Chlorine Corrosion in a Low-Power Boiler Fired with Agricultural Biomass

The selection of appropriate heat-resistant materials which are at the same time resistant to atmospheres rich in chlorine and its compounds is one of the most important current construction problems in steel boiler elements when using biomass fuels of agricultural origin. In the research presented here, an area was identified in the furnace of a 10 kW boiler where there was a potential risk of chlorine corrosion. This zone was determined based on numerical analysis of the combustion process; it is the zone with the highest temperatures and where the gas atmosphere conducive to the formation of chlorine corrosion centers. Subsequently, tests were carried out in the process environment of the combustion chamber of a 10 kW boiler (the fuel was barley straw) by placing samples of eight construction materials in a numerically-designated zone. These included samples of steel (coal boiler St41K, heat-resistant H25T and H24JS, and heat-resistant valve 50H21G9N4) as well as intermetallic materials based on phases (FeAl, Fe3Al, NiAl, and Ni3Al). The samples remained in the atmosphere of the boiler furnace for 1152 h at a temperature of 750–900 °C. After this time, the surfaces of the samples were subjected to SEM microscopy and scanning analysis. The results showed that the St41K boiler steel was not suitable for operation under the assumed conditions, and that a thick layer of complex corrosion products was visible on its surface. The least amount of corrosion damage was observed for the samples of 50H21G9N4 steel and intermetallic materials.

Updating Subsurface Image of Khashim Al-Ahmer Gas Field Using the Interpretation for Anisotropic Velocity Model North-Eastern Iraq

This research deals with structural interpretation of Khashim Al-Ahmer Gas Field North-Eastern Iraq in Diyala Province, using the interpretation of inhomogeneous velocity data. The specific target in this field is the gaseous Jeribe reservoir representing the L. Miocene-Tertiary period. A very thick layer of evaporates Al-Fatha Formation is overlap the Jeribe Formation in the gas field and play as a sealed bed and transition zone for faults movement as a thrust fault. The thrust fault with gas content negatively affected the seismic energy, causing a high attenuation below the level of Al-Fatha Formation in the dome of the Khashm Al-Ahmer structure. Using the interval velocities derived from the sonic logs of five surrounding wells that represent the inhomogeneous behavior of the seismic wave velocity within the rock layers, a model of the velocity behavior in the field was built and the extent of the Jeribe gas reservoir was reconstructed according to the new velocities interpretation data.

Mulching with almond hull and olive leaves for weed control in fennel (Foeniculum vulgare Mill.) and flower beds

Weeds are a major problem in cropping systems and in urban areas. The aim of this study was to assess the effectiveness of organic mulching with olive leaves and almond hulls to control weeds in fennel (Foeniculum vulgare Mill.) and in flower beds (urban areas). A 3-cm thick layer of olive leaves or almond hulls was applied as mulching material in fennel. Control consisted of both an unmulched treatment and a weed free control. Moreover, in a flower bed of a railway station, plots mulched with 3 cm layer of olive leaves and almond hulls were compared with an unmulched treatment. Weed infestation was evaluated and the weights of the whole plant and of the marketable part of fennel (grumolo) measured. Mulching with olive leaves and almond hulls reduced weed infestation in both vegetable crop and flower beds. However, olive leaves reduced the weights of the whole plant and of the grumolo. The adoption of almond hulls and olive leaves as organic mulches could be an effective strategy for weed control. Further investigations should be carried out to assess whether the effectiveness of these mulching materials is mainly due to a mechanical activity or allelopathic compounds also play a significant role in weed suppression

Volcanic ash, victims, and tsunami debris from the Late Bronze Age Thera eruption discovered at Çeşme-Bağlararası (Turkey)

The Late Bronze Age Thera eruption was one of the largest natural disasters witnessed in human history. Its impact, consequences, and timing have dominated the discourse of ancient Mediterranean studies for nearly a century. Despite the eruption’s high intensity (Volcanic Explosivity Index 7; Dense Rock Equivalent of 78 to 86 km) [T. H. Druitt, F. W. McCoy, G. E. Vougioukalakis, Elements 15, 185–190 (2019)] and tsunami-generating capabilities [K. Minoura et al., Geology 28, 59–62 (2000)], few tsunami deposits are reported. In contrast, descriptions of pumice, ash, and tephra deposits are widely published. This mismatch may be an artifact of interpretive capabilities, given how rapidly tsunami sedimentology has advanced in recent years. A well-preserved volcanic ash layer and chaotic destruction horizon were identified in stratified deposits at Çeşme-Bağlararası, a western Anatolian/Aegean coastal archaeological site. To interpret these deposits, archaeological and sedimentological analysis (X-ray fluorescence spectroscopy instrumental neutron activation analysis, granulometry, micropaleontology, and radiocarbon dating) were performed. According to the results, the archaeological site was hit by a series of strong tsunamis that caused damage and erosion, leaving behind a thick layer of debris, distinguishable by its physical, biological, and chemical signature. An articulated human and dog skeleton discovered within the tsunami debris are in situ victims related to the Late Bronze Age Thera eruption event. Calibrated radiocarbon ages from well-constrained, short-lived organics from within the tsunami deposit constrain the event to no earlier than 1612 BCE. The deposit provides a time capsule that demonstrates the nature, enormity, and expansive geographic extent of this catastrophic event.

Peculiarities of Stratigraphic Distribution and Paleoecology of Jurassic Bivalve Mollusks of the Pre-Сarpathian Foredeep

Pre-Carpathian region is one of the oldest oil and gas producing regions of our country, which is attracting more and more attention of scientists. In the Outer zone of the Pre-Carpathian Foredeep, Jurassic deposits occur at considerable depths (up to 3,000 m), so we obtain almost all geological information about them exclusively during the study of core material selected during drilling. A comprehensive and detailed study of the Jurassic deposits of this zone during exploration drilling in the 1950s contributed to the discovery of the Kokhanivske and Sudovovyshnianske oil deposits and Rudkivske gas deposit, as well as a number of oil and gas manifestations. After that, the interest in the conditions of formation and stratification of Jurassic deposits increased. Researchers have begun to treat them as the promising objects for oil and gas exploration. Jurassic deposits in the Pre-Сarpathian Foredeep fill a single depression – the Stryi Jurassic deflection, covered by a thick layer of Cretaceous and Neogene rocks. The study of their geology and stratigraphy has acquired important applied and scientific significance, because stratigraphic research serves as a basis for clarifying the history of geological development of the region, performing tectonic constructions, reconstruction of paleogeographic and paleoecological conditions, comparison of productive horizons and specification of their stratigraphic position, search for new objects promising for hydrocarbons. Extremely rare finds of paleontological remains (which are not always well preserved) do not allow to unambiguously determining the age of the host rocks. It is still not always possible to clearly stratigraphically distinguish and correlate these rocks due to weak paleontological study and partial uncertainty in the interpretation of the geological structure of these strata. Despite the significant amount of research we have done, there are some debatable issues regarding the completeness of the section of these rocks and the presence of separate stratigraphic units in them. For many years, we have studied in detail and comprehensively bivalve mollusks found in the core of wells drilled in the Outer zone of the Pre-Carpathian Foredeep. As a result, the age of the host strata was specified and confirmed, as well as the thickness of individual stratigraphic units.

Modeling Asymmetry of a Current–Voltage Curve of a Novel MF-4SC/PTMSP Bilayer Membrane

A novel bilayer cation-exchange membrane—consisting of a thick layer of a pristine perfluorinated membrane MF-4SC (Russian equivalent of Nafion®-117) and a thinner layer (1 μm) of the membrane, on a base of glassy polymer of internal microporosity poly(1-trimethylsilyl-1-propyne) (PTMSP)—was prepared and characterized. Using the physicochemical characteristics of one-layer membranes MF-4SC and PTMSP in 0.05 M HCl and NaCl solutions, the asymmetric current–voltage curves (CVC) of the bilayer composite were described with good accuracy up to the overlimiting regime, based on the “fine-porous membrane” model. The MF-4SC/PTMSP bilayer composite has a significant asymmetry of CVC that is promising for using it in electromembrane devices, such as membrane detectors, sensors, and diodes.

Capture and Ex-Situ Analysis of Environmental Biofilms in Livestock Buildings

Little information about biofilm microbial communities on the surface of livestock buildings is available yet. While these spatially organized communities proliferate in close contact with animals and can harbor undesirable microorganisms, no standardized methods have been described to sample them non-destructively. We propose a reproducible coupon-based capture method associated with a set of complementary ex-situ analysis tools to describe the major features of those communities. To demonstrate the biofilm dynamics in a pig farm building, we analyzed the coupons on polymeric and metallic materials, as representative of these environments, over 4 weeks. Confocal laser scanning microscopy (CLSM) revealed a rapid coverage of the coupons with a thick layer of biological material and the existence of dispersed clusters of active metabolic microorganisms. After detaching the cells from the coupons, counts to quantify the CFU/cm2 were done with high reproducibility. High-throughput sequencing of the 16S rRNA V3-V4 region shows bacterial diversity profiles in accordance with reported bacteria diversity in pig intestinal ecosystems and reveals differences between materials. The coupon-based methodology allows us to deepen our knowledge on biofilm structure and composition on the surface of a pig farm and opens the door for application in different types of livestock buildings.

Directional Radial Drilling Increases Reservoir Coverage with Precise Wellbore Placement Resulting in a Significant Production Increase from a Thin Reservoir

In many oil and gas provinces not only in Russia, but throughout the world, carbonate strata make up a significant portion of the sedimentary cover, and large accumulations of hydrocarbons are associated with them. However, the purposeful study of them as reservoirs for hydrocarbons in our country practically began only in the post-war years. In the special petrography laboratory carbonate rocks composing various stratigraphic complexes of almost all oil and gas provinces of the Soviet Union were studied, and in particular, Paleozoic carbonate strata of the Timan-Pechora province, Ural-Volga region, Belarus, Kazakhstan, ancient Riphean-Cambrian formations of Yakutia and relatively young strata of the Late Cretaceous of the northeastern Ciscaucasia. Carbonates are widespread sedimentary rocks. A very significant part of them was formed in the conditions of vast shallow-water marine epicontinental basins. A large number of works are devoted to the study of such deposits. However, issues related to the conditions of formation of carbonate sediments and their postsedimentary changes cannot be considered resolved, as well as the classification of the rocks themselves. The analyzed field is the Osvanyurskoye one. It was discovered in 2007. The field is located in the north-east of the European part of the Russian Federation, 2 km from Usinsk in the Komi Republic. The field is a part of the Timano-Pechora oil and gas province and it is a mature field (fig. 1). The objective was a 2.5m thick layer of the Serpukhov horizon.

Restoring Well Productivity Through a Fit-for-Purpose Sludge Cleanout Job

Sludge formation could significantly impair well productivity if deposited in the wellbore or surface flow lines. In a field where sludge formation is not common, an oil production well showed a sudden deterioration in well productivity. Thorough investigation of abnormal well performance, from surface and sub-surface perspective, indicated that the deposition of a thick layer of a tight emulsion across the surface choke has resulted in ceasing the oil flow to the gas oil separation plant. Extensive lab analysis indicated that the obstruction material was a sludge deposition promoted by the presence of asphaltene, high amount of iron and low pH brine. It is noteworthy to mention that the analytical results of lab prepared emulsion samples elucidate the rule of low pH aqueous solution, asphaltene and iron ions in inducing tight emulsion formation which helps to understand the root causes of sludge deposition. To come up with a cost-effective remedial treatment considering health, safety and environment (HSE), different emulsion breaking formulations, including different de-emulsifiers and anti-sludge agents, were examined in this study. An effective diesel-based formulation including proper de-emulsifier and anti-sludging agent was used during the execution of the field job. The design of the field job took into consideration a minimal footprint to the environment through the flowback of the well to the neighboring gas oil separation plant. This paper summarizes the joint efforts by production engineers and lab scientists to systemically tackle such major flow assurance issues which could significantly jeopardize wells productivity. The systemic approach starts with problem detection through well intervention and sample collection. It also includes the lab work which was carried out to identify the type and composition of deposition and evaluate/optimize a proper formulation for sludge deposition removal. The paper discusses in detail the design and execution of a successful field treatment, which has resulted in restoring and maintaining the well potential.