aryl sulfide
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2021 ◽  
Vol 226 ◽  
pp. 113873
Author(s):  
Alice Legru ◽  
Federica Verdirosa ◽  
Jean-François Hernandez ◽  
Giusy Tassone ◽  
Filomena Sannio ◽  
...  

2021 ◽  
Author(s):  
Fusheng Bie ◽  
Xuejing Liu ◽  
Han Cao ◽  
Yijun Shi ◽  
Tongliang Zhou ◽  
...  
Keyword(s):  

Author(s):  
Ryota Isshiki ◽  
Miki B. Kurosawa ◽  
Kei Muto ◽  
Junichiro Yamaguchi

2021 ◽  
Author(s):  
Ryota Isshiki ◽  
Miki B. Kurosawa ◽  
Kei Muto ◽  
Junichiro Yamaguchi

A Ni-catalyzed aryl sulfide synthesis through an aryl exchange reaction between aryl sulfides and a variety of aryl electrophiles was developed. By using 2-pyridyl sulfide as a sulfide donor, this reaction achieved the synthesis of aryl sulfides without using odorous and toxic thiols. The use of a Ni/dcypt catalyst capable of cleaving and forming aryl–S bonds was important for the aryl exchange reaction between 2-pyridyl sulfides and aryl electrophiles, which include aromatic esters, arenol derivatives, and aryl halides. Mechanistic studies revealed that Ni/dcypt can simultaneously undergo oxidative additions of aryl sulfides and aromatic esters, followed by ligand exchange between the generated aryl–Ni–SR and aryl–Ni–OAr species to furnish aryl exchanged compounds.


2021 ◽  
Author(s):  
Ryota Isshiki ◽  
Miki B. Kurosawa ◽  
Kei Muto ◽  
Junichiro Yamaguchi

A Ni-catalyzed aryl sulfide synthesis through an aryl exchange reaction between aryl sulfides and a variety of aryl electrophiles was developed. By using 2-pyridyl sulfide as a sulfide donor, this reaction achieved the synthesis of aryl sulfides without using odorous and toxic thiols. The use of a Ni/dcypt catalyst capable of cleaving and forming aryl–S bonds was important for the aryl exchange reaction between 2-pyridyl sulfides and aryl electrophiles, which include aromatic esters, arenol derivatives, and aryl halides. Mechanistic studies revealed that Ni/dcypt can simultaneously undergo oxidative additions of aryl sulfides and aromatic esters, followed by ligand exchange between the generated aryl–Ni–SR and aryl–Ni–OAr species to furnish aryl exchanged compounds.


2020 ◽  
Vol 56 (61) ◽  
pp. 8699-8702
Author(s):  
Xue-Qiang Chu ◽  
Ting Xie ◽  
Ya-Wen Wang ◽  
Xiang-Rui Li ◽  
Weidong Rao ◽  
...  

Cascade reactions of α-perfluoroalkyl ketones with sodium sulfinates or arylsulfonyl chlorides that allowed the efficient synthesis of fluoroalkylated di(hetero)aryl sulfide derivatives under transition metal-free conditions were developed.


2019 ◽  
Vol 52 (4) ◽  
pp. 1707-1717 ◽  
Author(s):  
Jia Yu ◽  
Yanjing Gao ◽  
Shengling Jiang ◽  
Fang Sun

RSC Advances ◽  
2018 ◽  
Vol 8 (44) ◽  
pp. 25123-25126 ◽  
Author(s):  
Ren-Hua Zheng ◽  
Hai-Chang Guo ◽  
Ting-Ting Chen ◽  
Qing Huang ◽  
Guo-Bo Huang ◽  
...  

A method for the construction of a C–S bond via the ruthenium-catalyzed decarboxylative cross-coupling of carbonothioate under mild conditions is described.


Tetrahedron ◽  
2017 ◽  
Vol 73 (18) ◽  
pp. 2591-2601 ◽  
Author(s):  
Shweta Bisht ◽  
Rama Krishna Peddinti

RSC Advances ◽  
2017 ◽  
Vol 7 (81) ◽  
pp. 51475-51484 ◽  
Author(s):  
Sheng Fang ◽  
Meiyan Wang ◽  
Jingjing Liu ◽  
Bingwen Li ◽  
Jing-yao Liu

The reaction mechanism of Ni(COD)2 catalyzed hydrodesulfurization of aryl sulfide PhSMe with HSiMe3 has been predicted to have two competitive reaction pathways, with or without PhSMe spectator ligand, by using density functional theory methods.


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