Резонансная микроволновая спектроскопия полупроводников с микронным разрешением

We have proposed and experimentally verified a local method of microwave resonant spectroscopy of semiconductors. The microwave circuit of the spectrometer based on the Cascade Microtech probe station is equipped with a coaxial resonator of special geometry. As result, the measurement accuracy of the previously developed volt-impedance spectroscopy method was greatly increased. A technique for spectrometer calibration and resonant measurements of the complex impedance of the probe-sample system has been developed. We have measured the impedance of test structures with Schottky contacts of 30 - 60 μm in diameter on a single-crystal GaAs wafer at several discrete frequencies in the range of 50 - 250 MHz. The nontrivial resistive properties of the structures are studied, which consist of the excess resistance that is 1–2 orders higher than the spreading resistance for the alternating current in the unperturbed region of the semiconductor. The discovered effect is presumably associated with the a.c. charge modulation on deep levels of the semiconductor. A model calculation of the impedance spectrum has been performed, which demonstrates a good agreement with the experimental spectra.

Non-Fermi liquid behavior below the Néel temperature in the frustrated heavy fermion magnet UAu2

The term Fermi liquid is almost synonymous with the metallic state. The association is known to break down at quantum critical points (QCPs), but these require precise values of tuning parameters, such as pressure and applied magnetic field, to exactly suppress a continuous phase transition temperature to the absolute zero. Three-dimensional non-Fermi liquid states, apart from superconductivity, that are unshackled from a QCP are much rarer and are not currently well understood. Here, we report that the triangular lattice system uranium diauride (UAu2) forms such a state with a non-Fermi liquid low-temperature heat capacity C/T∼log (1/T) and electrical resistivity ρ(T)−ρ(0)∝T1.35 far below its Néel temperature. The magnetic order itself has a novel structure and is accompanied by weak charge modulation that is not simply due to magnetostriction. The charge modulation continues to grow in amplitude with decreasing temperature, suggesting that charge degrees of freedom play an important role in the non-Fermi liquid behavior. In contrast with QCPs, the heat capacity and resistivity we find are unusually resilient in magnetic field. Our results suggest that a combination of magnetic frustration and Kondo physics may result in the emergence of this novel state.

The orthorhombic-to-monoclinic phase transition in NbCrP – Peierls distortion of the chromium chain

The equiatomic metal-rich phosphide NbCrP shows a structural phase transition around 125 K. The structures of the high- and low-temperature modifications were refined from single crystal X-ray diffractometer data of an un-twinned crystal: TiNiSi type, Pnma, a = 619.80(2), b = 353.74(4), c = 735.24(6) pm, wR = 0.0706, 288 F 2 values, 20 variables at 240 K and P121/c1, a = 630.59(3), b = 739.64(4), c = 933.09(5) pm, β = 132.491(6)°, wR = 0.0531, 1007 F 2 values, 57 variables at 90 K. The structural phase transition is of a classical Peierls type. The equidistant chromium chain in HT-NbCrP (353.7 pm Cr–Cr) splits pairwise into shorter (315.2 pm) and longer (373.2 pm) Cr–Cr distances. This goes along with a strengthening of Cr–P bonding. The superstructure formation is discussed on the basis of a group–subgroup scheme. Electronic structure calculations show a lifting of band degeneracy. Protection of the non-symmorphic symmetry of space group Pnma is crucial for the phase transition. The estimated charge modulation is consistent with the interpretation as Peierls transition.

Designing Asymmetrically Modified Nanochannel Sensors Using Virtual EIS

We devised an approach to capture the physics of localized charge modulation and its effect on ionic transport across asymmetrically charged nanopores by combining computational and experimental strategies. A virtual EIS tool has been developed to compute the impedance across nanopores. Nanoporous anodic alumina membrane (NAA) is employed for thrombin detection with thrombin binding aptamer to experimentally validate the computed impedance results. Using the approach proposed in this work, a novel biosensor is designed and a way to enhance the sensitivity of the sensor is established.

Designing Asymmetrically Modified Nanochannel Sensors Using Virtual EIS

We devised an approach to capture the physics of localized charge modulation and its effect on ionic transport across asymmetrically charged nanopores by combining computational and experimental strategies. A virtual EIS tool has been developed to compute the impedance across nanopores. Nanoporous anodic alumina membrane (NAA) is employed for thrombin detection with thrombin binding aptamer to experimentally validate the computed impedance results. Using the approach proposed in this work, a novel biosensor is designed and a way to enhance the sensitivity of the sensor is established.