Extreme precipitating events in satellite and rain-gauge products over the Sahel

Over the recent decades, Extreme Precipitation Events (EPE) have become more frequent over the Sahel. Their properties, however, have so far received little attention. In this study the spatial distribution, intensity, seasonality and interannual variability of EPEs are examined, using both a reference dataset, based on a high-density rain-gauge network over Burkina Faso and 24 precipitation gridded datasets. The gridded datasets are evaluated in depth over Burkina Faso while their commonalities are used to document the EPE properties over the Sahel. EPEs are defined as the occurrence of daily-accumulated precipitation exceeding the all-day 99th percentile over a 1°x1° pixel. Over Burkina Faso, this percentile ranges between 21 and 33 mm day-1. The reference dataset show that EPEs occur in phase with the West African monsoon annual cycle, more frequently during the monsoon core season and during wet years. These results are consistent among the gridded datasets over Burkina Faso but also over the wider Sahel. The gridded datasets exhibit a wide diversity of skills when compared to the Burkinabe reference. The Global Precipitation Climatology Centre Full Data Daily version 1 (GPCC-FDDv1) and the Global Satellite Mapping of Precipitation gauge Reanalysis version 6.0 (GSMaP-gauge-RNL v6.0) are the only products that properly reproduce all of the EPE features examined in this work. The datasets using a combination of microwave and infrared measurements are prone to overestimate the EPE intensity, while infrared-only products generally underestimate it. Their calibrated versions perform than their uncalibrated (near-real-time) versions. This study finally emphasizes that the lack of rain-gauge data availability over the whole Sahel strongly impedes our ability to gain insights in EPE properties.

Implementation of SiN thin film in fiber-optic sensor working in telecommunication range of wavelengths

Mirrors are used in optical sensors and measurement setups. This creates a demand for mirrors made of new materials and having various properties tailored to specific applications. In this work, we propose silicon covered with a thin silicon nitride layer as a mirror for near-infrared measurements. SiN layer was deposited on a standard silicon wafer with a Low-Pressure Chemical Vapor Deposition furnace. Then, the created layer was investigated using ellipsometry and scanning electron microscope. Subsequently, the mirror was used as a reflecting surface in a Fabry–Perot fiber-optic interferometer. The mirror performance was investigated for wavelengths used in telecomunication (1310 nm and 1550 nm) and then compared with results obtained with the same measurement setup, with a silver mirror instead of silicon covered with SiN, as reference. Results showed that the proposed mirror can replace the silver one with satisfying results for investigated wavelengths.

Interannual Variability of the Lena River Plume Propagation in 1993–2020 during the Ice-Free Period on the Base of Satellite Salinity, Temperature, and Altimetry Measurements

The Lena River plume significantly affects the thermohaline, optical and chemical properties of the eastern Arctic seas. We use sea surface salinity (SSS), temperature (SST), and altimetry measurements to study features of the Lena plume propagation during 1993–2020. A comparison of Soil Moisture Active Passive (SMAP) SSS measurements with in situ data obtained using the flow-through system in oceanographic surveys in 2018–2019 demonstrates good coincidence with correlation ~ 0.96 and RMSD ~ 1 psu. The SMAP data were used to reconstruct the plume evolution in 2015–2020 and to identify three main types of Lena plume propagation, which are mainly related to the variability of dominant zonal wind direction: «northern»—the plume moves to the north from the delta up to 78° N; «eastern»—the plume moves eastward along the Siberian coast up to 180° E; «mixed» between two main types. Brackish plume waters were characterized by increased temperature and sea level, which provides the opportunity for studying the Lena plume dynamics using satellite altimetry and infrared measurements. These data were analyzed to study the interannual variability of plume propagation during the ice-free period of 1993–2020. The obtained results show that the «northern» type is observed twice more often than the «eastern» one, but the «eastern» type has intensified since 2010.

Simulated Multispectral Temperature and Atmospheric Composition Retrievals for the JPL GEO-IR Sounder

Satellite measurements enable quantification of atmospheric temperature, humidity, and trace gas vertical profiles. The majority of current instruments operate on polar orbiting satellites and either in the thermal/mid-wave or in the shortwave infrared spectral regions. We present a new multispectral instrument concept for improved measurements from geostationary orbit (GEO) with sensitivity to the boundary layer. The JPL GEO-IR sounder, which is an imaging Fourier Transform Spectrometer, uses a wide spectral range (1–15.4 μm), encompassing both reflected solar and thermal emission bands to improve sensitivity to the lower troposphere and boundary layer. We perform retrieval simulations for both clean and polluted scenarios that also encompass different temperature and humidity profiles. The results illustrate the benefits of combining shortwave and thermal infrared measurements. In particular, the former adds information in the boundary layer, while the latter helps to separate near-surface and mid-tropospheric variability. The performance of the JPL GEO-IR sounder is similar to or better than currently operational instruments. The proposed concept is expected to improve weather forecasting, severe storm tracking and forecasting, and also benefit local and global air quality and climate research.

Inverse Identification of the Ductile Failure Law for Ti6Al4V Based on Orthogonal Cutting Experimental Outcomes

Despite the prevalence of machining, tools and cutting conditions are often chosen based on empirical databases, which are hard to be made, and they are only valid in the range of conditions tested to develop it. Predictive numerical models have thus emerged as a promising approach. To function correctly, they require accurate data related to appropriate material properties (e.g., constitutive models, ductile failure law). Nevertheless, material characterization is usually carried out through thermomechanical tests, under conditions far different from those encountered in machining. In addition, segmented chips observed when cutting titanium alloys make it a challenge to develop an accurate model. At low cutting speeds, chip segmentation is assumed to be due to lack of ductility of the material. In this work, orthogonal cutting tests of Ti6Al4V alloy were carried out, varying the uncut chip thickness from 0.2 to 0.4 mm and the cutting speed from 2.5 to 7.5 m/min. The temperature in the shear zone was measured through infrared measurements with high resolution. It was observed experimentally, and in the FEM, that chip segmentation causes oscillations in the workpiece temperature, chip thickness and cutting forces. Moreover, workpiece temperature and cutting force signals were observed to be in counterphase, which was predicted by the ductile failure model. Oscillation frequency was employed in order to improve the ductile failure law by using inverse simulation, reducing the prediction error of segmentation frequency from more than 100% to an average error lower than 10%.

Fault Isolation for Desalting Processes Using Near-Infrared Measurements

Due to the important role of crude oil desalting for the whole petroleum refining process, the near-infrared spectroscopy resulting from molecular vibration is used to detect and isolate potential faults of the desalting process in this paper. With the molecular spectral data reflected by the near-infrared spectroscopy, the principal component analysis is adopted to monitor the process to see if it is in a normal operating condition or not. Considering the feature that the dimension of near-infrared spectroscopy is much larger than the sample size, the least absolute shrinkage and selection operator is employed to achieve an automatic variable selection procedure of the observed spectral data. Simultaneously, if some faults occur, the least absolute shrinkage and selection operator can be used to locate the spectral region affected by the failure. In such a way, the roots of faults can be tracked according to the change of the wavelength numbers. Performances of the proposed fault detection and isolation approaches are evaluated based on the near-infrared spectroscopy sampled for the crude oil desalting process to show the effectiveness.

Dual reference method for high precision infrared measurement of leaf surface temperature under field conditions

Temperature is a key control over biological activities from the cellular to the ecosystem scales. However, direct, high precision measurements of surface temperature of small objects such as leaves under field conditions with large variations in ambient conditions remain rare. Contact methods such as thermocouples are prone to large errors. The use of non-contact remote sensing methods such as thermal infrared measurements provides an ideal solution, but their accuracy has been low (in the order of ~2°C) due to necessity for corrections for material emissivity and fluctuations in background radiation (Lbg). A novel 'dual-reference' method was developed to increase the accuracy of infrared needle-leaf surface temperature measurements in the field. It accounts for variations in Lbg and corrects for the systematic camera offset using two reference plates. We accurately captured surface temperature and leaf-to-air temperature differences of needle-leaves in a forest ecosystem with large diurnal and seasonal temperature fluctuations with an uncertainty of ±0.23 and ±0.25°C, respectively. Routine high precision leaf temperature measurements even under harsh field conditions, such as demonstrated here, opens the way for investigating a wide range of leaf-scale processes and its dynamics.

Experimental and DFT studies on the structural and optical properties of chitosan/polyvinyle pyrrolidone/ZnS nano composites

Chitosan/ Polyvinyl pyrrolidone (CS/PVP) semi-natural polymeric blend involving gradient concentrations of ZnS nanoparticles (ZnS-NPS) was prepared via a simple casting method. In conjunction with computational density functional theory approaches (DFT), prepared samples were characterized by UV/Vis spectrophotometric studies and Fourier transform infrared measurements (FTIR) to take into account a detailed description of the different reaction mechanisms within the polymeric matrices. To conduct all calculations, the Becke three-parameter hybrid functional (B3LYP) correlation function used with the electron core potential basis set LANL2DZ was used. A detailed study for different reaction regimes was studied and reaction via Oxygen was observed to be preferred and compatible with that of the experimental data. UV/vis. Absorption experimental data were used to calculate the optical energy gap using the Mott-Davis equation and observed data was found to follow an indirect transition route.

Influence of Detector Size and Positioning on Near-Infrared Measurements and Iso-pathlength Point of Turbid Materials

Measuring physical phenomena in an experimental system is commonly limited by the detector. When dealing with spatially defined behaviors, the critical parameter is the detector size. In this work, we examine near-infrared (NIR) measurements of turbid media using different size detectors at different positions. We examine cylindrical and semi-infinite scattering samples and measure their intensity distribution. An apparent crossing point between samples with different scatterings was previously discovered and named the iso-pathlength point (IPL). Monte Carlo simulations show the expected changes due to an increase in detector size or similarly as the detector’s location is distanced from the turbid element. First, the simulations show that the intensity profile changes, as well as the apparent IPL. Next, we show the average optical pathlength, and as a result, the differential pathlength factor, are mostly influenced by the detector size in the range close to the source. Experimental measurements using different size detectors at different locations validate the influence of these parameters on the intensity profiles and apparent IPL point. These findings must be considered when assessing optical parameters based on multiple scattering models. In cases such as NIR assessment of tissue oxygenation, size and location may cause false results for absorption or optical path.