Identification and mapping of ancient pigments in a Roman Egyptian funerary portrait by application of reflectance and luminescence imaging spectroscopy

Imaging spectroscopy (IS) is an important tool in the comprehensive technical analysis required of archaeological paintings. The complexity of pigment mixtures, diverse artistic practices and painting technologies, and the often-fragile and weathered nature of these objects render macroscale, non-invasive chemical mapping an essential component of the analytical protocol. Furthermore, the use of pigments such as Egyptian blue and madder lake, featuring diagnostic photoluminescence emission, provides motivation to perform photoluminescence mapping on the macroscale. This work demonstrates and advances new applications of dual-mode imaging spectroscopy and data analysis approaches for ancient painting. Both reflectance (RIS) and luminescence (LIS) modes were utilized for the study of a Roman Egyptian funerary portrait from second century CE Egypt. The first derivative of the RIS image cube was analyzed and found to significantly improve materials separation, identification, and the extent of mapping. Egyptian blue and madder lake were mapped across a decorated surface using their luminescence spectral signatures in the region of 540–1000 nm as endmembers in LIS analyses. Linear unmixing of the LIS endmembers and subsequent derivative analyses resulted in an improved separation and mapping of the luminescence pigments. RIS and LIS studies, combined with complementary, single-spot collection elemental and molecular spectroscopy, were able to successfully characterize the portrait’s painting materials and binding media used by the ancient artist, providing key insight into their material use, stylistic practices, and technological choices.

Accreting protoplanets: Spectral signatures and magnitude of gas and dust extinction at H α

Context. Accreting planetary-mass objects have been detected at H α, but targeted searches have mainly resulted in non-detections. Accretion tracers in the planetary-mass regime could originate from the shock itself, making them particularly susceptible to extinction by the accreting material. High-resolution (R > 50 000) spectrographs operating at H α should soon enable one to study how the incoming material shapes the line profile. Aims. We calculate how much the gas and dust accreting onto a planet reduce the H α flux from the shock at the planetary surface and how they affect the line shape. We also study the absorption-modified relationship between the H α luminosity and accretion rate. Methods. We computed the high-resolution radiative transfer of the H α line using a one-dimensional velocity–density–temperature structure for the inflowing matter in three representative accretion geometries: spherical symmetry, polar inflow, and magnetospheric accretion. For each, we explored the wide relevant ranges of the accretion rate and planet mass. We used detailed gas opacities and carefully estimated possible dust opacities. Results. At accretion rates of Ṁ ≲ 3 × 10−6 MJ yr−1, gas extinction is negligible for spherical or polar inflow and at most AH α ≲ 0.5 mag for magnetospheric accretion. Up to Ṁ ≈ 3 × 10−4 MJ yr−1, the gas contributes AH α ≲ 4 mag. This contribution decreases with mass. We estimate realistic dust opacities at H α to be κ ~ 0.01–10 cm2 g−1, which is 10–104 times lower than in the interstellar medium. Extinction flattens the LH α –Ṁ relationship, which becomes non-monotonic with a maximum luminosity LH α ~ 10−4 L⊙ towards Ṁ ≈ 10−4 MJ yr−1 for a planet mass ~10 MJ. In magnetospheric accretion, the gas can introduce features in the line profile, while the velocity gradient smears them out in other geometries. Conclusions. For a wide part of parameter space, extinction by the accreting matter should be negligible, simplifying the interpretation of observations, especially for planets in gaps. At high Ṁ, strong absorption reduces the H α flux, and some measurements can be interpreted as two Ṁ values. Highly resolved line profiles (R ~ 105) can provide (complex) constraints on the thermal and dynamical structure of the accretion flow.

Photoacoustic Imaging of Enucleated Eyes from Patients with Uveal Melanoma can Reveal Extrascleral Growth

Background: Uveal melanoma is treated by either enucleation (removal of the eye) or local eye-sparing therapies, depending on tumor size and whether there are signs of extrascleral growth. Photoacoustic (PA) imaging is a novel imaging modality that provides high-resolution images of the molecular composition of tissues. Objective: In this study, the feasibility of PA imaging for uveal melanomas and detection of extrascleral growth was explored. Methods: Seven enucleated human eyes with uveal melanomas were examined using PA imaging. The spectral signatures of the melanomas and the layers of the normal eyewall were characterized using 59 excitation wavelengths from 680 to 970 nm. Results: Significant differences were seen between the spectra obtained from melanoma and the healthy eyewall. Using spectral unmixing, melanin, hemoglobin and collagen could be mapped out, showing the architecture of the tumor in relation to the eyewall. This allowed visualization of regions where the tumor extended into the extrascleral space. Conclusion: PA imaging appears to have the potential to aid in assessing uveal melanomas and as a diagnostic tool for the detection of extrascleral growth.

Strain-spectroscopy of strongly interacting defects in superconducting qubits

The proper functioning of some micro-fabricated novel quantum devices, such as superconducting resonators and qubits, is severely affected by the presence of parasitic structural material defects known as tunneling two-level-systems (TLS). Recent experiments have reported unambiguous evidence of the strong interaction between individual (coherent) TLS using strain-assisted spectroscopy. This work provides an alternative and simple theoretical insight that illustrates how to obtain the spectral response of such strongly interacting defects residing inside the amorphous tunnel barrier of a qubit's Josephson junction. Moreover, the corresponding spectral signatures obtained here may serve to quickly and efficiently elucidate the actual state of these interacting TLS in experiments based on strain- or electric-field spectroscopy.

An Innovative Security Screening Architecture for Detecting Illicit Goods and Threats

Every year, millions of letters/parcels containing illicit goods are detected by customs authorities, which use traditional security screening equipment. However this equipment cannot detect all kinds of illicit goods and the detection procedure heavily depends on the attention of the customs officer. In order to achieve sufficiently fast intelligent screening of the large volumes of letters/parcels and detect all common kinds of threats, this paper proposes a highly innovative architecture well-beyond the state-of–art. In particular the proposed architecture monitors every letter/parcel by incorporating: (a) terahertz/X-ray sensors, (b) chemical, biological, radiological and nuclear (CBNR) sensors, (c) artificial robot-noses for narcotics, explosives etc., (d) magnetometers for weapons, firearms, banknotes etc., (e) acoustic sensors for liquids/gases/solids, (f) weight/pressure sensors to measure weight distribution, size and shape. Sensory information can be: (a) used to create a “Spectral Signatures Dictionary of Illicit Goods and Threats”, (b) fused to segment/isolate illicit goods and (c) visualized in the form of annotated high-resolution tensor-structured (3D/4D) multisensory image data. The proposed solution also gathers available information for the sender/recipient from various resources, while it also analyzes data from the dark web. All information is forwarded to an AI-based knowledge infrastructure.

Tracking excited state decay mechanisms of pyrimidine nucleosides in real time

DNA owes its remarkable photostability to its building blocks—the nucleosides—that efficiently dissipate the energy acquired upon ultraviolet light absorption. The mechanism occurring on a sub-picosecond time scale has been a matter of intense debate. Here we combine sub-30-fs transient absorption spectroscopy experiments with broad spectral coverage and state-of-the-art mixed quantum-classical dynamics with spectral signal simulations to resolve the early steps of the deactivation mechanisms of uridine (Urd) and 5-methyluridine (5mUrd) in aqueous solution. We track the wave packet motion from the Franck-Condon region to the conical intersections (CIs) with the ground state and observe spectral signatures of excited-state vibrational modes. 5mUrd exhibits an order of magnitude longer lifetime with respect to Urd due to the solvent reorganization needed to facilitate bulky methyl group motions leading to the CI. This activates potentially lesion-inducing dynamics such as ring opening. Involvement of the 1nπ* state is found to be negligible.

LIMITATION ASSESSMENT AND WORKFLOW REFINEMENT OF THE MANGROVE VEGETATION INDEX (MVI)-BASED MAPPING METHODOLOGY USING SENTINEL-2 IMAGERY

The Mangrove Vegetation Index (MVI) was developed to map mangroves extent from remotely-sensed imageries accurately and quickly. MVI measures the probability of a pixel to be a ‘mangrove’ by extracting the greenness and moisture information from the green, NIR, and SWIR bands. The range of MVI values may vary depending on factors such as land cover classes, climatic conditions, or tidal conditions. Mapping the scope of mangrove sites involves setting a maximum and minimum MVI threshold to separate them from other land cover classes and vegetation. Although the MVI has a high index accuracy, its mapping performance is limited by some biophysical and environmental factors. Misclassification occurs in aquacultural areas, irrigated croplands, and sites with palm trees where mangrove and surrounding vegetation pixels have highly similar spectral signatures. There are scenes with complex environments, such as in aquaculture areas and along a network of rivers and streams, where an optimal threshold varies across the site, and setting a single MVI threshold may not yield excellent results. An automated threshold setting using the Otsu method was explored; however, the results were inaccurate due to a low intensity contrast between mangroves and other vegetation in the MVI raster layer. This study also looked into possible adjustments to improve the manual threshold setting workflow for a successful mapping of mangrove extent using MVI on Sentinel-2 imagery.