Give Me a Few Hours: Exploring Short Timescales in Rubin Observatory Cadence Simulations

The limiting temporal resolution of a time-domain survey in detecting transient behavior is set by the time between observations of the same sky area. We analyze the distribution of visit separations for a range of Vera C. Rubin Observatory cadence simulations. Simulations from families v1.5–v1.7.1 are strongly peaked at the 22 minute visit pair separation and provide effectively no constraint on temporal evolution within the night. This choice will necessarily prevent Rubin from discovering a wide range of astrophysical phenomena in time to trigger rapid follow-up. We present a science-agnostic metric to supplement detailed simulations of fast-evolving transients and variables and suggest potential approaches for improving the range of timescales explored.

Hydrogen evolution via noble metals based photocatalysts: A review

In recent decades, the use of photocatalysts in the evolution of hydrogen (H2) has received much attention. However, the use of the well-known titanium oxide and another photocatalyst as a base for noble metals is limited due to their major weakness in electron-hole pair separation. The use of cocatalysts can be a good way to overcome this problem and provide better performance for the evolution of hydrogen. In this review, suitable high-efficiency cocatalysts for solar hydrogen production have been thoroughly reviewed. New strategies and solutions were examined in terms of increasing the recombination of charge carriers, designing reactive sites, and enhancing the wavelengths of light absorption. Several new types of cocatalysts based on semiconductors in noble groups and dual metals have been evaluated. It is expected that these photocatalysts will be able to reduce the activation energy of reaction and charge separation. In this regard, the existing views and challenges in the field of photocatalysts are presented. The characteristics of monoatomic photocatalysts are reviewed in this manuscript and the latest advances in this field are summarized. Further, the future trends and upcoming research are also briefly discussed. Finally, this review presents noble metal-based photocatalysts for providing suitable photocatalysts on a larger scale and improving their applicability.

Structural and dynamical properties of 13-atom Cu–Co mixed clusters

In this paper, the geometric structures and the melting-like processes of the 13-atom pure copper, pure cobalt cluster and their 13-atom mixed clusters are investigated and compared by the molecular dynamics method. The calculation shows that the pure copper and cobalt clusters have the standard icosahedral structures and the mixed clusters take on the deformed icosahedral structures. The quantitative analysis shows that the deformations are slight. Moreover, an element similarity function is introduced by which the contribution of the compositions of the clusters to the deformation of the mixed clusters is analyzed and discussed. With the increase of the temperature, the migrating and recombination of the atoms on the surface of the clusters are observed, indicating the starting of the transition from solid-like to liquid-like state for the clusters. Through the calculating of the relative root-mean-squared pair separation fluctuation and monitoring the dynamical structures of the clusters, it is found that the mixed clusters experience a multi-step process in the transition.

Relative dispersion with finite inertial ranges

Relative dispersion experiments are often analysed using theoretical predictions from two- and three-dimensional turbulence. These apply to infinite inertial ranges, assuming the same dispersive behaviour over all scales. With finite inertial ranges, the metrics are less conclusive. We examine this using pair separation probability density functions (PDFs), obtained by integrating a Fokker–Planck equation with different diffusivity profiles. We consider time-based metrics, such as the relative dispersion, and separation-based metrics, such as the finite scale Lyapunov exponent (FSLE). As the latter cannot be calculated from a PDF, we introduce a new measure, the cumulative inverse separation time (CIST), which can. This behaves like the FSLE, but advantageously has analytical solutions in the inertial ranges. This allows the establishment of consistency between the time- and space-based metrics, something which has been lacking previously. We focus on three dispersion regimes: non-local spreading (as in a two-dimensional enstrophy inertial range), Richardson dispersion (as in an energy inertial range) and diffusion (for uncorrelated pair motion). The time-based metrics are more successful with non-local dispersion, as the corresponding PDF applies from the initial time. Richardson dispersion is barely observed, because the self-similar PDF applies only asymptotically in time. In contrast, the separation-based CIST correctly captures the dependencies, even with a short (one decade) inertial range, and is superior to the traditional FSLE at large scales. Nevertheless, it is advantageous to use all measures together, to seek consistent indications of the dispersion.

A Catalog of 204 Offset and Dual Active Galactic Nuclei (AGNs): Increased AGN Activation in Major Mergers and Separations under 4 kpc

During galaxy mergers, gas and dust are driven toward the centers of merging galaxies, triggering enhanced star formation and supermassive black hole (SMBH) growth. Theory predicts that this heightened activity peaks at SMBH separations <20 kpc; if sufficient material accretes onto one or both of the SMBHs for them to become observable as active galactic nuclei (AGNs) during this phase, they are known as offset and dual AGNs, respectively. To better study these systems, we have built the ACS-AGN Merger Catalog, a large catalog (N = 204) of uniformly selected offset and dual AGN observed by the Hubble Space Telescope at 0.2 < z < 2.5 with separations <20 kpc. Using this catalog, we answer many questions regarding SMBH−galaxy coevolution during mergers. First, we confirm predictions that the AGN fraction peaks at SMBH pair separations <10 kpc; specifically, we find that the fraction increases significantly at pair separations of <4 kpc. Second, we find that AGNs in mergers are preferentially found in major mergers and that the fraction of AGNs found in mergers follows a logarithmic relation, decreasing as merger mass ratio increases. Third, we do not find that mergers (nor the major or minor merger subpopulations) trigger the most luminous AGNs. Finally, we find that nuclear column density, AGN luminosity, and host galaxy star formation rate have no dependence on SMBH pair separation or merger mass ratio in these systems, nor do the distributions of these values differ significantly from that of the overall AGN population.

Nanostructure Engineering via Intramolecular Construction of Carbon Nitride as Efficient Photocatalyst for CO2 Reduction

Light-driven heterogeneous photocatalysis has gained great significance for generating solar fuel; the challenging charge separation process and sluggish surface catalytic reactions significantly restrict the progress of solar energy conversion using a semiconductor photocatalyst. Herein, we propose a novel and feasible strategy to incorporate dihydroxy benzene (DHB) as a conjugated monomer within the framework of urea containing CN (CNU-DHBx) to tune the electronic conductivity and charge separation due to the aromaticity of the benzene ring, which acts as an electron-donating species. Systematic characterizations such as SPV, PL, XPS, DRS, and TRPL demonstrated that the incorporation of the DHB monomer greatly enhanced the photocatalytic CO2 reduction of CN due to the enhanced charge separation and modulation of the ionic mobility. The significantly enhanced photocatalytic activity of CNU–DHB15.0 in comparison with parental CN was 85 µmol/h for CO and 19.92 µmol/h of the H2 source. It can be attributed to the electron–hole pair separation and enhance the optical adsorption due to the presence of DHB. Furthermore, this remarkable modification affected the chemical composition, bandgap, and surface area, encouraging the controlled detachment of light-produced photons and making it the ideal choice for CO2 photoreduction. Our research findings potentially offer a solution for tuning complex charge separation and catalytic reactions in photocatalysis that could practically lead to the generation of artificial photocatalysts for efficient solar energy into chemical energy conversion.

The Ion Pair Thermal Model of MALDI MS

The ion pair thermal model for MALDI MS is described. Key elements of the model include thermal desorption and ionization, strong tendency to neutralization via ion pair formation and proton transfer in the gas phase, thermal equilibrium, overall charge neutral plume, and thermal energy assisted free ion generation via ion pair separation by ion extraction potential. The quantities of ions in the solid sample and in the gaseous plume are estimated. Ion yields of different classes of molecules including peptides, nucleic acids, permanent salts and neutral molecules are estimated at the macroscale and single ion pair levels. The estimated ion yields are close to experimentally observed values under certain assumptions. Explanations of several observations in MALDI MS such as mostly single-charged peaks, improvement of spectra by ammonium cation, and ion suppression are provided. We expect that the model can give insights for the design of new conditions and systems for improving the sensitivity and resolution of MALDI MS and improving its capability and reliability to analyze large biomolecules.

A Titania-Supported Polyoxometalate and Au Cocatalyst for Efficient Photocatalytic Environmental Remediation

Photocatalysis has been considered an effective method for environmental purification and pollutant removal, with many experiments having being performed. The sustainable development of environmentally friendly materials that can photocatalytically oxidize and degrade contaminants is widely studied. Here, we report the results of the photocatalytic oxidation of contaminants (over 99% conversion of the contaminants was achieved) on a tri-component photocatalyst by the simultaneous decoration of Au nanoparticles and a new type of Sn-substituted Keggin structure polyoxometalate (POM) on a TiO2 semiconductor (denoted as AuPT). The light absorption and the electron–hole pair separation capacity of TiO2 was significantly ameliorated on AuPT. The synergistic effect of the Au resonance energy transfer (RET) course and the POM redox transformation can be advantageous to the efficient transmission of photogenerated electrons and holes in a way that achieves efficient photocatalytic oxidation of contaminants.

New Star-Shaped Polyether-Pentols (PEPOs) for Fabrication of Crosslinked Polyurethanes—Synthesis and Characterization

Polyether-pentols (PEPOs) were synthesized from glycidyl ethers and butylene oxide with the application of tripotassium salts of 2,2,6,6-tetrakis(hydroxymethyl)cyclohexanol (HMCH) activated 18C6 for ring-opening polymerization (ROP). The construction of the applied initiator system reflects the ability of crown ether to influence the degree of ion-pair separation with an increased activating effect. As a result formation of bi- or trimodal polymers was observed with molar masses in the range of (Mn = 1200–6000). The observed multi-fraction composition is prescribed to the formation of ionic aggregates with different reactivities during polymerization. The mechanism of the studied processes is discussed. The obtained PEPOs served for a crosslinked PUR synthesis, for which the hydrogen bond index for coupling of hard segments was calculated. Additionally, the range of phase separation was calculated that was higher for PUR-containing aromatic rings as the substituent.