Characterization and Modeling Study on Softening and Seepage Behavior of Weakly Cemented Sandy Mudstone after Water Injection

Water injection-induced rock softening and the associated water seepage characteristics are the common and basic problems in underground reservoir construction and the prevention of mine water disaster. In this paper, a series of experimental studies was carried out to investigate these characteristics with the weakly cemented sandy mudstone collected from Shendong Buertai coal mine, China. The characteristics of water softening and the stress-seepage interactions in water-saturated weakly cemented sandy mudstone were directly obtained. Then, a modification method of the constitutive model for rock mass considering the softening effect and a stress-damage-driven model for permeability evolution were established. Research results show that water saturation reduces the tensile strength, compressive strength, and cohesion by 56% and reduces the elastic modulus by 28%. The hydraulic effects on Poisson’s ratio and internal friction angle are negligible. The relationship between the permeability of weakly cemented sandy mudstone with complete compaction deformation is to be divided into three stages of seepage shielding, seepage surge, and seepage recovery. Rock permeability in each stage has a negative exponential relationship with the effective stress. This research provides a theoretical basis for the researches of hydromechanical couplings on weakly cemented sandy mudstone, which is insightful for rock engineering practice.

Materials degradation in non-thermal plasma generators by corona discharge

Atmospheric corona discharge devices are being studied as innovative systems for cooling, sterilization, and propulsion, in several industrial fields, from robotics to medical devices, from drones to space applications. However, their industrial scale implementation still requires additional understanding of several complex phenomena, such as corrosion, degradation, and fatigue behaviour, which may affect final system performance. This study focuses on the corrosive behaviour of wires that perform as a high-voltage electrode subject to DC positive corona discharge in atmospheric air. The experiments demonstrate that the non-thermal plasma process promotes the growth of the oxidative films and modifies the physicochemical properties of the materials chosen as corona electrodes, hence affecting device operation. Surfaces exposed to this non-thermal plasma are electrically characterized by negative exponential decay of time-depend power and analysed with SEM. Implications on performance are analysed and discussed.

Estimation of Infiltration Volumes and Rates in Seasonally Water-Filled Topographic Depressions Based on Remote-Sensing Time Series

In semi-arid ecoregions of temperate zones, focused snowmelt water infiltration in topographic depressions is a key, but imperfectly understood, groundwater recharge mechanism. Routine monitoring is precluded by the abundance of depressions. We have used remote-sensing data to construct mass balances and estimate volumes of temporary ponds in the Tambov area of Russia. First, small water bodies were automatically recognized in each of a time series of high-resolution Planet Labs images taken in April and May 2021 by object-oriented supervised classification. A training set of water pixels defined in one of the latest images using a small unmanned aerial vehicle enabled high-confidence predictions of water pixels in the earlier images (Cohen’s Κ = 0.99). A digital elevation model was used to estimate the ponds’ water volumes, which decreased with time following a negative exponential equation. The power of the exponent did not systematically depend on the pond size. With adjustment for estimates of daily Penman evaporation, function-based interpolation of the water bodies’ areas and volumes allowed calculation of daily infiltration into the depression beds. The infiltration was maximal (5–40 mm/day) at onset of spring and decreased with time during the study period. Use of the spatially variable infiltration rates improved steady-state shallow groundwater simulations.

Ablation Patterns of the Debris Covered Tongue of Halong Glacier Revealed by Short Term Unmanned Aerial Vehicle Surveys

Debris-covered glaciers are an important glacier type and have attracted more and more attention. This study presents the results of ablation patterns of debris-covered tongue of the Halong Glacier in the northeastern Tibetan Plateau, by using two repeated unmanned aerial vehicle (UAV) surveys performed on August 11 and September 15, 2019. The results show that the tongue of Halong Glacier has experienced strong ablation during the surveyed period, with an overall ice loss amount to 4.17 × 105 metric tons Among all the briefly classified surface types, supraglacial debris has the largest area (80.9%) and also mass losses (58.6%) comparing to others. However, ice cliffs show the strongest and the most significant ablation rates (averagely 1.36 and 1.22 m w.e. for supraglacial and lateral ice cliffs, respectively), followed by clean ice regions (1.01 m w.e.). The backwastes of ice cliffs also resulted in up to 7.8 m horizontal back-off at different parts of Halong Glacier, lead to fast terminal retreat and narrowing down of the glacier tongue, and may result in the break off of Halong Glacier tongue into separated parts in the future. The surface ablation rates show a clear negative exponential relationship with the measured debris thicknesses, well in accordance with previous studies. Regions in cutting and flushing by supraglacial and lateral rivers have the largest surface elevation decreases but are not significant due to their limited area and the relatively lower quality of UAV digital surface models (DSMs) in those covered regions.

Image-based goniometric appearance characterisation of bronze patinas

Patinas are a form of metal polychromy used to decorate metallic artworks. Due to the nature of the metallic surface, their colour and gloss is perceived differently when the illumination and viewing directions vary. Sparkle effect on surfaces is a physical phenomenom caused by micro-facets on the surface coating which are also perceived with changing viewing and illumination geometry. In this paper, a method designed for the measurement of sparkle is applied for the goniometric characterisation of bronze patinas. Using a set of six different patinas, in three colours and two surface finishes, it is found that these surfaces exhibit different appearance when illuminated and viewed at different angles. Moreover, the roughness of the patinas is measured and as expected, as the roughness increases the specular reflection peak decreases. The experiment is repeated at two different institutions with different sets of equipment to test its repeatability and robustness. The sparkle is presented as a function of the angle of tilting, and it is characterised by its maximum value and full-width halfmaximum. It is found that the maximum and the roughness have a negative exponential relationship whereas the full-width halfmaximum and the roughness have a linear relationship.

Controlled Release Study on Bifidocin A from a Polyvinyl Alcohol/Chitosan Blend Particle-Based Biodegradable and Active Packaging Coupled with Mechanistic Assessment and Experimental Modeling

On the basis of PVA-CS, which is incorporated with Bifidocin A, anti-microbial biodegradable films were prepared, characterized by their abilities to control the Bifidocin A’s total release rate into foods as needed for packaging of active foods. This study aimed to explore the anti-microbial effects and release kinetics of active substances in polyvinyl alcoholchitosan (PVA-CS) particle composite films added with Bifidocin A. Pseudomonas fluorescens was used as indicator bacteria to evaluate the anti-microbial activity of the films. Fick’s law, power law and negative exponential growth model were applied to further study the release kinetics of Bifidocin A. The results revealed that the composite films of PVA and CS had better mechanical properties and anti-microbial activity when the content of Bifidocin A was 50% with 1:1 PVA/CS, but it impairs the structure of the film, which can be resolved by including a suitable amount of grycerol. The anti-microbial was released faster at higher temperature and concentration of Bifidocin A, and the diffusion coeffcients increased significantlywith the increase of temperature and concentration. According to the thermodynamic parameters, the release of Bifidocin A was endothermic and spontaneous. High correlation factors (R2 > 0.99) were acquired by fitting the release data of the Bifidocin A with the negative exponential growth model. The potential of Bifidocin A to deliver from the films into the food analog appropriately at low temperatures favored the obtained active films to be applied on food packaging, especially suitable for refrigerated foods.

Study on the Mechanical Characteristics of the Screw Driving Torque during the Emptying of the Shield Soil Bin

This article studies the changing law of the driving torque of the screw conveyor during the emptying process of the earth pressure balance shield chamber. First, the discrete element method of discrete medium theory and 3D software SolidWorks were used to create the research object and the screw conveyor model, and then the model parameters were determined and calibrated through numerical calculations and indoor experiments. The final numerical calculation results show that: 1) the screw torque will drop in waves with the increase of the calculation time. When the screw conveyor rotates at 360 deg/s, the calculated screw torque fluctuation amplitude is small; 2) when the number of particles in the soil bin is reduced to a certain extent, the use of a higher screw speed to improve the “dumping soil effect” is of little significance; 3) the negative exponential function can be used to better fit the decrease of screw torque with time; 4) for the bulk medium, for a given particle size and screw structure, there is a suitable speed, so that the effect of “machine-soil collision” is small, and the torque change of the screw is relatively stable.

Comparison of Two Different Analytical Forms of Response for Fractional Oscillation Equation

The impulse response of the fractional oscillation equation was investigated, where the damping term was characterized by means of the Riemann–Liouville fractional derivative with the order α satisfying 0≤α≤2. Two different analytical forms of the response were obtained by using the two different methods of inverse Laplace transform. The first analytical form is a series composed of positive powers of t, which converges rapidly for a small t. The second form is a sum of a damped harmonic oscillation with negative exponential amplitude and a decayed function in the form of an infinite integral, where the infinite integral converges rapidly for a large t. Furthermore, the Gauss–Laguerre quadrature formula was used for numerical calculation of the infinite integral to generate an analytical approximation to the response. The asymptotic behaviours for a small t and large t were obtained from the two forms of response. The second form provides more details for the response and is applicable for a larger range of t. The results include that of the integer-order cases, α= 0, 1 and 2.

A Computational Model for Oxygen Depletion Hypothesis in FLASH Effect

Experiments have reported low normal tissue toxicities during FLASH irradiation, but the mechanism has not been elaborated. Several hypotheses have been proposed to explain the mechanism. One hypothesis is oxygen depletion. We analyze the time-dependent change of oxygen concentration in the tissue to study the oxygen depletion hypothesis using a computational model. The effects of physical, chemical and physiological parameters on oxygen depletion were explored. The kinetic equation of the model is solved numerically using the finite difference method with rational boundary conditions. Results of oxygen distribution is supported by the experiments of oxygen-sensitivity electrodes and experiments on the expression and distribution of the hypoxia-inducible factors. The analysis of parameters shows that the steady-state oxygen distribution before irradiation is determined by the oxygen consumption rate of the tissue and the microvessel density. The change of oxygen concentration after irradiation has been found to follow a negative exponential function, and the time constant is mainly determined by the microvessel density. The change of oxygen during exposure increases with dose rate and tends to be saturated because of oxygen diffusion. When the dose rate is high enough, the same dose results in the same reduction of oxygen concentration regardless of dose rate. The analysis of the FLASH effect in the brain tissue based on this model does not support the explanation of the oxygen depletion hypothesis. The oxygen depletion hypothesis remains controversial because the oxygen in most normal tissues cannot be depleted to radiation resistance level by FLASH irradiation.

Characterization and Modeling Study on Softening and Seepage Behavior of Weakly Cemented Sandy Mudstone After Water Injection

Water injection induced rock softening and the associated water seepage characteristics are the common and basic problems in hard roof pressure relief, underground reservoir construction and the prevention of mine water disaster. In this paper, a series of laboratory studies was carried out to investigate these characteristics with the weakly cemented sandy mudstone collected from Shendong Buertai coal mine, China. The characteristics of water softening and the stress-seepage interactions in saturated weekly cemented sandy mudstone were directly obtained. Then a modification method of the constitutive model for rock mass considering the softening effect and a stress-damage-driven model for permeability evolution were established. Research results show that water saturation reduces the tensile strength, compressive strength and cohesion by 56%, and reduces the elastic modulus by 28%. The hydraulic effect on Poisson’s ratio and internal friction angle is negligible. The relationship between the permeability of weakly cemented sandy mudstone with complete compaction deformation is to be divided into three stages of seepage shielding, seepage surge and seepage recovery. Rock permeability in each stage has a negative exponential relationship with the effective stress. This research provides a theoretical basis for the researches of hydro-mechanical couplings on weakly cemented sandy mudstone, which is insightful for rock engineering practice.