A Study on Conservation and Desalination for Iron Weapons During the Korean War from DMZ

The weapons excavated from the de-militarized zones (DMZ) of Korea are vulnerable to corrosion due to the immediate and drastic environmental change. Especially, the chloride ions (Cl⁻) in iron weapons cause active corrosion and require removal. In this study, conservation treatment and de-salination was performed for the discovered weapons from excavation sites of soldiers killed in action during the Korean War. Furthermore, an attempt was made to prepare the most stable plan for conservation treatment through the comparative study of soaking weapons in distilled water without chemicals and in a solution of sodium (SSC) at different temperatures. In the preliminarily experiments, the comparison of the eluted Cl⁻ ions according to different conditions of de-salination showed that the highest number of ions were detected from the de-salination with SSC at a temperature of 100℃, and its duration was much smaller, i.e., 1∼2 weeks. Accordingly, for the parts from the guns and rifles amongst other objects, a six-time de-salination was conducted in the SSC solution for 8 hours at 100℃ and subsequently, for 16 hours at room temperature during which the distilled water and SSC were exchanged every week. However, in the case of a loaded rifle, the de-salination was not conducted, considering the risk that the high temperature and pressure by impregnation in vacuum could cause an explosion

Improved performance of corrugated metal gaskets in boiler’s piping system through multilayered coating

The corrugated metal gasket is still in the early stages of development. However, gasket contact flanges with a high surface roughness (more than 3.5 µm) leak and require a lot of force to tighten. A nickel or copper-coated corrugated metal gasket was designed. A water pressure test was used to measure leaks, and the results revealed that nickel or copper-covered gaskets performed better. The effect of high temperature has not been explored in this study, which only reveals high pressure. The goal of this study is to use copper and nickel coatings to improve the performance of corrugated metal gaskets. Copper or nickel infiltrates the pipe flange's rough surface, preventing leaking. The purpose of this study is to investigate the performance of a coated corrugated metal gasket in a boiler system, which has high temperature and pressure. Corrugated metal gaskets were formed using a cold forming process. The gasket material was SUS304, which is copper or nickel-plated through electroplating. The gasket was installed in a series of pipes in the boiler that flows water at high temperature and pressure. The water leak was trickling on white paper that had been placed beneath the gasket. Even small water leaks are detected on white paper. The thermal camera can detect vapor leaks. The results of the studies reveal that the coated corrugated metal gasket's performance was improved, as seen by the reduction in leakage. At the highest pressure of 7 bar and the lowest tightening force of 40 kN, neither gasket leaked. This result is different from standard corrugated metal gaskets, where at the same pressure and temperature, steam and water leaks are observed. Both copper and nickel-plating types can be used to coat corrugated metal gaskets made of SUS304.

The Pressure Buildup Well Test Analysis considering Stress Sensitivity Effect for Deepwater Composite Gas Reservoir with High Temperature and Pressure

Some deepwater gas reservoirs with high temperature and pressure have obvious stress sensitivity effect resulting in difficulty in well test interpretations. The influence of stress sensitivity effect on the pressure drawdown well test is discussed in many papers. However, the influence on the pressure buildup well test is barely discussed. For practices in oilfields, the quality of pressure data from the drawdown stage of well test is poor due to the influence of production fluctuation. Thus, the pressure data from the buildup stage is used for well test interpretations in most cases. In order to analyze the influence of stress sensitivity effect on the pressure buildup well test, this paper establishes a composite gas reservoir pressure buildup well test model considering the stress sensitivity effect and the hysteresis effect. Numerical solutions to both pressure drawdown and buildup well test models are obtained by the numerical differentiation method. The numerical solutions are verified by comparing with analytical solutions and the homogeneous gas reservoir well test solution. Then, the differences between pressure drawdown and buildup well test curves considering the stress sensitivity effect are compared. The parameter sensitivity analysis is conducted. Compared with the conventional well test curve, the pressure derivative curve of pressure drawdown well test considering the stress sensitivity effect deviates upward from the 0.5 horizontal line at the inner zone radial flow stage, while it deviates upward from the M/2 (mobility ratio/2) horizontal line at the outer zone radial flow stage. However, for the pressure buildup well test curve considering the stress sensitivity effect, the pressure derivative curve gradually descends to the 0.5 horizontal line at the inner zone radial flow stage, while it descends to the M/2 (mobility ratio/2) horizontal line at the outer zone radial flow stage. The pressure derivative curve of pressure buildup well test considering the hysteresis effect is higher than the curve without considering the hysteresis effect, because the permeability cannot be recovered to its original value in the buildup stage after considering the hysteresis effect. Meanwhile, skin factor and mobility ratio have different effects on pressure drawdown and buildup well test curves. Based on the model, a well test interpretation case from a deepwater gas reservoir with high temperature and pressure is studied. The result indicates that the accuracy of the interpretation is improved after considering the stress sensitivity effect, and the skin factor will be exaggerated without considering the stress sensitivity effect.

Colloidal Stability of Silica-Modified Magnetite Nanoparticles: Comparison of Various Dispersion Techniques

The production of stable and homogeneous batches during nanoparticle fabrication is challenging. Surface charging, as a stability determinant, was estimated for 3-aminopropyltriethoxysilane (APTES) coated pre-formed magnetite nanoparticles (MNPs). An important consideration for preparing stable and homogenous MNPs colloidal systems is the dispersion stage of pre-formed samples, which makes it feasible to increase the MNP reactive binding sites, to enhance functionality. The results gave evidence that the samples that had undergone stirring had a higher loading capacity towards polyanions, in terms of filler content, compared to the sonicated ones. These later results were likely due to the harsh effects of sonication (extremely high temperature and pressure in the cavities formed at the interfaces), which induced the destruction of the MNPs.

On the Jumps of Volume, Enthalpy and Entropy at the Melting Point, the Thermal Conductivity and Thermal Diffusivity for F.C.C. Au: the Temperature- and Pressure-Dependences

The melting temperature, the jumps of volume, enthalpy and entropy at the melting point, the isothermal compressibility, the thermal expansion coefficient, the heat capacity at constant volume, the Grüneisen parameter, the Debye temperature, the electrical resistivity, the thermal conductivity, and the thermal diffusivity for defective and perfect f.c.c. metals are studied by combining the statistical moment method (SMM), the limiting condition of the absolute stability of the crystalline state, the Clapeyron–Clausius equation, the Debye model, the Grüneisen equation, the Wiedemann–Franz law, and the Mott equation. Numerical calculations are carried out for Au under high temperature and pressure. The calculated melting curve of Au is in good agreement with experiments and other calculations. Obtained results are predictive and orient towards new experiments.

Development of Dynamic Tube Blocking Test Method to Study Halite Scale Deposition and Inhibition

Halite scaling has been observed in the oil/gas field with high TDS and low water cut. Due to its higher solubility, slight changes in temperature (T) and pressure (P) and evaporative effect could yield a large amount of scale, causing significant operational problems. Accurate prediction and control of halite scaling in the oil and gas production system have been a challenge. Therefore, this study aims to shed light on the prediction of halite scale formation, deposition behavior, and inhibition at close to oil field conditions. We have designed and developed a dynamic scale loop (DSL) test methodology that can be used at various T and P. The test method utilizes a change in temperature (ΔT) as a driving force to create halite supersaturation and follow with the scale precipitation/deposition. The tube blocking experiments suggest that the tube blockage can be caused by bulk precipitation and or deposition of halite precipitate. SEM analysis of the tube cross-sections indicated that tube blockage, presumably by bulk precipitation, could be seen at the beginning of the reaction tube, but deposition was observed towards the exit end of the tube. Similarly, various experimentation to simulate the water dilution at constant pressure and ΔT were conducted. The effect of the addition of water to prevent halite deposition was analyzed computationally by using ScaleSoftPitzer (SSP) software. Brine compatibility of several inhibitors were tested via bottle tests and autoclave tests and qualified inhibitors were tested in the tube blocking experiments to identify the performance of the inhibitor to treat the halite precipitation at high temperature and pressure. Overall, a robust test method was designed and developed for halite scaling under high temperature and pressure that can simulate the oil and gas production in the field.

Lightning-induced high temperature and pressure microstructures in surface and subsurface fulgurites

Cloud-to-ground lightning causes both high-temperature and high-pressure metamorphism of rocks, forming rock fulgurite. We demonstrate that a range of microstructural features indicative of high temperatures and pressures can form in fulgurites at the surface and in fractures up to several meters below the surface. In comparison to a granite reference sample collected from a borehole at a depth of 138 m, microstructures in both the surface and fracture fulgurite are characterized by: (i) the presence of glass, (ii) a phase transformation in K-feldspar with the presence of exsolution lamellae of plagioclase, and (iii) high residual stresses up to 1.5 GPa. Since this is the first time that fracture-related fulgurite has been described, we also carried out a 1-D numerical model to investigate the processes by which these can form. The model shows that the electric current density in fractures up to 40 m from the landing point can be as high as that on the surface, providing an explanation for the occurrence of fracture-related fulgurites. Our work broadens the near-surface environments in which rock fulgurite has been reported, and provides a detailed description of microstructures that can be compared to those formed during other types of extreme metamorphic events.