Characterization of Electrical Parameters of Copper Phthalocyanine Based Organic Electronic Device in Presence of Fullerene Nanoparticles

Characterization of electrical parameters of Copper Phthalocyanine dye has been done in the present work. In the context of electrical parameters, the Schottky barrier and ideality factor of the organic device has been measured and the effects of fullerene nanoparticles on these parameters have been studied. Analysis of electrical parameters has been done by the current-voltage characteristics of the device. The influence of fullerene nanoparticles lessens the Schottky barrier to 0.71 eV from 0.75 eV. The current flow is assumed to be injection limited as the Schottky barrier is greater than 0.3 eV - 0.4 eV. The Schottky barrier is also estimated by the Norde method. Norde's method shows lessening of barrier height from 0.70 eV to 0.65 eV under the influence of fullerene nanoparticles. The measured ideality factor value reduces from 3.787 to 1.495 in presence of fullerene nanoparticles. The charge injection mechanism at metal-organic contact gets influenced by the interfacial Schottky barrier height. Decrease in both Schottky barrier and ideality factor attribute to the increase in charge flow and it allows a reduction in the device’s transition voltage from 2.5 V to 1.0 V.

Study on Dispersion Stability and Friction Characteristics of C60 Nanomicrosphere Lubricating Additives for Improving Cutting Conditions in Manufacturing Process

Antifriction lubrication is an important research hotspot in the manufacturing field. A high-performance lubricating additive is of great significance for condition monitoring in the metal cutting process system. To improve cutting conditions in manufacturing process, we study the dispersion stability and tribological properties of fullerene nanoparticles in HM32 antiwear lubricating fluid. Fullerene nanoparticles are fully integrated into HM32 antiwear lubricating fluid by electromagnetic stirring and ultrasonic oscillation. The dispersion stability of fullerene nanoparticles in HM32 antiwear lubricating fluid was comprehensively studied by microscope scanning experiment, static sedimentation experiment, and absorption experiment. The four-ball friction experiment was operated to investigate the extreme pressure property and tribological property of lubricating fluids with fullerene concentration ranging from 100 ppm to 1000 ppm. The results show that fullerene nanoparticle can significantly improve the extreme pressure property and wear resistance of HM32 basic lubricating fluid. Meanwhile, we found that an excessively high concentration of fullerene nanoparticles will increase the friction and wear of the four-ball friction pair. The best concentration of fullerene nanoparticles is 200 ppm. When the fullerene concentration reaches 200 ppm, the maximum nonsintering load is significantly increased, and the friction coefficient and the steel ball wear scar diameter are significantly reduced.

Metabolomic Characterizations of Fullerene Nanomaterials Potentiate Muscle of Clownfish (Amphiprion Ocellaris)

Fullerene nanomaterials exposure often causes a variety of diseases. Many studies have pointed out that fullerene nanomaterials can be studied in fish. However, there are few studies on health risk assessment of clownfish with lower doses of fullerene nanoparticles or different exposure durations. In this study, we set 1.5% and 3.0% for low- and high-dose fullerene nanomaterials exposure concentrations, respectively. Meanwhile, we performed a time-series analysis to investigate that the activation of lipid and amino acids metabolism after fullerene nanomaterials exposure in clownfish. 1368 metabolites were detected from clownfish by using liquid chromatography-mass spectrometry (LC-MS) analyses. Our results suggest that exposure to lower fullerenes nanoparticles may have a certain promoting effect on clownfish overall length, body length and weight. At the same time, the activation of potential metabolic pathways enriched by different metabolites in KEGG pathway may also indicate the positive promoting effect of fullerene nanoparticles after exposure. The present work indicates that it is particularly important to find the concentration window for fullerene nanomaterials to improve government safety guidelines, especially when these are applied to assess the health risk of human.

Antitumor Activity and Potential Mechanism of Novel Fullerene Derivative Nanoparticles

The development of novel nanoparticles as a new generation therapeutic drug platform is an active field of chemistry and cancer research. In recent years, fullerene nanoparticles have received extensive attention due to their unique physical and chemical properties. Properly modified fullerene nanoparticles have excellent biocompatibility and significant anti-tumor activity, which makes them have broad application prospects in the field of cancer therapy. Therefore, understanding the anti-tumor mechanism of fullerene nanoparticles is of great significance for the design and development of anti-tumor drugs with low toxicity and high targeting. This review has focused on various anti-tumor mechanisms of fullerene derivatives and discusses their toxicity and their distribution in organisms. Finally, the review points out some urgent problems that need solution before fullerene derivatives as a new generation of anti-tumor nano-drug platform enter clinical research.

Oxidation Stability of Natural Ester Modified by Means of Fullerene Nanoparticles

Increasing environmental demands influence the requirements for devices and materials used in the power industry. One example is a power transformer and an electro-insulating liquid used in it. In order to meet these requirements, electro-insulating liquids should be characterized by, inter alia, high biodegradability and good fire properties. One of such liquids is natural ester. However, its oxidation stability is low in comparison to mineral oil and demands improvement, which can be achieved by the addition of an antioxidant. The authors of this work used fullerene nanoparticles for that purpose. Pure natural ester samples were prepared, and samples with two concentrations of fullerene, 250 mg/L and 500 mg/L in natural ester. All these samples were aged in a thermal oxidation process. Thereafter, the aging properties of all the samples were compared to assess the oxidation stability of modified liquids. Moreover, the electrical properties of prepared insulating liquids were investigated to assess if fullerene deteriorates these properties after aging process. Based on the obtained results, it was proved that the aging process slowed down in the case of both fullerene concentrations in ester. The acid number of natural ester modified using fullerene was lower than in the case of pure liquid.