Wastewater deodorization: problems and solutions

The problem of specific malodours odorants, emitted from the territory of wastewater and sludge treatment facilities is set in the article. This article presents a critical review concerning the reasons of odorants formation during wastewater treatment, their influence on human health and ways of wastewater and sludge deodorization. Review is presented by 52 resources of Russian, Chinese, Italian, Greek, Indian, American and other researches from 2000 to 2021 years. According to the review the main sources of odours emission are units of mechanical treatment, sludge thickening and sludge digestion. The main odorants are volatile organic compounds (VOCs), hydrogen sulphide, ammonia, particulate matters and greenhouse gases (carbon dioxide, methane, nitrogen oxide). Based on the article, there are two ways of emission controlling: controlling the technological parameters of wastewater treatment process or gases treatment at specific facilities (adsorbers, biofilters, bioscrubbers, chemical scrubbers).

Microbiological and Toxicological Hazards in Sewage Treatment Plant Bioaerosol and Dust

Despite the awareness that work in the sewage treatment plant is associated with biological hazards, they have not been fully recognised so far. The research aims to comprehensively evaluate microbiological and toxicological hazards in the air and settled dust in workstations in a sewage treatment plant. The number of microorganisms in the air and settled dust was determined using the culture method and the diversity was evaluated using high-throughput sequencing. Endotoxin concentration was assessed with GC-MS (gas chromatography-mass spectrometry) while secondary metabolites with LC-MS/MS (liquid chromatography coupled to tandem mass spectrometry). Moreover, cytotoxicity of settled dust against a human lung epithelial lung cell line was determined with the MTT (3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide) assay and UHPLC-Q-ToF-UHRMS (ultra-high-performance liquid chromatography-quadrupole time-of-flight ultrahigh-resolution mass spectrometry) analysis was performed to determine the source of cytotoxicity. The total dust concentration in the sewage treatment plant was low and ranged from 0.030 mg m−3 to 0.044 mg m−3. The highest microbiological contamination was observed in sludge thickening building and screenings storage. Three secondary metabolites were detected in the air and sixteen in the settled dust. They were dominated by compounds typical of lichen and plants and Aspergillus, Penicillium and Fusarium genera mould. The settled dust from the sludge thickening building revealed high cytotoxicity to human lung epithelial cells A-549 (IC50 = 6.98 after 72 h). This effect can be attributed to a biocidal compound—didecyldimethylammonium chloride (DDAC-C10) and seven toxic compounds: 4-hydroxynonenal, carbofuran, cerulenin, diethylphosphate, fenpropimorph, naphthalene and onchidal. The presence of DDAC-C10 and other biocidal substances in the sewage treatment plant environment may bring negative results for biological sewage treatment and the natural environment in the future and contribute to microorganisms’ increasing antibiotics resistance. Therefore, the concentration of antibiotics, pesticides and disinfectants in sewage treatment plant workstations should be monitored.

Characterization of Tailings Dams by Electrical Geophysical Methods (ERT, IP): Federico Mine (La Carolina, Southeastern Spain)

This work analyzed the effectiveness of two electrical geophysical methods in characte-rizing tailings dams. A large flotation cell used for sludge thickening in the concentration plant of the Federico Mine (closed in 1985) within the old mining district of La Carolina (southeastern Spain) was selected for this research. In addition to the direct information provided by the geology of the study area and the surface exposure of the waste deposits, information regarding the construction of this mining structure was available, which helped in the interpretations of the geophysical survey data. In this study, two geophysical surveying methods were used simultaneously: Electrical resistivity tomography (ERT) and induced polarization (IP). Six profiles were acquired, processed, and interpreted. The length of the profiles allowed the obtaining of data reaching maximum investigation depths ranging between 7 and 65 m. These profiles provided information for a detailed analysis of the internal characteristics of the deposited materials. The lateral and vertical observed variations are linked to different degrees of moisture content. The study also defines the geometry of the top of the bedrock and the tectonics that affect the pouring/dumping hole. Old flotation sludge has resistivity values that range between 1 and 100 Ωm (i.e., wet waste 1–30 Ωm, dry waste 30–100 Ωm), while phyllites in the rocky substrate have resistivities larger than 200 Ωm and can even reach va-lues greater than 1000 Ωm. Between the waste and unaltered phyllites, there is a supergene alteration zone (weathering) with resistivity values between 100 and 200 Ωm. The IP method was used to detect the presence of metals in the accumulated waste in the pond by analyzing the presence of large chargeability anomalies. Anomalies were detected in four of the profiles, which ranged from low (i.e., between 0 and 8 mV/V) to medium (i.e., between 8 and 18 mV/V) and high values (i.e., 18 and >30 mV/V).