Geochemistry of the Dust Collected by Passive Samplers as a Tool for Search of Pollution Sources: The Case of Klaipėda Port, Lithuania

Geochemical investigations of total suspended particulates (TSP) help detect hotspots and emission sources in port cities with stevedoring operations. The aim was to reveal these sources via geochemical indices (gI). TSP were collected in Klaipėda using original passive samplers in ten sites during four periods, during one of them, in ten additional sites near iron ore stevedoring (IOS). The contents of 22 elements (PHEs, crustal, Br, Cl) were determined by EDXRF in TSP and characteristic dust (CD) of stevedored iron ore, apatite, phosphorite, potassium fertilizers, and in waste incineration ash. Median Fe content in TSP near IOS was ~29%. The significant anthropogenic origin of clusters Fe–Cr, Sr–P, V–Ni–Zn–Cu, Pb–As, and Mg–Ca, Br–S–Cl was confirmed by gI mapping and analysis of CD. Significant temporal variability of Cl, S, Sr, Ni, Br, V, and Zn due to weather changes was revealed. Near IOS, significantly higher values of gI were found for Fe and Cr, while far from IOS, for K, Sr, Ti, Rb, Cu, Al, Si, Zr, Ca, Mg. Significantly higher values of normalized enrichment factor near IOS were not only for Fe and Cr, but also for As, Pb, S, Mn, Br, and Cl.

Evaluation of airborne total suspended particulates and heavy metals in anodizing and electroplating surface treatment process

This study is to evaluate exposure to harmful substances, such as particulate and heavy metals, by considering various factors, in anodizing and electroplating surface treatment process. Exposure evaluation studies on seven heavy metals (Cr, Zn, Ni, Pb, Cd, Al, and Ba) and total suspended particulates (TSP) were conducted. Heavy metals were analyzed using inductively coupled plasma mass spectrometry (ICP-MS). This study also checked the ventilation volume of the hood with a thermal anemometer. Measurement was conducted for 8 h and 8 days. The sample number, N, of the heavy metals and TSP was 107. Geometric mean (GM) of TSP during Cr plating process was 6.15(GSD, 3.35) mg/m3. GM of Cr during Cr plating was 1.86(GSD, 6.65) mg/m3. GM of TSP and heavy metals differences were statistically significant for each process and date variation. Average ventilation volume for all hoods ranged from 1.20 to 4.98 m3/s. In the hood 30 cm from bath, ventilation was 0.1 times lower. Increasing ventilation volume of the hood was the most influential factor, followed by machine operation time and workload. The high concentration was due to low ventilation suction flow. We can improve health to reduce exposure by resolving the fundamental cause of risk occurrence.

A study to quantify surgical plume and survey the efficiency of different local exhaust ventilations

This study aimed to compare the concentration of surgical smoke produced by different tissues and electric diathermy modes and to measure the effectiveness of various local exhaust ventilations. We compared the surgical plume concentration from different tissues and settings with a porcine tissue model. We also compared the efficiency of three local exhaust ventilations: (1) a desktop unit (Medtronic Rapid Vac), (2) a central evacuation system with ENT suction, and (3) a central evacuation system with a urethral catheter (PAHSCO Urethral Catheter). In the cutting setting, the skin tissue had a higher concentration of total suspended particulates (TPS), which were 1990 ± 2000 (mean ± SD, μg/m3), 6440 ± 3000 and 9800 ± 2300 at 15, 30 and 45 s, respectively (p < 0.05). In the coagulation setting, the adipose tissue had a higher concentration of TPS, which were 3330 ± 2600, 11,200 ± 5500 and 15,800 ± 7300, respectively (p < 0.05). We found that all three smoke extractors had more than 96% efficiency in clearing surgical smoke. With electric diathermy, skin tissue in the cutting model and adipose tissue in the coagulation mode will produce higher concentration of particles within surgical plumes. An electric surgical scalpel adapted with a urethral catheter is a simple and effective way to exhaust smoke in surgical operations.

Exposure Assessment of Total Suspended Particulates and Heavy Metals in Anodizing and Electroplating Surface Treatment Process

Objective: This study is to evaluate exposure to harmful substances, such as particulate and heavy metals, by considering various factors, in anodizing and electroplating surface treatment process.Methods: Exposure evaluation studies on seven heavy metals (Cr, Zn, Ni, Pb, Cd, Al, and Ba) and total suspended particulates (TSP) were conducted. Heavy metals were analyzed using inductively coupled plasma mass spectrometry (ICP-MS). This study also checked the ventilation volume of the hood with a thermal anemometer. Measurement was conducted for 8 hours and 8 days. The sample number, N, of the heavy metals and TSP was 107. Results: Geometric mean (GM) of TSP during Cr plating process was 6.15(GSD, 3.35) mg/m3. GM of Cr during Cr plating was 1.86(GSD, 6.65) mg/m3. GM of TSP and heavy metals differences were statistically significant for each process and date variation. Average ventilation volume for all hoods ranged from 1.20 to 4.98 m3/s. In the hood 30 cm from bath, ventilation was 0.1 times lower. Increasing ventilation volume of the hood was the most influential factor, followed by machine operation time and workload.Conclusion: The high concentration was due to low ventilation suction flow. We can improve health to reduce exposure by resolving the fundamental cause of risk occurrence.

Community Health Risk Assessment of Total Suspended Particulates near a Cement Plant in Maros Regency, Indonesia

Background. Cement plants generate particulate matter (PM) across processes from raw material preparation to packaging. The presence of total suspended particulates (TSP) coming out of the stack causes a high accumulation of dust in residential areas. Human exposure to TSP could affect human health and wellbeing. Objectives. The present study aims to evaluate concentrations of TSP and to estimate the health risks of TSP exposure through the inhalation pathway in communities surrounding a private cement industry in Maros regency, Indonesia. Methods. Total suspended particulates were collected using a high-volume air sampler (HVAS) at five locations. Samples were taken by grab sampling for 24 hours. The SCREEN3 program was used to view the maximum range and distribution of pollutants based on the geographical, stack profiles and meteorological factors in the study area. Hazard quotient (HQ) was used to estimate non-carcinogenic risks of TSP in surrounding communities. Results. Total suspended particulate concentrations were measured with a maximum value of 133.24 μg/m3 and a minimum value of 18.48 μg/m3. This maximum value exceeds the minimum acceptable level from Canadian National Ambient Air Quality Objectives (C-NAAQOs). The non-carcinogenic risks from the inhalation pathway were low except for location 3 (HQ&gt;1) across all locations. Conclusions. The cement plant may significantly contribute to total TSP concentrations in air and may potentially have adverse effects on human health. Communities near the cement plant are vulnerable to TSP exposure and measures are needed to reduce TSP in Maros regency, Indonesia. Participant Consent. Obtained Ethics Approval. This study was approved by the Health Research Ethics Committee of Hasanuddin University with protocol number 28920093022. Competing Interests. The authors declare no competing financial interests.

Size-Segregated Atmospheric Humic-Like Substances (HULIS) in Shanghai: Abundance, Seasonal Variation, and Source Identification

Humic-like substances (HULIS) are of great interest due to their optical and chemical characteristics. In this study, a total of 180 samples of atmospheric particulate matter (PM) of different sizes were collected from summer 2018 to spring 2019, in order to analyze the size distribution, to investigate the seasonal variation and then to identify the key sources of HULIS. The annual mean concentration of HULIS in the total suspended particulates reached 5.12 ± 1.42 μg/m3. The HULIS concentration was extremely higher in winter (8.35 ± 2.06 μg/m3) than in autumn (4.88 ± 0.95 μg/m3), in summer (3.62 ± 1.68 μg/m3) and in spring (3.36 ± 0.99 μg/m3). The average annual ratio of water-soluble organic carbon (WSOC) to OC and the ratio of HULIS to WSOC reached 0.546 ± 0.092 and 0.56 ± 0.06, respectively. Throughout the whole year, the size distributions of WSOC and HULIS-C were relatively smooth. The peaks of WSOC appeared at 1.8~3.2 μm and 0.56~1.0 μm, while the peaks of HULIS-C were located at 3.2~5.6 μm, 1.0~1.8 μm and 0.18~0.32 μm. The distribution of the HULIS particle mode was similar in spring, summer and autumn, while there was a lower proportion of the coarse mode and a higher proportion of the condensation mode in winter. By using the comprehensive analysis of principal component analysis (PCA), air mass backward trajectories (AMBTs) and fire point maps, key sources of WSOC and HULIS in Shanghai were identified as biomass combustion (48.42%), coal combustion (17.49%), secondary formation (16.07%) and vehicle exhaust (5.37%). The remaining part might be contributed by crustal dust sources, marine sources and/or other possible sources. This study provides new insight into the characteristics and size distribution of HULIS in Shanghai, thereby providing a practical base for further modeling.

Effect of transport measures and curfew against COVID-19 spread on air pollution (TSP) in Ecuador’s three most populous cities

Although current circumstances pose challenges to foretelling the future consequences of coronavirus spread, we consider environmental load-related researches became more and more important nowadays perhaps as never before. Many experts believe that the increasingly dire public health emergency situation, policy makers and word leaders should make it possible that the COVID-19 outbreak contributes to a transition of sustainable consumption. With the purpose of contributing to rethink the importance of sustainability efforts, here we present total suspended particulates (TSP) results which represent traffic emission caused air pollution in the three most populous cities of Ecuador obtained before, during, and after the: (i) the traffic measures entered into force on state level; (ii) curfew entered into force on state level; (iii) and quarantine entered into force (in Guayaquil, and whole Guayas province). We documented significant decrease in TSP emissions (PM2.5 and PM10) compared to normal traffic operation obtained from some four lanes roads in Quito, Guayaquil, and Cuenca. The most remarkable fall in suspended particulate values (96.47% decrease in PM2.5) compared to emission observed before traffic measures occurred in Cuenca.

Effect of transport measures and curfew against COVID-19 spread on air pollution (TSP) in Ecuador’s three most populous cities

Although the current situation poses challenges to foretelling the future consequences of coronavirus spread, we consider that environmental load-related research has become more important than ever before. Many experts believe that in the framework of increasingly dire public health emergency, policy and decision makers should facilitate COVID-19 outbreak to transitioning to sustainable consumption and production. With the purpose of evaluating the importance of sustainability efforts, here we describe the total suspended particulates (TSP), originating from traffic emissions, caused by air pollution in the three most populous cities of Ecuador. Compared are measurements taken prior to, during, and after (i) traffic measures entered into force at national level; (ii) curfew entered into force at national level; and (iii) quarantine entered into force (in Guayaquil, and whole Guayas province). We documented significant decrease in TSP emissions (PM2.5 and PM10) as compared to normal traffic proceeding in four-lane roads, in the cities of Quito, Guayaquil, and Cuenca. The most substantial drop in suspended particulate values (96.47% decrease in PM2.5) relative to emissions observed prior to restricting traffic occurred in Cuenca.

Air purifier – individual protection against indoor particulate matter

The research work presents the findings of testing air purified using two commercial air purifiers available on the local market. Tests were carried out in the office and bedroom of a residential building. The results obtained show a high (75–93%) yield of air purification from particulate matter. Particulate matters fractions such as: PM1, PM2.5, PM4.0, PM10 and total suspended particulates (TSP) were analysed by means professional dust meter. A very strong correlation of particulate matter (PM) contents were found in individual particle classes during equipment operation. Obtained results approve high efficiency of equipment operation in the total range of measured values. This study is one of the first in the topic of assessing the effectiveness of PM purification, taking into account various dust fractions. This study should be useful for individual customers and for public utilities during purchase decisions.