alkylphosphonic acids
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Electrochem ◽  
2022 ◽  
Vol 3 (1) ◽  
pp. 58-69
Author(s):  
Valbonë Mehmeti ◽  
Fetah Podvorica

Alkylphosphonic acids are well known for their ability to form self-assembled monolayers on hydroxide surfaces. A crucial step to understanding fundamentally how these surfaces are created is the elucidation of the interaction process that leads to such interface creation. In this study, we employed electrochemical impedance spectroscopy (EIS), Monte Carlo and molecular dynamics to understand this process. The interaction with the Cu(111) surface of three different alkylphosphonic acids (hexyl-, octyl- and decylphosphonic acids) is evaluated in an aqueous acidic and in an ethanol solution by Monte Carlo and molecular dynamics simulations, while EIS measurements are used to put in evidence the impact of the layer made in ethanol on copper protection. Nyquist diagrams of copper samples modified with an alkylphosphonic monolayer showed a higher polarization resistance that mitigates the copper corrosion in an aqueous acid medium. The phase–frequency Bode plots had higher and broader phase maxima for a modified copper surface with phosphonic moieties, which confirmed the ability of this organic layer to prevent copper corrosion.


Molecules ◽  
2021 ◽  
Vol 26 (17) ◽  
pp. 5303
Author(s):  
Nikoletta Harsági ◽  
Réka Henyecz ◽  
Péter Ábrányi-Balogh ◽  
László Drahos ◽  
György Keglevich

It is well-known that the P-acids including phosphonic acids resist undergoing direct esterification. However, it was found that a series of alkylphoshonic acids could be involved in monoesterification with C2–C4 alcohols under microwave (MW) irradiation in the presence of [bmim][BF4] as an additive. The selectivity amounted to 80–98%, while the isolated yields fell in the range of 61–79%. The method developed is a green method for P-acid esterification. DFT calculations at the M062X/6–311+G (d,p) level of theory (performed considering the solvent effect of the corresponding alcohol) explored the three-step mechanism, and justified a higher enthalpy of activation (160.6–194.1 kJ·mol−1) that may be overcome only by MW irradiation. The major role of the [bmim][BF4] additive is to increase the absorption of MW energy. The specific chemical role of the [BF4] anion of the ionic liquid in an alternative mechanism was also raised by the computations.


2021 ◽  
Vol 2021 (10) ◽  
pp. 1596-1602
Author(s):  
Vladimir A. Kuimov ◽  
Svetlana F. Malysheva ◽  
Natalia A. Belogorlova ◽  
Alexander I. Albanov ◽  
Nina K. Gusarova ◽  
...  

2019 ◽  
Vol 5 (8) ◽  
pp. eaaw4307 ◽  
Author(s):  
Andrew M. Turner ◽  
Matthew J. Abplanalp ◽  
Alexandre Bergantini ◽  
Robert Frigge ◽  
Cheng Zhu ◽  
...  

For decades, the source of phosphorus incorporated into Earth’s first organisms has remained a fundamental, unsolved puzzle. Although contemporary biomolecules incorporate P(+V) in their phosphate moieties, the limited bioavailability of phosphates led to the proposal that more soluble P(+III) compounds served as the initial source of phosphorus. Here, we report via laboratory simulation experiments that the three simplest alkylphosphonic acids, soluble organic phosphorus P(+III) compounds, can be efficiently generated in interstellar, phosphine-doped ices through interaction with galactic cosmic rays. This discovery opens a previously overlooked avenue into the formation of key molecules of astrobiological significance and untangles basic mechanisms of a facile synthesis of phosphorus-containing organics in extraterrestrial ices, which can be incorporated into comets and asteroids before their delivery and detection on Earth such as in the Murchison meteorite.


Molecules ◽  
2018 ◽  
Vol 23 (4) ◽  
pp. 859 ◽  
Author(s):  
Marek Cypryk ◽  
Jozef Drabowicz ◽  
Bartlomiej Gostynski ◽  
Marcin Kudzin ◽  
Zbigniew Kudzin ◽  
...  

2017 ◽  
Vol 192 (6) ◽  
pp. 651-658 ◽  
Author(s):  
Marek Cypryk ◽  
Jozef Drabowicz ◽  
Bartlomiej Gostynski ◽  
Marcin H. Kudzin ◽  
Zbigniew H. Kudzin ◽  
...  

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