Enhancing the peroxidase-like activity of MIL-88B by ligand exchange with polydopamine

Metal-organic framework (MOF) as nanozymes has been widely used in biosensing. However, MOF has inherent defects of easy agglomeration, leading to stacking of active surfaces. In addition, the low conductivity...

Constructing a method for assessing the effectiveness of using protective barriers near highways to decrease the level of air pollution

Highways are an intensive source of environmental pollution. Atmospheric air is exposed to the fastest anthropogenic influence. Therefore, a particularly important task is to minimize the level of air pollution near the highway. An effective method for solving this problem is the use of protective barriers of various shapes installed near highways. At the stage of designing these protective structures, an important task arises to assess their effectiveness. Estimation of the effectiveness of protective barriers by the method of the physical experiment takes considerable time to set up and conduct an experiment, as well as analyze the results of physical modeling. This method is not always convenient during design work. An alternative method is the method of mathematical modeling. For the designer, it is very important to have mathematical models that make it possible to quickly obtain a predictive result and take into consideration a set of important factors on which the effectiveness of the protective barrier depends. A method has been devised that makes it possible to assess the effectiveness of using protective barriers to reduce the level of air pollution near the highway. It was found that an increase in barrier height by 80 % leads to a 22 % decrease in the concentration of impurities behind the barrier. It was established that applying a barrier with a height of 1.5 m leads to a 26 % decrease in the concentration of impurities in buildings adjacent to the highway. A method has been devised to assess the effectiveness of using absorbent "TX Active" surfaces on the protective barrier located near the highway. This study's result revealed that the application of a barrier with one "TX Active" surface leads to a decrease in the concentration of NO behind the barrier by an average of 43 %. When using a barrier with two "TX Active" surfaces, a decrease in the NO concentration behind the barrier is 85 % on average

Lagrangian mechanics of active systems

We present a multi-scale modeling and simulation framework for low-Reynolds number hydrodynamics of shape-changing immersed objects, e.g., biological microswimmers and active surfaces. The key idea is to consider principal shape changes as generalized coordinates and define conjugate generalized hydrodynamic friction forces. Conveniently, the corresponding generalized friction coefficients can be pre-computed and subsequently reused to solve dynamic equations of motion fast. This framework extends Lagrangian mechanics of dissipative systems to active surfaces and active microswimmers, whose shape dynamics is driven by internal forces. As an application case, we predict in-phase and anti-phase synchronization in pairs of cilia for an experimentally measured cilia beat pattern. Graphic Abstract

PtNiFe Nanoalloys with Co-existence of Energy-optimized Active surfaces for Synergistic Catalysis of Oxygen Reduction and Evolution

Platinum nanocatalysts mediated by 3d transition metals show improved activity for oxygen reduction reaction (ORR) but poor activity for oxygen evolution reaction (OER). Herein, we report the preparation of a...