Rational design of zwitterionic porous organic framework loading Co (II) ions to host sulfur and synergistically boost polysulfides redox kinetics for lithium sulfur batteries

In the development of lithium-sulfur batteries (LiSBs), the irreversible volume changes, annoying shuttle effect and slow conversion kinetics of lithium polysulfides (LiPSs) are main obstacles for further commercialization. Therefore, a...

Rational Construction of a Responsive Azo-Functionalized Porous Organic Framework for CO2 Sorption

An azo-functionalized porous organic framework (denoted as JJU-1) was synthesized via FeCl3-promoted oxidative coupling polymerization. By virtue of a porous skeleton and a light/heat responsive azo functional group, this task-specific JJU-1 displays a reversible stimuli-responsive adsorption property triggered by UV irradiation and heat treatment. The initial Brunauer–Emmet–Teller (BET) surface area of this porous material is 467 m2 g–1. The CO2 sorption isotherms exhibit a slight decrease after UV irradiation because of the trans to cis conversion of the azo functional skeleton. It is worth mentioning that the responsive CO2 adsorption performance can be recycled for three cycles via alternating external stimuli, confirming the excellently reversible switchability of trans-to-cis isomerization and controllable CO2 adsorption.

Recyclable Catalysts for Alkyne Functionalization

In this review, we present an assessment of recent advances in alkyne functionalization reactions, classified according to different classes of recyclable catalysts. In this work, we have incorporated and reviewed the activity and selectivity of recyclable catalytic systems such as polysiloxane-encapsulated novel metal nanoparticle-based catalysts, silica–copper-supported nanocatalysts, graphitic carbon-supported nanocatalysts, metal organic framework (MOF) catalysts, porous organic framework (POP) catalysts, bio-material-supported catalysts, and metal/solvent free recyclable catalysts. In addition, several alkyne functionalization reactions have been elucidated to demonstrate the success and efficiency of recyclable catalysts. In addition, this review also provides the fundamental knowledge required for utilization of green catalysts, which can combine the advantageous features of both homogeneous (catalyst modulation) and heterogeneous (catalyst recycling) catalysis.