Laser synthesis of nanocomposite hydrocarbon fuel and CARS diagnostics of its combustion flame

We report an analysis of diffusive combustion in oxygen of a composite fuel formed by the addition of aluminium nanoparticles (NPs) to isopropanol. The process of obtaining Al NPs consisted in laser fragmentation of initially large industrial NPs using radiation of a pulsed nanosecond neodymium laser. The size distribution of Al NPs was determined using a measuring disk centrifuge. The average nanoparticle size was 20 nm, which is confirmed by transmission electron microscopy data. A diagnostic system based on coherent anti-Stokes Raman scattering (CARS) was used to experimentally study the diffusive combustion of composite fuel. The temperature distributions were measured in two mutually orthogonal directions (along the flame and in the transverse direction) in pure isopropanol and in isopropanol with the addition of 0.15 wt % of Al nanoparticles.

Study of the dependences of coal-wood composition, identification of combustion features of the obtained composite materials

In the study of the combustion of samples, it was found that, other things being equal, under the experimental conditions and with the fixed technical characteristics of the fuel, different parameters of the flame are observed, namely, the speed of reaching a stationary mode, the completeness of fuel combustion, the size and distribution of temperature zones strongly depend on the methods used to carry out the mechanical fuel processing. Comparison of the results showed that under the same experimental conditions, the temperature distribution along the length of the experimental stand, in a stationary mode of operation, is higher for the composite fuel. In the case of composite fuel, 70 percent of the fuel burned up was observed at a 1 m section, which is indicative of these fuel consumption and kindling processes at industrial thermal power plants.

Study of synthesis and combustion of composite fuels based on n-decane and Al nanoparticles

The article is devoted to the analysis of a diffusion combustion of a composite fuel (formed by an addition of non-oxidized aluminum (Al) nanoparticles (NP’s) to n-decane) with oxygen. The process of obtaining Al NP’s consisted of a laser fragmentation of initially large commercially produced NP’s (so called “Alex” with mean diameter is about 450 nm) in the solution of isopropanol. A final size distribution of NP’s was determined by a CPS DC2400 measuring disk centrifuge. The morphology of NP’s was characterized with the Transmission Electron Microscope (TEM) JEM-100C. The measured average diameter of NP’s was about 40 nm. In the final step of a preparation of a composite fuel an isopropanol was exchanged on n-decane. To characterize the composite fuel, diffusion combustion was used in combination with the laser diagnostic technique CARS. Temperature distributions along the x direction were measured at two values of distances from the nozzle. It has been shown that, for the fuel consistent of 0.1% mass concentration of Al NP’s in n-decane, the temperature at the distance equaled 14 mm downstream from the nozzle exit of a burner in the vicinity of the flame front was significantly higher (by 200–300 K) than that upon burning of pure n-decane.

RELATED REGULATION OF BIOGAS SUPPLIES AND METHANE IN A GAS ENGINE

The results of experimental researches were received on a gas-electric installation with a rated power of 30 kW at 1500 rpm. The spark-ignited petrol drive engine (8-cylinder, 100 mm cylinder diameter, 88 mm stroke) was converted to a pure gas one. The compression ratio of 8.5 did not change. The gas fuel supply system consists of a supply line and an emergency shut-off circuit. The natural gas supply line was connected to the domestic main line through a special gas distributor. On the basis of HEINZMANN components, a system for dosing mixed gas fuel was developed, which, through a microprocessor control unit and an actuator, acted on the throttle valve of the gas mixer. In experimental researches, the composite fuel was a model gas – a mixture of natural and carbon dioxide gases, which was prepared in a zero pressure reducer before the gas mixer. With an increase in the volume fraction of carbon dioxide in the model gas by more than 34 %, a deterioration of the combustion process was observed in the steady state. In the article, based on the analysis of the experimental results of the operation of a piston gas engine on a model gas, an algorithm for the use of associated automatic control of biogas and methane feeds is substantiated. The transition from quantitative to qualitative regulation of the gas-air mixture has been substantiated. To do this, it is necessary to create two automatic control loops for the supply of air and a mixture of natural gas, which are interconnected through an external load. With the developed algorithm, as the load increases, the supply of natural gas increases, and the supply of biogas decreases. With an increase in the load of 75 % or more, a more intensive enrichment of the fuel mixture with natural gas occurs than at low and medium loads. The proposed algorithm for regulating the fuel mixture can be implemented using electromagnetic gas injectors for dosing the components of the composite fuel. Signals from sensors for oxygen and methane content in exhaust gases were selected as corrective links for the coupled control algorithm. Recommendations on the choice of tuning modes for oxygen and methane sensors have been developed.

Effect of Metal Nanopowders on the Performance of Solid Rocket Propellants: A Review

The effects of different types of nano-sized metal particles, such as aluminum (nAl), zirconium (nZr), titanium (nTi), and nickel (nNi), on the properties of a variety of solid rocket propellants (composite, fuel-rich, and composite modified double base (CMDB)) were analyzed and compared with those of propellants loaded with micro-sized Al (mAl) powder. Emphasis was placed on the investigation of burning rate, pressure exponent (n), and hazardous properties, which control whether a propellant can be adopted in solid rocket motors. It was found that nano-sized additives can affect the combustion behavior and increase the burning rate of propellants. Compared with the corresponding micro-sized ones, the nano-sized particles promote higher impact sensitivity and friction sensitivity. In this paper, 101 references are enclosed.