К вопросу о влиянии неоднородного диэлектрического покрытия на характеристики металлической поверхности

Within the framework of the quantum-statistical functional and the Ritz method, the the problem of finding the surface energy per unit area and work function electrons of a metal flat surface with a inhomogeneous dielectric coating, taken into account in the approximation of a continuous medium. For a uniform coating, the calculated values are insensitive to the selection one-parameter functions for an electronic profile, but sensitive to the gradient series of kinetic energy non-interacting electrons. Calculations are performed for Al, Na and the comparison with the calculations by the Kohn-Shem method is made. Analytically the connection between the theory of the Ritz method for inhomogeneous coatings and calculations by the Kohn-Shem method work function of electrons for metal-dielectric nanosandwiches. As it turned out, the influence inhomogeneous coating on the characteristics of the metal surface can be scaled down to a uniform coverage case. The possibility of using the obtained results in various experimental situations are discussed.

Development of a Protective Coating for Evaluating the Sub-surface Microstructure of a Worn Material

In the current study, electrolytic deposition using two different electrodes, copper (Cu) and nickel (Ni) was investigated with the aim of protecting the worn surface during mechanical sectioning and polishing, for a posterior examination of the sub-surface microstructure. The efficacies of the two coatings were visually assessed based on its adhesivity and the ability to protect the wear tracks of an as-cast 26% Cr high chromium cast iron (HCCI) alloy. It was observed that electrodeposition using Cu as the electrode was ineffective owing to a poor adhesivity of the coating on the HCCI surface. The coating had peeled off at several regions across the cross-section during the mechanical sectioning. On the other hand, Ni electroplating using Ni strike as the electrolyte was successfully able to protect the wear track, and the sub-surface characteristics of the wear track could be clearly visualized. A uniform coating thickness of about 8 µm was deposited after 30–40 min with the current density maintained between 1 and 5 A/dm2. The presence of the Ni coating also acted as a protective barrier preventing the ejection of the broken carbide fragments underneath the wear track.

Research on Trench Etching and Photolithography Process of SiC Trench MOSFET

In this paper, the development of trench etching process and photolithography process for 6-inch 4H-SiC trench-type power MOSFET devices is mainly studied. Among them, the etching process successfully solved the anisotropy of dry etching of SiC, the different etching rates of different crystal planes, the difficulty of controlling the angle of the trench sidewall, and the easy formation of micro-trenches at the corners, etc. Successfully realized trenches with etch depth greater than 1.2um and sidewall angle greater than 90° in SiC. Subsequently, the trench was filled with SiO2 to achieve no holes in the trench after filling, and then the photolithography process was studied. Photolithography process is resolved at the trench coating, exposing and developing the non-uniformity problem, achieve a full and uniform coating, self-aligned trench overlay and the overlay accuracy of less than 0.1um, and there is no residue of photoresist in the groove after development. This article uses scanning electron microscope (SEM) to measure the morphology of the trench after etching and photolithography to characterize the experimental results, and the results meet the process requirements. The successful development of this process will facilitate the research and development of deeper trench-type power MOSFET devices.

Rapid Coating of Aqueous Pearls with Carbon Nanotubes via In Situ Polymerization of Dopamine

Millimeter-scale calcium alginate aqueous core capsules (mm-CaSA-Caps) are suitable for embedding of temperature and chemical sensitive substances because of its excellent biocompatibility and biodegradability. In this study, mm-CaSA-Caps were coated with multiwalled carbon nanotubes (MWNTs) via in situ self-polymerization of dopamine (DA) under mild conditions. During the modification process, mm-CaSA-Caps transferred quickly from colorless and transparent capsules to dark and opaque “pearls” in 15 min. The obtained MWNTs-polydopamine- (PDA-) modified mm-CaSA-Caps (mm-MWNTs-PDA@CaSA-Caps) retained the spherical appearance of mm-CaSA-Caps with uniform coating of MWNTs-PDA. Obviously, the MWNTs were easily coated on the mm-PDA@CaSA-Caps due to the strong adhesive property of PDA. As the MWNTs content increased, the stacking density of MWNTs on surface of the mm-MWNTs-PDA@CaSA-Caps raised. The water loss ratio of mm-MWNTs-PDA@CaSA-Caps was enhanced ascribed to increasing the path length of water by raising stacking density of MWNTs. This study provided a new path for enhancement of the barrier property of hydrogel capsules.

High-Temperature Oxidation of Cr-Coated Resistance Upset Welds Made from E110 Alloy

The resistance upset welds (RUW) made from E110 alloy without and with Cr coatings were oxidized in air atmosphere at 1100 °C for 2, 10 and 30 min. The cross-section microstructure, elemental composition and hardness were studied before and after oxidation using optical and scanning electron microscopy, and indentations in welding region. The RUW welding does not noticeably change oxidation kinetics of E110 alloy. The most crucial effect has surface non-regularities formed after welding, which prevent uniform coating deposition on full surface of welded cladding tube and end plug. Cr coating deposition can strongly reduce oxidation of welded E110 alloy, while additional post-processing treatment should be applied to improve surface morphology after RUW welding. Several suggestions favorable to development of ATF Zr-based claddings using Cr coating deposition on welded nuclear rods were discussed.

D.C. Magnetron Sputtering Coating on Trenches

The development and application of plasma processing such as plasma assisted CVD and PVD become highly important in various industrial fields such as microelectronics, sensors, solar cells, automobiles, cutting tools, etc. In PVD different process are used such as Vacuum Evaporation, Electron Beam evaporation, Sputtering etc. But all processes have common limitation of one as such deposition is inline sight. It is difficult to achieve uniform coating on complex surfaces, holes and trenches. The width dimension and higher aspect ratio (Depth: width >1) of trenches generally in compatible with sputter deposition. When aspect ratio is increased, undesirable discontinuity can be observed at the lower half compared to upper half of trenches. So that 3 axis rotation of substrate holder was designed with a stepper motors to get uniform coating on complex surfaces and holes. The angle of rotation and the speed are controlled by programmed micro controller. By positioning the surface features perpendicular to the plasma the holes, grooves are coated uniformly. The coating was characterized using X-ray diffractometer, SEM and micro hardness tester.

In Situ Synthesis of Silver Nanoparticles on Amino-Grafted Polyacrylonitrile Fiber and Its Antibacterial Activity

In this study, amino hyperbranched polymers (HBP)-grafted polyacrylonitrile (PAN) fiber was prepared through an amidation reaction in an autoclave. The prepared PAN-G-HBP fiber can complex Ag+ through amino groups of amino HBP, and in a hot steaming condition, Ag+ can be converted to Ag0 through the reducibility of HBP. PAN-G-HBP and Ag nanoparticles (NPs)-coated fibers were then characterized through FTIR, UV–VIS DRS, FE-SEM, EDS, XPS and antibacterial measurement. FTIR results confirmed HBP was grafted on the surface of PAN fiber. FE-SEM showed that after grafting with HBP, the average diameter of PAN fibers was amplified. EDS, XPS, and UV–VIS DRS method indicated that under hot steaming condition and with the reducibility of HBP, Ag NPs uniform coating on the PAN-G-HBP. Ag NPs-coated fibers exhibits excellent antibacterial property against Escherichia coli and Staphylococcus aureus. Even under 20 times home washing conditions, the antibacterial reduction of Ag NPs-coated PAN fiber can achieved more than 98.94%.