceutical purposes.

Strategy Targets Risk Management for CO2 Waterless Fracturing

This article, written by JPT Technology Editor Chris Carpenter, contains highlights of paper OTC 30437, “Risk Management and Control for CO2 Waterless Fracturing,” by Siwei Meng, Qinghai Yang, SPE, and Yongwei Duan, PetroChina, et al., prepared for the 2020 Offshore Technology Conference Asia, originally scheduled to be held in Kuala Lumpur, 2–6 November. The paper has not been peer reviewed. Copyright 2020 Offshore Technology Conference. Reproduced by permission. Given shortages and uneven distribution of water resources in China, efforts must be made to develop waterless fracturing techniques. The fluid experiences high pressures and low temperatures during carbon dioxide (CO2) waterless fracturing operations, which can lead to accidents and environmental pollution. In the complete paper, a safety-management approach and a contingency plan for such operations are developed. At the time of writing, this CO2 waterless fracturing methodology has been completed successfully more than 20 times. Surface Process Work Flow of CO2 Waterless Fracturing The basic process of a CO2 waterless fracturing operation is shown in Fig. 1. First, several CO2 storage tanks are connected in parallel. The booster, sealed blender, fracturing pump (all mounted on trunks), and wellhead equipment are connected. The measuring trunk communicates with each vehicle to monitor operation status. Proppant is put into the sealed blender, into which liquid CO2 is injected for pre-cooling. Pump testing is conducted on the high-pressure line and the wellhead and the low-pressure liquid supply line is pressure-tested. Operation does not proceed until pressure-testing results are positive. Afterward, liquid CO2 is injected into formations to fracture them and, moreover, extend created fractures. The sealed blender is enabled to inject prop-pants, and displacement begins after the end of proppant injection. Finally, a series of tasks, including well shut-in for soaking and flowback, is carried out successively.