A Novel Graphite-Based Sorbent for Oil Spill Cleanup

The performance of an innovative material based on expanded graphite, Grafysorber® G+ (Directa Plus), has been tested through laboratory, tank, and confinement tests for oil removal in case of an oil spill and water treatment. In addition to the ability to retain oil, the possibility of reusing this material after regeneration via squeezing was also evaluated. As a comparison, the same experimental tests were conducted using polypropylene flakes (PP), the material currently most used to deal with spill accidents. Oils with different chemical and physical properties were used, namely kerosene, diesel, and crude oil. From the laboratory tests, the capacity of Grafysorber® G+ to retain oil was found to be directly proportional to the viscosity of the latter, with adsorption values ranging from 76.8 g/g for diesel to 50.8 g/g for kerosene, confirming the potential of the innovative material compared to the PP. Cyclical use tests have confirmed certain reusability of the material, even if its adsorbent capacity decreases significantly after the first cycle and continues to decrease in subsequent cycles, but a less marked manner. Finally, some considerations based on the adsorption capacities were found to suggest that the adoption of the new material is also economically preferable, resulting in savings of 20 to 40% per kg of hydrocarbon treated.

Bio-Inspired Hierarchical Carbon Nanotube Yarn with Ester Bond Cross-Linkages towards High Conductivity for Multifunctional Applications

The cross-linked hierarchical structure in biological systems provides insight into the development of innovative material structures. Specifically, the sarcoplasmic reticulum muscle is able to transmit electrical impulses in skeletal muscle due to its cross-linked hierarchical tubular cell structure. Inspired by the cross-linked tubular cell structure, we designed and built chemical cross-links between the carbon nanotubes within the carbon nanotube yarn (CNT yarn) structure by an esterification reaction. Consequently, compared with the pristine CNT yarn, its electrical conductivity dramatically enhanced 348%, from 557 S/cm to 1950 S/cm. Furthermore, when applied with three voltages, the electro-thermal temperature of esterified CNT yarn reached 261 °C, much higher than that of pristine CNT yarn (175 °C). In addition, the esterified CNT yarn exhibits a linear and stable piezo-resistive response, with a 158% enhanced gauge factor (the ratio of electrical resistance changing to strain change ~1.9). The superconductivity, flexibility, and stable sensitivity of the esterified flexible CNT yarn demonstrate its great potential in the applications of intelligent devices, smart clothing, or other advanced composites.

Impact of Methanol Concentration on Properties of Ultra-Nanocrystalline Diamond Films Grown by Hot-Filament Chemical Vapour Deposition

Diamond is a very interesting material with a wide range of properties, making it highly applicable, for example, in power electronics, chemo- and biosensors, tools’ coatings, and heaters. Due to the high demand for this innovative material based on the properties it is already expected to have, it is important to obtain homogeneous diamond layers for specific applications. Doping is often chosen to modify the properties of layers. However, there is an alternative way to achieve this goal and it is shown in this publication. The presented research results reveal that the change in methanol content during the Hot Filament Chemical Vapour Deposition (HF CVD) process is a sufficient factor to tune the properties of deposited layers. This was confirmed by analysing the properties of the obtained layers, which were determined using Raman spectroscopy, scanning electron microscopy (SEM), X-ray diffraction (XRD), and an atomic force microscope (AFM), and the results were correlated with those of X-ray photoelectron spectroscopy (XPS). The results showed that the increasing of the concentration of methanol resulted in a slight decrease in the sp3 phase content. At the same time, the concentration of the -H, -OH, and =O groups increased with the increasing of the methanol concentration. This affirmed that by changing the content of methanol, it is possible to obtain layers with different properties.

Economic Evaluation of Cement Grouted Bituminous Mixes for Airport Pavements

The Cement Grouted Bituminous Mix (CGBM) is an innovative material that could be used to build airport pavements subjected to heavy concentrated loads or fuel and solvent leaks. CGBM is composed of a porous asphalt clogged with an expansive cement mixture, which fills the asphalt voids. This paper focuses on two airport pavements (i.e., a taxiway and a helipad one) to be paved in an Italian airport. For each surface, the construction and maintenance costs of a CGBM pavement and a traditional flexible pavement have been compared. The pavements should bear different traffic loads, while the weather, subgrade, and materials are the same: the fatigue and rutting verification gives structures whose cost analysis leads to different results. The CGBM solution for the taxiway has a cost comparable to that of the equivalent traditional flexible pavement (i.e., 73.87 €/m2 vs. 73.20 €/m2 during the service life). On the other hand, the overall discounted cost of the helipad surface paved with CGBM is higher than that obtained for the traditional pavement (i.e., 82.4 €/m2 vs. 67.5 €/m2). Therefore, the study demonstrates that the economic opportunity of CGBM solutions strongly depends on traffic loads.

Domestic and foreign experience of antimonopoly regulation of the food market in the context of economic globalization

The globalization of the economy creates new opportunities for the formation of global food supply chains as a new type of infrastructure, which requires improved antitrust regulation of global food markets. The purpose of this work is to identify trends in the system of antimonopoly regulation of the food market in the context of globalization based on the systematization of the most important research results of foreign and domestic authors and the practice of competition authorities. The work uses the methods of a systematic approach, logical-structural analysis. The study is based on the provisions and conclusions of modern theories of the foundations of competition, competitive advantage. Information and analytical materials of the Federal Antimonopoly Service play an important role in the work. Results. The content of changes in the contours of global food supply chains is revealed, which manifests itself in the complication of the chain around leading large retailers; active education in the chain of new technology companies; improving chain management processes, leading to lower costs. The analysis of theoretical views on antitrust regulation of global food supply chains is carried out, which makes it possible to identify a number of fundamental provisions on which the activities of competition authorities should be based - to stimulate the competitive behavior of participants in the chain. An assessment of the practice of antimonopoly regulation of global food supply chains in a number of countries is given, focusing on a detailed analysis of all links of the chain, identifying constraints on the development of competition in the segments of the chain. The dynamics of the main indicators of the activities of FAS Russia in the food market is presented, indicating an increase in the identified violations in this economy. Attention is focused on new mechanisms for ensuring competition through the technological transfer of innovative material to Russian companies to enhance their competitiveness. Scientific novelty. The trends and features of the development of global food supply chains are identified based on the identification of specific factors in the context of globalization. Some principles of state antimonopoly control of global food supply chains have been formed, which makes it possible to improve the practice of their regulation.

American tulipwood (Liriodendron tulipifera L.) as an innovative material in CLT technology

American tulipwood (Liriodendron tulipifera L.) as an innovative material in CLT technology. CLT (cross laminated timber, X-Lam) is one type of engineered wood products. The first idea of CLT was presented in the seventies of the last century. It is manufactured with timber boards placed side by side commonly with 3, 5 and 7 layers glued at 90 degrees to adjacent layer. The CLT production technology was developed for softwood. The main species in CLT production is Norway spruce (Picea abies L.) and less often White fir (Abies alba Mill.). Hardwood is also used more and more for production of CLT, most often, the wood of Silver birch (Betula pendula Roth.), Ash (Fraxinus excelsior L.), poplars (Populus spp.), Locust tree (Robinia pseudoacacia L.). This paper describes the suitability of cheap tulipwood (Liriodendron tulipifera L.) as a raw material for the production of CLT. Examples of the use of this type of panels in construction are also presented. The tulipwood has similar physical characteristics to softwood, for which CLT production technologies were previously developed. This makes it possible to use the technology previously for softwood CLT was developed. In addition, the tulipwood is characterized by aesthetic visual quality (wood surface similar to marble). Thanks to this, CLT boards to make exposed surfaces can be used.

Recent Advances in Design and Preparation of Polymer-Based Thermal Management Material

The boosting of consumer electronics and 5G technology cause the continuous increment of the power density of electronic devices and lead to inevitable overheating problems, which reduces the operation efficiency and shortens the service life of electronic devices. Therefore, it is the primary task and a prerequisite to explore innovative material for meeting the requirement of high heat dissipation performance. In comparison with traditional thermal management material (e.g., ceramics and metals), the polymer-based thermal management material exhibit excellent mechanical, electrical insulation, chemical resistance and processing properties, and therefore is considered to be the most promising candidate to solve the heat dissipation problem. In this review, we summarized the recent advances of two typical polymer-based thermal management material including thermal-conduction thermal management material and thermal-storage thermal management material. Furtherly, the structural design, processing strategies and typical applications for two polymer-based thermal management materials were discussed. Finally, we proposed the challenges and prospects of the polymer-based thermal management material. This work presents new perspectives to develop advanced processing approaches and construction high-performance polymer-based thermal management material.

3D Puzzle in Cube Pattern for Anisotropic/Isotropic Mechanical Control of Structure Fabricated by Metal Additive Manufacturing

Metal additive manufacturing is a powerful tool for providing the desired functional performance through a three-dimensional (3D) structural design. Among the material functions, anisotropic mechanical properties are indispensable for enabling the capabilities of structural materials for living tissues. For biomedical materials to replace bone function, it is necessary to provide an anisotropic mechanical property that mimics that of bones. For desired control of the mechanical performance of the materials, we propose a novel 3D puzzle structure with cube-shaped parts comprising 27 (3 × 3 × 3) unit compartments. We designed and fabricated a Co–Cr–Mo composite structure through spatial control of the positional arrangement of powder/solid parts using the laser powder bed fusion (L-PBF) method. The mechanical function of the fabricated structure can be predicted using the rule of mixtures based on the arrangement pattern of each part. The solid parts in the cubic structure were obtained by melting and solidifying the metal powder with a laser, while the powder parts were obtained through the remaining nonmelted powders inside the structure. This is the first report to achieve an innovative material design that can provide an anisotropic Young’s modulus by arranging the powder and solid parts using additive manufacturing technology.

Preliminary hemocompatibility assessment of an innovative material for blood contacting surfaces

Over the years, several devices have been created (and the development of many others is currently in progress) to be in permanent contact with blood: mechanical circulatory supports represent an example thereof. The hemocompatibility of these devices largely depends on the chemical composition of blood-contacting components. In the present work, an innovative material (hybrid membrane) is proposed to fabricate the inner surfaces of a pulsatile ventricular chamber: it has been obtained by coupling a synthetic polymer (e.g., commercial polycarbonate urethane) with decellularized porcine pericardium. The hemocompatibility of the innovative material has been preliminarily assessed by measuring its capacity to promote thrombin generation and induce platelet activation. Our results demonstrated the blood compatibility of the proposed hybrid membrane.

DERIVATION OF MOTIVATORS FOR THE USE OF ALUMINUM FOAM SANDWICH AND ADVANTAGEOUS APPLICATIONS

Aluminum foam sandwich (AFS) is an innovative material combination for designing lighter products and has many advantages such as a high bending stiffness at a low density and good energy absorption properties. Although the material is ready for series production, the number of industrial applications is low because of the high costs of the material, a lack of design knowledge and missing reference applications. This paper focuses on the aspect of missing reference applications and how to improve this situation in order to give designers an idea of where the material could be used profitably and to provide the basis for a selection method. Therefore, a systematic literature review is carried out to identify profitable applications with their respective advantages. As a main result, a set of motivators for the use of aluminum foam sandwich is developed, which will support the designer in evaluating the potential use of aluminum foam sandwich.