Hydrochemical and Stable Isotope Analyses Show Limited Interactions Between Groundwater and Lake Water in the Lake Bosomtwi Impact Crater, Ghana.

The relationship between groundwater and surface water in the Lake Bosumtwi impact crater has been assessed using hydrochemical data and stable water isotopes of δ18O and δD. This study aimed to define likely groundwater flow and recharge zones, estimate the rate of evaporation, and examine the relationship between the lake and groundwater in the study area. The results of Q-Mode hierarchical cluster analysis (HCA) clearly differentiate the lake water from the groundwater based on their spatial relationship. These preliminary results indicated that groundwater recharge occurs on the hilltops of the crater, where it is slightly acidic with low levels of dissolved minerals, characterized by short residence time and rapid unrestricted vertical infiltration and recharge. The groundwater becomes more mineralized with longer contact times and deeper circulation with the host rock, while it flows from the recharge areas towards the lake at lower elevations. Analyses of stable water isotopes of δ18O and δD showed a high evaporation rate on the lake surface, of ~90% with a relatively significant evaporative enrichment, whereas groundwater showed a relatively lower evaporation rate ranging between 54-60%. Both reservoirs do not appear to be hydraulically connected, and where such a connection exists, it is expected to favour the lake.

Integrating Stable Isotopes with Mean Residence Time Estimation to Characterize Groundwater Circulation in a Metamorphic Geothermal Field in Yilan, Taiwan

This paper presents a water circulation model by combing oxygen and hydrogen stable isotopes and mean residence time (MRT) estimation in a high-temperature metamorphic geothermal field, Tuchen, in Yilan, Taiwan. A total of 18 months of oxygen and hydrogen stable isotopes of surface water and thermal water show the same variation pattern, heavier values in summer and lighter values in the rest of the year. A shift of δ18O with a relative constant δD indicates the slow fluid–rock interaction process in the study area. Two adjacent watersheds, the Tianguer River and Duowang River, exhibit different isotopic values and imply different recharge altitudes. The seasonal variation enabled us to use stable isotope to estimate mean residence time of groundwater in the study area. Two wells, 160 m and 2200 m deep, were used to estimate mean residence time of the groundwater. Deep circulation recharges from higher elevations, with lighter isotopic values, 5.9‰ and 64‰ of δ18O and δD, and a longer mean residence time, 1148 days, while the shallow circulation comes from another source with heavier values, 5.7‰ and 54.4‰ of δ18O and δD, and a shorter mean residence time, 150 days. A two-circulation model was established based on temporal and spatial distribution characteristics of stable isotopes and the assistance of MRT. This study demonstrates the usefulness of the combined usage for further understanding water circulation of other various temperatures of metamorphic geothermalfields.

Explanation Of Marine Lake Formation At Misool Raja Ampat West Papua, Indonesia

Marine lake in a karst landscape is one of the macro karst forms known as doline and is only found in some locations in the world. Moreover, the theory of marine doline formation is always associated with global sea-level rise which differs from one place to another due to several factors. This research was conducted to understand the formation process of marine lakes in Misool and how the water fills the basins formed especially at Holocene time. This was achieved by obtaining information on the longest underwater terrace which is also the longest standing water position recorded on the sea wall. The marine terraces were measured by sounding profiles to the sea bordering the seven marine lakes including Lenmakana, Balbullol, Lenkafal, Keramat, Karawapop, Keramat-2, and Keramat-3 as well as Harapan Jaya Sea. A total of 24 profiles were measured and stable isotopes δ18O and δD of water samples were used to determine the origin of water in the lakes. The results showed the longest terrace was at the depth of ˗33 and ˗3 m while the references from the area closest to Misool showed the same water level positions at 10,500 BP and 6,985 BP. Furthermore, the composition of δ18O and δD from lake water indicated the water samples were a mixture of groundwater and seawater with the seawater having the more dominant concentration and this allows it to fill the lake first through a previously formed cavity system.

Continuous monitoring of surface water vapour isotopic compositions at Neumayer Station III, East Antarctica

In this study, the first fully continuous monitoring of water vapour isotopic composition at Neumayer Station III, Antarctica, during the 2-year period from February 2017 to January 2019 is presented. Seasonal and synoptic-scale variations in both stable water isotopes H218O and HDO are reported, and their links to variations in key meteorological variables are analysed. In addition, the diurnal cycle of isotope variations during the summer months (December and January 2017/18 and 2018/19) has been examined. Changes in local temperature and specific humidity are the main drivers for the variability in δ18O and δD in vapour at Neumayer Station III, on both seasonal and shorter timescales. In contrast to the measured δ18O and δD variations, no seasonal cycle in the Deuterium excess signal (d) in vapour is detected. However, a rather high uncertainty in measured d values especially in austral winter limits the confidence of this finding. Overall, the d signal shows a stronger inverse correlation with specific humidity than with temperature, and this inverse correlation between d and specific humidity is stronger for the cloudy-sky conditions than for clear-sky conditions during summertime. Back-trajectory simulations performed with the FLEXPART model show that seasonal and synoptic variations in δ18O and δD in vapour coincide with changes in the main sources of water vapour transported to Neumayer Station III. In general, moisture transport pathways from the east lead to higher temperatures and more enriched δ18O values in vapour, while weather situations with southerly winds lead to lower temperatures and more depleted δ18O values. However, on several occasions, δ18O variations linked to wind direction changes were observed, which were not accompanied by a corresponding temperature change. Comparing isotopic compositions of water vapour at Neumayer Station III and snow samples taken in the vicinity of the station reveals almost identical slopes, both for the δ18O–δD relation and for the temperature–δ18O relation.

Evaluating the Potential of Rhyolitic Glass as a Lithium Source for Brine Deposits

Lithium is an economically important element that is increasingly extracted from brines accumulated in continental basins. While a number of studies have identified silicic magmatic rocks as the ultimate source of dissolved brine lithium, the processes by which Li is mobilized remain poorly constrained. Here we focus on the potential of low-temperature, post-eruptive processes to remove Li from volcanic glass and generate Li-rich fluids. The rhyolitic glasses in this study (from the Yellowstone-Snake River Plain volcanic province in western North America) have interacted with meteoric water emplacement as revealed by textures and a variety of geochemical and isotopic signatures. Indices of glass hydration correlate with Li concentrations, suggesting Li is lost to the water during the water–rock interaction. We estimate the original Li content upon deposition and the magnitude of Li depletion both by direct in situ glass measurements and by applying a partition-coefficient approach to plagioclase Li contents. Across our whole sample set (19 eruptive units spanning ca. 10 m.y.), Li losses average 8.9 ppm, with a maximum loss of 37.5 ppm. This allows estimation of the dense rock equivalent of silicic volcanic lithologies required to potentially source a brine deposit. Our data indicate that surficial processes occurring post-eruption may provide sufficient Li to form economic deposits. We found no relationship between deposit age and Li loss, i.e., hydration does not appear to be an ongoing process. Rather, it occurs primarily while the deposit is cooling shortly after eruption, with δ18O and δD in our case study suggesting a temperature window of 40° to 70°C.

Water-source contributions to barrier lakes and water-rock interactions in the Wudalianchi volcanic area, Northeast China

Wudalianchi is a typical continental Cenozoic volcanic group rich in potassic volcanic rocks (Northeast China). Five hydrologically connected barrier lakes (Lakes 5 to 1) and upwelling cold mineral springs occur, forming a complex lake-groundwater system. Clarifying the water-source contributions and the role of water-rock interactions in the hydrological cycling for barrier lakes remains a challenge from scientific and engineering perspectives. In this study, seasonal variations of multiple isotopes were analyzed. δ18O and δD data indicate that the Wudalianchi lakes were mainly fed by mineral springs. The values, however, were greatly influenced by precipitation (rain and snow) and varying evaporation intensities. In contrast, 87Sr/86Sr ratios varied little between seasons (0.70701–0.7079), suggesting similar water-rock interactions through time. Nonetheless, Sr isotopic mixing models suggested that shallow mineral springs generally contributed >50% of the water to lower reaches. In contrast, the upstream wetland contributed >50% to Lake 5 and decreased down-valley (10.3–53.6%). Calculations based on the δ18O and δD Rayleigh fractionation equation suggest that evaporation in upper reaches were higher than the lower reaches. The evaporation in July were generally higher than in October. This study demonstrates the homogenous water-rock interactions and the associated water mixing effects on the terrestrial volcanic area.

Estimation of the Deep Geothermal Reservoir Temperature of the Thermal Waters of the Active Continental Margin (Okhotsk Sea Coast, Far East of Asia)

Low-enthalpy thermal waters (30–70 °C) with nitrogen as a dominant associated gas are spread within the active continental margin of the Russian Far East (east and north of the Okhotsk Sea Coast) and traditionally are of great importance for recreation and balneology facilities. The thermal waters are chemically classified into three groups: (i) Na–HCO3(SO4) type, with low TDS (0.2 g/L) and lowest temperature (<50 °C) and high pH (9.1–9.3), (ii) Na–SO4 type with TDS (~1 g/L), highest temperature (70 °C) and weak alkaline pH (8.7) and (iii) Ca–Na–Cl type with high TDS (15 g/L), moderate T (59 °C) and neutral pH (7.5). The δ18O and δD values suggest that the thermal waters originate from meteoric water, and they are not isotopically fractionated. Silica and cation geothermometers and thermodynamic equilibrium calculations using the GeoT and PHREEQC programs indicate a reservoir temperature for the Na–HCO3(SO4) type thermal waters of 103–121 °C and for Na–SO4 and Ca–Na–Cl types of 136 and 153 °C, respectively. The evaluation of the mixing degree of the thermal water with cold groundwater shows that the equilibration temperature ranges between 148 and 153 °С. Estimated circulation depths for thermal manifestations range from 2.7 to 4.3 km and may be as great as 6 km.

A dedicated robust instrument for water vapor generation at low humidity for use with a laser water isotope analyzer in cold and dry polar regions

Obtaining precise continuous measurements of water vapor isotopic composition in dry places (polar or high-altitude regions) is an important challenge. The current limitation is the strong influence of humidity on the measured water isotopic composition by laser spectroscopy instruments for low humidity levels (below 3000 ppmv). This problem is addressed by determining the relationships between humidity and measured δ18O and δD of known water standards. Here, we present the development of a robust field instrument able to generate water vapor, down to 70 ppmv, at very stable humidity levels (average 1σ lower than 10 ppmv). This instrument, operated by a Raspberry interface, can be coupled to a commercial laser spectroscopy instrument. We checked the stability of the system as well as its accuracy when expressing the measured isotopic composition of water vapor on the VSMOW–SLAP (Vienna Standard Mean Ocean Water – Standard Light Antarctic Precipitation) scale. It proved to be highly stable during autonomous operation over more than 1 year at the East Antarctic Concordia and Dumont d'Urville stations.

New chronology of the Chinese loess-paleosol sequence by leaf wax δD records during the past 800 k.y.

The Chinese loess-paleosol sequences provide important archives for studying paleoenvironmental changes. However, the lack of independent and accurate time scales hinders the study between loess and other records. Asian stalagmite δ18O records indicate synchronous patterns of paleoprecipitation δ18O over large geographic regions. The record of hydrogen isotopic composition of plant wax (δDwax) in Chinese loess is also controlled by rainwater δD. Both share a common origin. The linear relationship between rainfall δ18O and δD variance provides the basis to tie together chronologies of the same climate event in different records. Here, we show a new loess chronology by correlating chronologies of marker boundaries of the prominent climate chronozones in stalagmite δ18O and summer insolation to the equivalent climate stratigraphy in the loess δDwax sequence. We first developed and tested this novel methodology with data since the last interglacial on a millennial scale, and then applied this approach to the loess δDwax sequence for the past 800 k.y. to improve the traditional chronology based on magnetic susceptibility and grain size. The new δDwax time series provides not only an improved chronology for studying paleoclimate changes during interglacial intervals, it also represents a unique database with which to better understand the links between the Asian monsoon changes in the Chinese loess and other global climate events, especially for the periods prior to 640 ka, for which stalagmite records are not available.

Continuous-Flow Analysis of δ17O, δ18O, and δD of H2O on an Ice Core from the South Pole

The δD and δ18O values of water are key measurements in polar ice-core research, owing to their strong and well-understood relationship with local temperature. Deuterium excess, d, the deviation from the average linear relationship between δD and δ18O, is also commonly used to provide information about the oceanic moisture sources where polar precipitation originates. Measurements of δ17O and “17O excess” (Δ17O) are also of interest because of their potential to provide information complementary to d. Such measurements are challenging because of the greater precision required, particularly for Δ17O. Here, high-precision measurements are reported for δ17O, δ18O, and δD on a new ice core from the South Pole, using a continuous-flow measurement system coupled to two cavity ring-down laser spectroscopy instruments. Replicate measurements show that at 0.5 cm resolution, external precision is ∼0.2‰ for δ17O and δ18O, and ∼1‰ for δD. For Δ17O, achieving external precision of &lt;0.01‰ requires depth averages of ∼50 cm. The resulting ∼54,000-year record of the complete oxygen and hydrogen isotope ratios from the South Pole ice core is discussed. The time series of Δ17O variations from the South Pole shows significant millennial-scale variability, and is correlated with the logarithmic formulation of deuterium excess (dln), but not the traditional linear formulation (d).