Abstract
Textile effluents containing synthetic refractory azo dyes are one of the most important sources of water pollution. However, these kinds of refractory organic pollutants were resistless to a persulfate (PS) oxidation process which was proper activated. In this study, PS was activated by ferrous sulfide (FeS) in a heterogeneous system to decompose azo dyes wastewater. The results showed that all five selected azo dyes were efficiently decomposed by the PS/FeS system, except DY 12, more than 95% of azo dyes were decolored within 60 minutes. The decolorization efficiency of DR 81 in PS/FeS system was comparable to PS activated with heat (60 °C) or Fe2+, and was slightly superior to Fe0 powders under the same conditions. The quenching studies indicated that both SO4−• and •OH were formed in the FeS surface and diffused into the solution to facilitate the successive transformation of DR 81, and •OH reacted with DR 81 might the crucial reaction. The coexisted chelating agents in real azo dyes effluents with high concentration had negative influence on azo dyes decolorization by PS/FeS. However, the superiority of the PS/FeS system was the regenerability and reusability of the heterogeneous catalyst.