Study of Ratio Variation of Binary Components of Cross Linking Agent on Extent of Polymerization and Mechanical Properties of Polyurethane Composites

Polyethylene glycol based polyurethane polymer and its fly ash reinforced polyurethane composite were prepared by optimizing the concentration ratio of binders, cross linking agents and curing agents. The components ratio of cross linking agents with the same hydroxyl functionalities i.e. 1,4-butane diol and 1,1,1-trimethylol propane affects the mechanical properties of polymer. The extent of polymerization of polyurethane matrix and fly ash reinforced polyurethane composite was found to be independent of the component ratio of cross linking agents. PEG based polyurethane polymer and their fly ash-reinforced composite can be synthesized at particular ratio by mass of cross linking agents i.e. 0.5 keeping constant w/w ratio 3:2 of binders and curing agents. Effect of w/w ratio variation of cross linking agents on the extent of polymerization has been studied through SEM technique. Cross linking agents, curing agents and polyurethane composite have been characterized by IR spectra. Effect of w/w ratio variation of binary components 1,4-butane diol and 1,1,1-trimethylol propane of cross linking agents on the mechanical properties of fly ash-reinforced polyurethane composite has been studied by evaluating tensile strength and Young modulus of composite material by universal testing machine. Hardness of fly ash-reinforced polyurethane composite with different ratio of 1,4-butane diol and 1,1,1-trimethylol propane of cross linking agents was evaluated by durometer

Nb and Ta benzotriazole or benzoxazole phenoxide complexes as catalysts for the ring-opening polymerization of glycidol to synthesize hyperbranched polyglycerols

New approach for synthesizing hyper branched polyethers using organometallic Nb and Ta complexes as catalysts and trimethylol propane as initiator was demonstrated.

Electron Beam Crosslinking of EVA/ENR-50/HNTS Nanocomposites in the Presence of Trimethylol Propane Triacrylate, TMPTA

Ethylene vinyl acetate/ Epoxidised natural rubber/ Halloysite nanotube (EVA/ENR-50/HNT) nanocomposite was prepared through melt blending process using twin screw extruder at 120 oC and 50 rpm of screw speed. The ratio of EVA/ENR-50/HNT was fixed at 80:20:4. The nanocomposites were irradiated with a 3.0 MeV electron beam machine at doses ranging from 50 to 200 kGy in air at room temperature. The effect of irradiation dose and co-agent Trimethylol Propane Triacrylate (TMPTA) on tensile strength and gel content of EVA/ENR-50/HNT nanocomposite were studied. It was found that the tensile strength and gel fraction of the EVA/ENR-50/HNT nanocomposites increased with the increased of irradiation dose. In the presence of TMPTA, a better performance in tensile strength was achieved due to the increased efficiency of irradiation induce crosslinking of EVA/ENR-50/HNT nanocomposite.