Oxygen and magnesium mass-independent isotopic fractionation induced by chemical reactions in plasma

Enrichment or depletion ranging from −40 to +100% in the major isotopes 16O and 24Mg were observed experimentally in solids condensed from carbonaceous plasma composed of CO2/MgCl2/Pentanol or N2O/Pentanol for O and MgCl2/Pentanol for Mg. In NanoSims imaging, isotope effects appear as micrometer-size hotspots embedded in a carbonaceous matrix showing no isotope fractionation. For Mg, these hotspots are localized in carbonaceous grains, which show positive and negative isotopic effects so that the whole grain has a standard isotope composition. For O, no specific structure was observed at hotspot locations. These results suggest that MIF (mass-independent fractionation) effects can be induced by chemical reactions taking place in plasma. The close agreement between the slopes of the linear correlations observed between δ25Mg versus δ26Mg and between δ17O versus δ18O and the slopes calculated using the empirical MIF factor η discovered in ozone [M. H. Thiemens, J. E. Heidenreich, III. Science 219, 1073–1075; C. Janssen, J. Guenther, K. Mauersberger, D. Krankowsky. Phys. Chem. Chem. Phys. 3, 4718–4721] attests to the ubiquity of this process. Although the chemical reactants used in the present experiments cannot be directly transposed to the protosolar nebula, a similar MIF mechanism is proposed for oxygen isotopes: at high temperature, at the surface of grains, a mass-independent isotope exchange could have taken place between condensing oxides and oxygen atoms originated form the dissociation of CO or H2O gas.

The role of ice lines in the formation of Uranus and Neptune

We aim at investigating whether the chemical composition of the outer region of the protosolar nebula can be consistent with current estimates of the elemental abundances in the ice giants. To do so, we use a self-consistent evolutionary disc and transport model to investigate the time and radial distributions of H 2 O, CO, CO 2 , CH 3 OH, CH 4 , N 2 and H 2 S, i.e. the main O-, C-, N and S-bearing volatiles in the outer disc. We show that it is impossible to accrete a mixture composed of gas and solids from the disc with a C/H ratio presenting enrichments comparable to the measurements (approx. 70 times protosolar). We also find that the C/N and C/S ratios measured in Uranus and Neptune are compatible with those acquired by building blocks agglomerated from solids condensed in the 10–20 AU region of the protosolar nebula. By contrast, the presence of protosolar C/N and C/S ratios in Uranus and Neptune would imply that their building blocks agglomerated from particles condensed at larger heliocentric distances. Our study outlines the importance of measuring the elemental abundances in the ice giant atmospheres, as they can be used to trace the planetary formation location, the origin of their building blocks and/or the chemical and physical conditions of the protosolar nebula. This article is part of a discussion meeting issue ‘Future exploration of ice giant systems’.

Carbon-grain sublimation: a new top-down component to protostellar chemistry

<p>One of the main goals in the fields of exoplanets and planet formation is to determine the composition of terrestrial, potentially habitable, planets and to link this to the composition of protoplanetary disks. A longstanding puzzle in this regard is the Earth's severe carbon deficit; Earth is 2-4 orders of magnitude depleted in carbon compared to interstellar grains and comets. The solution to this conundrum is that carbon must have been returned to the gas phase in the inner protosolar nebula, such that it could not get accreted onto the forming bodies. A process that could be responsible is the sublimation of carbon grains at the so-called soot line (~300 K) early in the planet-formation process. I will argue that the most likely signatures of this process are an excess of hydrocarbons and nitriles inside the soot line around protostars, and a higher excitation temperature for these molecules compared to oxygen-bearing complex organics that desorb around the water snowline (~100 K). Moreover, I will show that such characteristics have indeed been reported in the literature, for example, in Orion KL, although not uniformly, potentially due to differences in observational settings or related to the episodic nature of protostellar accretion. If this process is active, this would mean that there is an heretofore unrecognized component to the carbon chemistry during the protostellar phase that is acting from the top down - starting from the destruction of larger species - instead of from the bottom up from atoms. In the presence of such a top-down component, the origin of organic molecules needs to be re-explored. </p>

Ice lines and the formation of Uranus and Neptune

<p>We aim at investigating whether the chemical composition of the outer region of the protosolar nebula can be consistent with current estimates of the elemental abundances in the ice giants. To do so, we use a self-consistent evolutionary disc and transport model to investigate the time and radial distributions of H<sub>2</sub>O, CO, N<sub>2</sub>, and H<sub>2</sub>S, i.e., the main O-, C-, N, and S-bearing volatiles in the outer disc. We show that it is impossible to accrete a mixture composed of gas and solids from the disc with a C/H ratio presenting enrichments comparable to the measurements (70 times protosolar). We also find that the C/N and C/S ratios measured in Uranus and Neptune are compatible with those acquired by building blocks agglomerated from grains and pebbles condensed in the vicinities of N<sub>2</sub> and CO ice lines in the nebula. In contrast, the presence of protosolar C/N and C/S ratios in Uranus and Neptune would imply that their building blocks agglomerated from particles condensed at higher heliocentric distances. Our study demonstrates the importance of measuring the elemental abundances in the ice giant atmospheres, as they can be used to trace the planetary formation location and/or the chemical and physical conditions of the protosolar nebula.<span class="Apple-converted-space"> </span></p>

Rocklines of high temperature minerals in the protosolar nebula

<p>In our solar system, terrestrial planets and meteoritical matter exhibit various bulk compositions. To understand this variety of compositions, formation mechanisms of meteorites are usually investigated via a thermodynamic approach that neglect the processes of transport throughout the protosolar nebula. Here, we investigate the role played by rocklines (condensation/sublimation lines of refractory materials) in the innermost regions of the protosolar nebula to compute the composition of particles migrating inward the disk as a function of time. To do so, we utilize a one-dimensional  accretion disk model with a prescription for dust and vapor transport, sublimation and recondensation of refractory materials (ferrosilite, enstatite, fayalite, forsterite, iron sulfur, kamacite and nickel). We find that the diversity of the bulk composition of cosmic spherules can be explained by their formation close to rocklines, suggesting that solid matter is concentrated in the vicinity of these sublimation/condensation fronts. Although our model relies a lot on the number of considered species and the availability of thermodynamic data governing state change, it suggests that rocklines played a major role in the formation of small and large bodies in the innermost regions of the protosolar nebula. The results of our model are consistent with the composition of chondrules and cosmic spherules. Our model gives insights on the mechanisms that might have contributed to the formation of Mercury's large core.</p>

Identification of chondritic krypton and xenon in Yellowstone gases and the timing of terrestrial volatile accretion

Identifying the origin of noble gases in Earth’s mantle can provide crucial constraints on the source and timing of volatile (C, N, H2O, noble gases, etc.) delivery to Earth. It remains unclear whether the early Earth was able to directly capture and retain volatiles throughout accretion or whether it accreted anhydrously and subsequently acquired volatiles through later additions of chondritic material. Here, we report high-precision noble gas isotopic data from volcanic gases emanating from, in and around, the Yellowstone caldera (Wyoming, United States). We show that the He and Ne isotopic and elemental signatures of the Yellowstone gas requires an input from an undegassed mantle plume. Coupled with the distinct ratio of129Xe to primordial Xe isotopes in Yellowstone compared with mid-ocean ridge basalt (MORB) samples, this confirms that the deep plume and shallow MORB mantles have remained distinct from one another for the majority of Earth’s history. Krypton and xenon isotopes in the Yellowstone mantle plume are found to be chondritic in origin, similar to the MORB source mantle. This is in contrast with the origin of neon in the mantle, which exhibits an isotopic dichotomy between solar plume and chondritic MORB mantle sources. The co-occurrence of solar and chondritic noble gases in the deep mantle is thought to reflect the heterogeneous nature of Earth’s volatile accretion during the lifetime of the protosolar nebula. It notably implies that the Earth was able to retain its chondritic volatiles since its earliest stages of accretion, and not only through late additions.