solid phase extraction
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2022 ◽  
Vol 455 ◽  
pp. 214364
Author(s):  
Anna A. Kotova ◽  
Didier Thiebaut ◽  
Jérôme Vial ◽  
Antoine Tissot ◽  
Christian Serre

Polymers ◽  
2022 ◽  
Vol 14 (2) ◽  
pp. 311
Author(s):  
Ruth Oye Auke ◽  
Guilhem Arrachart ◽  
Romain Tavernier ◽  
Ghislain David ◽  
Stéphane Pellet-Rostaing

Rare-earth elements (REEs) are involved in most high technology devices and have become critical for many countries. The progress of processes for the extraction and recovery of REEs is therefore essential. Liquid–solid extraction methods are an attractive alternative to the conventional solvent extraction process used for the separation and/or purification of REEs. For this purpose, a solid-phase extraction system was investigated for the extraction and valorization of REEs. Ion-exchange resins were synthesized involving the condensation of terephthalaldehyde with resorcinol under alkaline conditions. The terephthalaldehyde, which is a non-hazardous aromatic dialdehyde, was used as an alternative to formaldehyde that is toxic and traditionally involved to prepare phenolic ion-exchange resins. The resulting formaldehyde-free resole-type phenolic resins were characterized and their ion-exchange capacity was investigated in regard to the extraction of rare-earth elements. We herein present a promising formaldehyde and phenol-free as a potential candidate for solid–liquid extraction REE with a capacity higher than 50 mg/g and the possibility to back-extract the REEs by a striping step using a 2 M HNO3 solution.


2022 ◽  
Author(s):  
zhikai hong ◽  
yingjiao dong ◽  
ruijie wang ◽  
Guanhua Wang

Covalent organic framework materials (COFs), a kind of porous organic material, have excellent potential application in the field of sample pretreatment due to their high surface areas and thermal stability....


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