Low-Impact Development (LID) in Coastal Watersheds: Infiltration Swale Pollutant Transfer in Transitional Tropical/Subtropical Climates

The control of runoff pollution is one of the advantages of low-impact development (LID) or sustainable drainage systems (SUDs), such as infiltration swales. Coastal areas may have characteristics that make the implementation of drainage systems difficult, such as sandy soils, shallow aquifers and flat terrains. The presence of contaminants was investigated through sampling and analysis of runoff, soil, and groundwater from a coastal region served by an infiltration swale located in southern Brazil. The swale proved to be very efficient in controlling the site’s urban drainage volumes even under intense tropical rainfall. Contaminants of Cd, Cu, Pb, Zn, Cr, Fe, Mn and Ni were identified at concentrations above the Brazilian regulatory limit (BRL) in both runoff and groundwater. Soil concentrations were low and within the regulatory limits, except for Cd. The soil was predominantly sandy, with neutral pH and low ionic exchange capacity, characteristic of coastal regions and not very suitable for contaminant retention. Thus, this kind of structure requires improvements for its use in similar environments, such as the use of adsorbents in soil swale to increase its retention capacity.

The Common Sunstar Crossaster papposus—A Neurotoxic Starfish

Saxitoxins (STXs) are a family of potent neurotoxins produced naturally by certain species of phytoplankton and cyanobacteria which are extremely toxic to mammalian nervous systems. The accumulation of STXs in bivalve molluscs can significantly impact animal and human health. Recent work conducted in the North Sea highlighted the widespread presence of various saxitoxins in a range of benthic organisms, with the common sunstar (Crossaster papposus) demonstrating high concentrations of saxitoxins. In this study, an extensive sampling program was undertaken across multiple seas surrounding the UK, with 146 starfish and 5 brittlestars of multiple species analysed for STXs. All the common sunstars analysed (n > 70) contained quantifiable levels of STXs, with the total concentrations ranging from 99 to 11,245 µg STX eq/kg. The common sunstars were statistically different in terms of toxin loading to all the other starfish species tested. Two distinct toxic profiles were observed in sunstars, a decarbomylsaxitoxin (dcSTX)-dominant profile which encompassed samples from most of the UK coast and an STX and gonyautoxin2 (GTX2) profile from the North Yorkshire coast of England. Compartmentalisation studies demonstrated that the female gonads exhibited the highest toxin concentrations of all the individual organs tested, with concentrations >40,000 µg STX eq/kg in one sample. All the sunstars, male or female, exhibited the presence of STXs in the skin, digestive glands and gonads. This study highlights that the common sunstar ubiquitously contains STXs, independent of the geographical location around the UK and often at concentrations many times higher than the current regulatory limits for STXs in molluscs; therefore, the common sunstar should be considered toxic hereafter.

Agronomic Factors Influencing the Scale of Fusarium Mycotoxin Contamination of Oats

Seven agronomic factors (crop season, farming system, harvest date, moisture, county, oat variety, and previous crop) were recorded for 202 oat crops grown across Ireland, and samples were analysed by LC-MS/MS for four major Fusarium mycotoxins: deoxynivalenol (DON), zearalenone (ZEN), T-2 toxin and HT-2 toxin. Type A trichothecenes were present in 62% of crops, with 7.4% exceeding European regulatory limits. DON (6.4%) and ZEN (9.9%) occurrences were relatively infrequent, though one and three samples were measured over their set limits, respectively. Overall, the type of farming system and the previous crop were the main factors identified as significantly influencing mycotoxin prevalence or concentration. Particularly, the adherence to an organic farming system and growing oats after a previous crop of grass were found to decrease contamination by type A trichothecenes. These are important findings and may provide valuable insights for many other types of cereal crops as Europe moves towards a much greater organic-based food system.

Big Data Analytics from a Wastewater Treatment Plant

Wastewater treatment plants (WWTPs) use considerable workforces and resources to meet the regulatory limits without mistakes. The advancement of information technology allowed for collecting large amounts of data from various sources using sophisticated sensors. Due to the lack of specialized tools and knowledge, operators and engineers cannot effectively extract meaningful and valuable information from large datasets. Unfortunately, the data are often stored digitally and then underutilized. Various data analytics techniques have been developed in the past few years. The methods are efficient for analyzing vast datasets. However, there is no wholly developed study in applying these techniques to assist wastewater treatment operation. Data analytics processes can immensely transform a large dataset into informative knowledge, such as hidden information, operational problems, or even a predictive model. The use of big data analytics will allow operators to have a much clear understanding of the operational status while saving the operation and maintenance costs and reducing the human resources required. Ultimately, the method can be applied to enhance the operational performance of the wastewater treatment infrastructure.

Contamination by Hazardous Elements in Low – Priced Children’s Plastic Toys Bought on the local Markets of Karachi, Pakistan

Children’s plastics toys maybe contain toxic metals to which infants and young children can be orally exposed and may pose acute or chronic adverse health effects. The objectives of this research were to evaluate the total metal concentrations (TMCs) of Pb, Cd, Cr, Ni, Zn, Cu, and Mn in children’s plastic Toys Bought in the local markets of Karachi, Pakistan, and compared TMCs to different regulatory limits. Total 44 children’s plastic toys sourced in the Karachi local markets had analyzed by an atomic absorption spectrophotometer for heavy metals contaminations. These toy samples had divided into two groups; Plastic toys (DCT) and Plastic toys with paints or coatings (DPCT). For plastic toys, 83% (19) of samples had TMCs that exceeded European Union (EU) toy safety regulation limits for Pb, and 65% (15) of samples that exceeded for Cd. For plastic toys with paints or coating, 43% (9) of samples had TMCs that exceeded EU migration limits for Pb and 24% (5) for Cd. More than 20 samples exceeded the United States Consumer Product Safety Commission (U.S. CPSC), Canadian, and Bureau of Indian Standards (BIS) toy safety regulation limits. In toys samples (n = 44) very high TMCs of Pb (64%), Cd (45%), Cr(5%), and Ni (2%) were observed. Zn, Cu, and Mn TMCs were also existing but below the Regulation limits. The Contamination levels of Pb, Cd, Cr, and Ni and smaller extent of Zn, Cu, and Mn still pose health issues in children and may cause serious problems in their health.

Agronomic Factors Influencing the Scale of Fusarium Mycotoxin Contamination of Oats

Seven agronomic factors (crop season, farming system, harvest date, moisture, county, oat variety, and previous crop) were recorded for 202 oat crops grown across Ireland, and samples were analysed by LC-MS/MS for four major Fusarium mycotoxins: deoxynivalenol (DON), zearalenone (ZEN), T-2 toxin and HT-2 toxin. Type A trichothecenes were present in 62% of crops, with 7.4% exceeding European regulatory limits. DON (6.4%) and ZEN (9.9%) occurrences were rela-tively infrequent, though one and three samples were measured over their set limits respectively. Overall, the type of farming system and the previous crop were the main factors identified to significantly influence mycotoxin prevalence or concentration. Particularly, adherence to an organic farming system and growing oats after a previous crop of grass were found to decrease contamination by type A trichothecenes. These are important findings and may provide valuable insights for many other types of cereals crops as Europe moves towards a much greater organic based food system.

Sustainable Applications for Utilizing Antimony Tailing Coarse Aggregate (ATCA) in Concrete: Characteristic of ATCA and Toxicity Risks of Concrete

In this research, the sustainable applications for utilizing antimony tailing coarse aggregate (ATCA) in concrete is investigated. Comprehensive verifications were performed by a series of experiments on the characteristic of ATCA and the toxicity risks of concrete. Firstly, a real case study of utilization of ATCA as a complete substitute for natural coarse aggregate (NCA) in high strength concrete was conducted. Then, chemical composition of ATCA was tested. It is demonstrated that the essential mineral is SiO2 and the lithology of ATCA is quartzite. The mechanical properties, coarse quality of ATCA, and NCA were studied and compared. The compressive strength, splitting tensile strength, and compressive elastic modulus of ATWR are 221.51 MPa, 5.93 MPa, and 3.33 × 104 MPa, which are 1.31, 2.22, 1.40 times of that of NR, respectively. All of the quality control indices of ATCA meet the requirements of the current industry standards of China. Finally, the toxicity risks of ATCA concrete were investigated. It is illustrated that the leaching of main heavy metals including Sb, As, Hg, Pb, Cd, and Zn in the ATCA concrete under different pH conditions are below the regulatory limits. The utilization of antimony tailing has significant environmental and economic benefits.

Radiological Risk Assessment of Vehicle Transport Accidents Associated with Consumer Products Containing NaturallyOccurring Radioactive Materials

Natural and artificial ionizing radiation can be harmful to human health when they come into contact with people and the environment. Transport of naturally occurring radioactive materials (NORMs) and consumer products containing NORM in the public domain is inevitable owing to their potential applications. This study evaluates the dose and risk to the public from transport accidents of NORM and consumer products. Radiological and physical data were obtained from previous literature. The median and maximum values of radioactivity concentration were applied to consumer products and NORM data, which serve as an input. An external dose rate at 1 m from a transported shipment was calculated using MicroShield® Pro version 12.11 code, which serves as input to RADTRAN 6 code. Based on developed transport accident scenarios, a RADTRAN 6 code was used to estimate collective dose and risk. The sensitivity analysis was conducted by considering the variation of release, aerosol, and respirable fractions of radionuclides at 0.1%, 1%, 10%, and 100% from the transported shipment during an accident, respectively. The results of dose and risk to the general public because of the damage of the shipment container following a fire accident are below the annual regulatory limits of 1 man-Sv recommended by IAEA transport regulation of 2018. The sensitivity results of all NORMs and associated consumer products are also below the regulatory limits. Therefore, radiological safety can be ensured in the event of a transport accident involving the transit of NORM and consumer products containing NORM.

Applying real-world data to justify requirements to purchased drugs in public procurement

The article describes the approaches of law enforcement practice in relation to the regulatory limits within which a medical institution may exercise it's right to establish requirements for purchased drugs based on purchaser's clinical practice and its own clinical experience.

Far-UVC efficiently inactivates an airborne pathogen in a room-sized chamber

Many infectious diseases, including COVID-19, are transmitted by airborne pathogens. There is a need for effective environmental control measures which, ideally, are not reliant on human behaviour. One potential solution is Far-UVC which can efficiently inactivate pathogens, such as coronaviruses and influenza, in air. When appropriately filtered, and because of its limited penetration, there is evidence that Far-UVC does not induce acute reactions in the skin or eyes, nor delayed effects such as skin cancer. While there is laboratory evidence for far-UVC efficacy, there is limited evidence in full-sized rooms. In the first study of its type, we show that Far-UVC deployed in a room-sized chamber effectively inactivates aerosolised Staphylococcus aureus. At a room ventilation rate of 3 air changes per hour (ACH), with 5 filtered sources the steady-state pathogen load was reduced by 92.1% providing an additional 35 equivalent air changes (eACH). This reduction was achieved using Far-UVC intensities consistent with current regulatory limits. Far-UVC is likely to be more effective against common airborne viruses, including SARS-CoV-2, and should thus be an effective and “hands-off” technology to reduce airborne disease transmission. The findings provide room-scale data to support the design and development of safe and effective Far-UVC systems.