Towards the Biobeneficiation of PGMs: Reviewing the Opportunities

Conventional beneficiation of the Platinum Group of Metals (PGMs) relies on the use of inorganic chemicals. With the depreciation of high grade deposits, these conventional processes are becoming less economically viable. Furthermore, the use of chemicals has serious negative impacts on the environment. To address the challenges of conventional PGM beneficiation, biobeneficiation has been proposed. In conventional flotation, the flotation behavior of the associated sulphides determines overall PGM recovery. The same principle may also be applied for the bio-beneficiation of PGMs. Therefore, this paper discusses the biobeneficiation behavior of sulphides closely associated with PGMs with the aim of postulating the bio-beneficiation behavior of PGMs associated with the same base metal sulphides. Conventional PGM processes are briefly discussed, as bio-beneficiation of PGMs is governed by similar underlying principles. Potential microorganisms for the biobeneficiation of PGMs are highlighted, as well as the corresponding conditions for their effectiveness. The use of both single cultures and mixed cultures is discussed. Depending on conditions, PGMs associated with pyrite and/or chalcopyrite were projected to be biofloatable with B. polymyxa, P. polymyxa, A. ferrooxidans, L. ferrooxidans, B. pumilus, B. subtilis, halophilic bacteria, Alicyclobacillus ferrooxidans, sulphate reducing bacteria, and mixed cultures of A. ferrooxidans, A. thiooxidans and L. ferrooxidans. Pyrite-associated PGMsare expected to be generally prone to biodepression, whereas chalcopyrite-associated PGMs are expected to be generally recovered as the floatable phase. Sulphate-reducing bacteria were reported to have a dual role on the bioflotation of sulphide ores (flotation and depression), depending on the conditions. Therefore, this type of microorganism may serve as both a depressant or a collector in the recovery of PGMs. Based on the bioflotation response of pyrrhotite to L. ferrooxidans, it is anticipated that pyrrhotite-associated PGMS can be biodepressed using L. ferrooxidans. In terms of bioflocculation, PGMs associated with chalcopyrite may be recovered using L. ferrooxidans, whereas A. ferrooxidans, A. thiooxidans, B. polyxyma and B. subtilis can be used in the bioflocculation of pyrite-associated PGMs. M. phlei can be employed in the reverse bioflocculation of pyrite-associated PGMs. Although no information was found on the biobeneficiation of pentlandite, postulations were made based on other sulphide minerals. It was postulated that biobeneficiation (biodepression and bioflotation) with pentlandite-associated PGMs should be possible using A. ferrooxidans. It is also projected that sulphate-reducing bacteria will be suitable for the bioflotation of PGMs associated with pentlandite. The removal of gangue species such as silicates and chromites associated with PGM concentrates was also discussed. A. ferrooxidans, P. polymyxa and B. mucilaginous are candidates for the removal of gangue species. Furthermore, the need to control process conditions was highlighted. The most suitable conditions for biobeneficiation of the various base metal sulphide minerals associated with PGMs are presented in the paper. Most of the challenges associated with biobeneficiation of PGMs are already common to conventional methods, and the means of circumventing them are already well established. Developments in genetic engineering and the advent of new data science techniques are tools that could make the biobeneficiation of PGMs a possibility.

Improvement of the Thermocouple Method for Testing Energy-Intensive Emulsions for Compatibility with the Sulfide Ores

The results are presented concerning improving the thermostatic method for studying the chemical compatibility of modern industrial emulsion explosives based on the ammonium nitrate with surrounding materials, the increased reactivity of which can lead to spontaneous ignition and even explosion. An assessment of the compatibility of emulsion explosives with sulphide ores was conducted using an original thermocouple methodology developed at the D. Mendeleyev University of Chemical Technology of Russia, fixation of the thermal effects of the interaction of shell-free explosives based on the ammonium nitrate with sulfide minerals. Improved thermocouple method allows to determine chemical compatibility of the industrial explosives with the reactive rocks. It is distinguished by the possibility of continuous recording of the thermocouple measurements during tests using an oscilloscope and combines the reliability of the results with small laboratory weights of the test samples (no more than 20 g, which ensures safety testing). Temperature measurement accuracy is ± 2 °С. It is concluded that the method used is able to identify the cases of the most dangerous interaction from the practice point of view using the emulsion explosives when the pyrite content in the ore exceeds 85 %. The results of experiments on the applicability of thermocouple measurements to testing low-activity rocks, highly reactive pyrite ores, mixed sulfide ores of medium activity, as well as on the identification of the main regularities of heat release during the interaction of emulsion explosives with the sulfide ores are considered.

Effect of Microwave Pretreatment on Leaching of Tetrahedrite

In mineral processing, the use of microwave radiation is important especially in pre-treatment processes. At present, there is an acceleration of processes as well as an increase in the efficiency of metal recovery. One of the main problems in copper recovery from complex sulphide ores is the removal of impurities such as antimony, arsenic, mercury. In the hydrometallurgical processing scheme, the key step is the leaching. The extraction process can be influenced by the selection of suitable leaching reagents or by suitable pre-treatment of the ore. The article describes the effect of microwave radiation on the leaching Sb, As and Hg of tetrahedrite and tetrahedrite concentrate. The samples were irradiated at the power 900 W for 30 seconds. The leaching of irradiated and non-irradiated samples was realized in an alkaline sodium sulphide. The positive effect of microwave radiation was confirmed by an increase in the recovery of Sb and As already after 15 min of extraction. After microwave leaching of irradiated tetrahedrite samples, the yield of Sb was 43.2 %, in irradiated tetrahedrite concentrate, the yield of Sb was 81.3 %.

Pretreatment to Leaching for a Primary Copper Sulphide Ore in Chloride Media

The dissolution of copper sulphide ores continues to be a challenge for the copper industry. Several media and leaching alternatives have been proposed to improve the dissolution of these minerals, especially for the leaching of chalcopyrite. Among the alternatives, pretreatment prior to leaching was proposed as an option that increases the dissolution of copper from sulphide ores. In this study, a mineral sample from a copper mining company was used. The copper grade of the sample was 0.79%, and its main contributor was chalcopyrite (84%). The effect of curing time (as pretreatment) in a chloride media on copper sulphide ore was evaluated at various temperatures: 25, 50, 70 and 90 °C. The pretreated sample and leaching residues were characterized by X-ray diffraction, scanning electron microscopy, and reflected light microscopy. Pretreatment products such as CuSO4, NaFe3(SO4)2(OH)6, and S0 were identified although with difficulty, due to the low presence of chalcopyrite in the initial sample (1.99%). Under the conditions of 15 kg/t of H2SO4, 25 kg/t of NaCl, and 15 days of curing time, a copper extraction of 93.1% was obtained at 90 °C with 50 g/L of Cl− and 0.2 M of H2SO4.

Research and complete the processing technology of Son La oxide copper ores for the Tay Bac Minerals Joint Stock Company

The copper ore processing plant of the Tay Bac Minerals Joint Stock Company has been designed and operated to produce metallic copper from copper sulphide ores and copper oxide ores in Son La province. Copper sulphide ores are processed to produce copper concentrates with content of more than 20% Cu for the next processing stage, while copper oxide ores, with average content of 1÷3% Cu and after grinding, are fed directly into hydrometallurgical processes to extract copper. However, this process requires large amount of chemicals. Therefore, the economic efficiency is not high. The National Institute of Mining - Metallurgy Science and Technology has researched and proposed a reasonable technology process for Son La copper oxide ores for solving difficulties and perfecting the processing technology at the plant that improves economic efficiency and minimizes environmental pollutions. This report presents results of the experimental production research project with the code CNKK.013.19, implemented by the Institute of Materials Science and sponsored by the Ministry of Industry and Trade.

The Effects of Sulphuric Acid and Sodium Chloride Agglomeration and Curing on Chalcopyrite Leaching

An option to improve the leaching efficiency of chalcopyrite is pretreatment prior to leaching. Pretreatment variables, such as the curing time and the addition of chloride, can increase the kinetics of copper extraction, particularly for sulphide ores. However, there has been little research on the topic. The reactions that govern this phenomenon have not been clearly identified. In this study, the effects of sulphuric acid and sodium chloride agglomeration and curing on chalcopyrite leaching were evaluated at various temperatures: 25, 50, 70, and 90 °C. The pretreated ore and leach residues were characterised by X-ray diffraction, scanning electron microscopy, and reflected light microscopy. Under the conditions of 15 kg/t of H2SO4, 25 kg/t of NaCl, and 15 days of curing time (as pretreatment), the following products were identified: CuSO4, NaFe3(SO4)2(OH)6, Cu2Cl(OH), and S0. Increasing the curing time and leaching temperature increased copper leaching. The copper extraction was 94% when leaching at 90 °C after pretreatment with 50 g/L of Cl- and 0.2 M of H2SO4. Elemental sulphur, jarosite, and copper polysulphide (CuS2) were detected in the leaching residues.

Acidophilic chemolithotrophic microorganisms: prospects for use in biohydrometallurgy and microbial fuel cells

Acidophilic chemolithotrophic microorganisms are used in biohydrometallurgy for the extraction of metals from sulphide ores. Some types of microorganisms belonging to this group are capable of generating electricity under certain conditions. This circumstance determined a recent upsurge of research interest in their use in biofuel cells. Under a constant supply of the substrate to the bioelectrochemical system, acidophilic chemolithotrophic microorganisms are capable of producing electricity for a prolonged period of time. The use of extremophiles in microbial fuel cells is of particular interest, since these microorganisms can serve as bioelectrocatalysts at extreme pH, salinity and temperature, while the vast majority of microorganisms are unable to survive under these conditions. Therefore, selection of optimal conditions and approaches to controlling the work of acidophilic chemolithotrophic microorganisms in such fuel cells is of particular importance. On this basis, a technology for the simulteneous bioleaching of metals from poor ores and the generation of electricity can be developed. Biofuel cells operating at low pH values using acidophilic chemolithotrophic microorganisms are yet to be investigated. The number of studies on acidophilic electroactive microorganisms is very limited. In this regard, the purpose of this review was to consider the prospects for the use of acidophilic chemolithotrophic microorganisms as bioagents in microbial fuel cells. The reviewed publications demonstrate that chemolithotrophic microorganisms can act as both anodic (metal-reducing, sulphur-oxidizing microorganisms) and cathodic (metal-oxidizing prokaryotes, sulfate reducers) highly efficient bioagents capable of using mining wastes as substrates.

Flotation of Vostok-2 skarn scheelite sulphide ore with modifiers

This paper describes the results of a study that looked at different reagent regimes of flotation of scheelite skarn ores with soda, sodium bicarbonate and sodium sulphide. According to published research data, these regimes of selective recovery scheelite from Skarn ores of Portuguese and Chinese deposits as an alternative to Petrov method. The results of studying the changes of the optical density of water glass in mixing with soda, sodium bicarbonate and sodium hydroxide at different temperatures are presented. Gelation of water glass is observed in a mixture of soda or sodium bicarbonate. The authors were studied the floatability of calcium minerals of scheelite sulphide ore by combined depressants (water glass and sodium sulphide), their dose (0–11.4 kg/t) and proportions (0.7 to 8), as well as the duration of conditioning at the Laboratory of Primorsky Concentrating Plant (PCP). In the course of research, it was established that a high dose of soda and sodium bicarbonate in the scheelite rougher flotation cycle determines a 2- to 6-times higher yield of rough scheelite concentrate with a 1.8-times lower WO3 enrichment ratio. A rise in the water dose to 1.4 kg/t in the rougher flotation cycle led to the recovery of scheelite falling to 30.4–41%, with the WO3 concentrate quality being 22.78–50.5%, corres pondingly. No commercial quality was reached when scheelite concentrate was subjected to heat treatment in a sodium sulphide (43–62 kg/t) and alkaline environment (рН 13) without water glass. Addition of 3.3 kg/t of water glass to sodium sulphide helped raise the quality of scheelite concentrate after three cleaner flotation to 54% WO3 and the recovery of scheelite was 68.4% only. A recovery of more than 82% of commercial grade scheelite concentrate (WO3 > 50%) was reached when running in standard mode using Petrov method of heat treatment. Application of the above processes, which demonstrated high performance in relation to scheelite ores taken from Skarn deposits of Portuguese and Chinese, to samples of Skarn scheelite sulphide ores from Far Eastern deposits, did not prove successful. The authors would like to thank the Research Laboratory of PCP for support with lab studies.

Potential of mining, agro-industrial, and urban wastes for the remediation of acidic mine water

<p>Mining is a crucial industry worldwide because of its economic and social importance. However, the increasing number of operating mines raises major concerns for health and the environment. The intense mining activity generates large quantities of wastes associated with several environmental problems. For example, the generation of acid mine drainages (AMD) by oxidation of sulphide ores stored in tailings deposits, leachates high concentrations of potentially harmful elements (PHEs), which poses severe pollution problems to the environment (aquatic and terrestrial ecosystems). This study evaluates the acid neutralisation capacity and the removal effectiveness of inorganic PHEs present in an AMD of different waste materials. This study is a first approach to future studies to develop pilot remediation studies using designed waste-derived Technosols. The waste used includes 4 mining wastes (iron oxide and hydroxide sludges [IO], marble cutting and polishing sludge [MS], gypsum spoil [GS], and carbonated waste from a peat extraction [CW]), 3 urban wastes (composted sewage sludge [WS], bio-stabilised material from municipal solid waste [BM], and vermicompost from pruning and gardening [VC]), and 3 agro-industrial wastes (2 solid olive-mill by-products [OW, OL] and composted greenhouse waste [GW]). All waste materials were spiked with the acidic water (AMD<sub>L</sub>) prepared in the laboratory from the oxidation of pyritic tailings from the Aznalcóllar mine accident (1998). Afterward, they were stirred for 24 h and filtered, separating the waste (solid phase) from the leachate (liquid phase). In the leachate (AMD<sub>L</sub> treated), pH<sub>(L) 1:5</sub>, EC<sub>(L) 1:5</sub>, and inorganic PHEs concentrations were measured, the latter by ICP-MS. The acidic water showed a strongly acidic character (pH<sub>(L)</sub> ~ 2.89), high salinity (EC<sub>(L)</sub> ~ 3.76 dS m<sup>-1</sup>), and high concentrations of PHEs. Among them, As, Cd, Cr, Cu, Ni, Pb, Sb, Th, Tl, U, V, Y, and Zn stood out since they far exceed various legal limits widely used worldwide and/or because their high toxicity to humans, animals, plants or microorganisms. The most abundant were Zn (32.21 mg l<sup>-1</sup>), Cu (6.24 mg l<sup>-1</sup>), As (2.86 mg l<sup>-1</sup>), Sb (0.82 mg l<sup>-1</sup>), Pb (0.60 mg l<sup>-1</sup>), and Cd (0.45 mg l<sup>-1</sup>). All wastes were effective in neutralising the acidic pH<sub>(L)</sub> of the AMD, as the leachates showed pH<sub>(L)</sub> close to 7. In contrast, changes in the EC<sub>(L)</sub> have been very irregular among the wastes used. In general, all wastes have been effective in adsorbing the PHEs. Inorganic wastes have been much more effective than organic ones, with adsorption efficiencies above 95% for many of the PHEs (particularly for those in higher concentrations). The waste with the best remediation behaviour were IO, CW, MS, GS, and VC. Conversely, GW and WS were the worst at removing PHEs present in AMD. Therefore, this study shows that many of wastes tested are suitable for the construction of Technosols from these wastes to prevent soil pollution by AMD discharge.</p>

Designs of new operating copper processing plants: process types, equipment selection, industry trends

The article describes the largest operating processing plants for lowgrade copper sulphide ores of our time: 10 plants using the semi-autogenous grinding (SAG) technology and 10 plants using high-pressure grinding rolls (HPGR), with the output of 18 to 100 Mtpa. The unfavorable natural and economic factors are balanced by improved ore preparation and concentration technologies and high-capacity equipment units, combined with cost-saving layout solutions. The ore preparation sector is currently divided between the competing technologies of semi-autogenous grinding and HPGR. The article contains an overview of their advantages and disadvantages. The world’s largest monosection with the capacity of 55.5 Mtpa, that uses the SAG technology, is described. The role of the Drop Weght Test JKSimMet (A×b) parameter in the selection of the ore preparation method and the trend for using HPGR in the processing of strong ores are shown. Examples are provided for the consequences of an inadequate assessment of the feed strength in SAG-based plant designs. Examples of ore preparation process intensification through the use of HPGR in semi-autogenous grinding circuits are also given. The volume of impeller flotation cells installed has reached 600 m3. An overview of the two largest processing plants of our time with the output of 88 and 100 Mtpa of ore is presented. The innovative technical solutions of a newest low-capacity copper plant are highlighted. Based on the results of the overview, a future processing plant is predicted to use ∅12.8–13 m SAG mills, HPGRs with the roll diameter of 3 m, vertical VTM-7000 mills in ore grinding cycles, large fine screens, large-scale impeller flotation cells, and staged SFR and DFR flotation reactors.