Composition based on one-component polyurethane modified with tetrapropoxysilane

The questions of interaction of one-component polyurethane and organosilicon compound from the group of alkoxysilanes - tetrapropoxysilane are considered. The composition is intended to obtain a hydrophobic coating with improved performance properties to protect building structures from the effects of technogenic and natural factors. The mechanisms of interaction of one-component polyurethane with tetrapropoxysilane have been studied using spectroscopy. The product of the interaction of the polymer and tetrapropoxysilane is a three-dimensionally crosslinked polymer in which polyurethane macromolecules are crosslinked by organosilicon molecules. The chemical reaction is based on the mechanism of interaction of isocyanate groups with reactive groups of alkoxysilane. The effect of the modifier on the surface structure of the cured coating was studied using a microscope. The contact angle of wetting of the modified and unmodified composition is determined, and the concentration of tetrapropoxysilane at which the coating acquires hydrophobic properties is determined. The effect of tetrapropoxysilane on the adhesive characteristics of the polymer composition has been studied. The change in the hardness of the composition at various concentrations of alkoxysilane was studied. Chemical modification of polyurethane allows you to vary its properties in the desired direction without deteriorating its other characteristics.

Investigation of heat transfer during evaporation of droplets of Fe3O4 nanofluids from biphilic surfaces

In this work, unique biphilic substrates were prepared with a sharp spatial gradient of the contact angle of wetting. Experimental studies of the process of evaporation of liquid droplets lying on the structured surfaces have been carried out. In the experiment, the dynamics of the temperature of an evaporating droplet was compared depending on its orientation in space. It was found that suspended droplets of 0.1 wt % Fe3O4 nanofluid have a higher evaporation temperature and a higher evaporation rate as compared to sessile droplets.

Synthesis and properties of nanosized ZnO/wood composite

The aim of the study was to synthesise a ZnO/silver birch wood (Bétula péndula) nanocomposite and evaluate its physical and mechanical properties in comparison with an unmodified natural polymer.Using the sol-gel method, we synthesised almost spherical impurity-free zinc oxide nanoparticles with a predominant particle size of about 20 nm. Amorphous hydrated Zn(OH)2 was impregnated into the wood material at the gel formation stage. It resulted in the reaction of zinc hydroxide decomposition with the formation of ZnO nanoparticles in the wood as a nanoreactor.The hydrophobic properties of the surface of ZnO/silver birch wood nanocomposite improved significantly (the contact angle of wetting doubled). Its moisture and water resistance decreased (2-5 times and 30%, respectively). The nanocomposite also showed less swelling in the radial (8-10 times) and tangential (2.6-10 times) directions in comparison with natural wood.

Dipinaconborate additives in solutions for washing parts of automotive vehicles

It is shown that the addition of 3 % wt. lithium, sodium and potassium dipinaconborates to a 5% Temp-100A solution achiev es the highest v alues of the degree of purification and the lowest values of the contact angle of wetting of the metal surface. The 20 steel corrosion rate decreases to 8⋅10-3 g / (m2∙h) and 4⋅10-3 g / (m2∙h) respectively after 24 h and 120 h of testing. The corrosion rate is 32⋅10-3 g / (m2∙h) and 24⋅10-3 g / (m2∙h) respectively in a 5% solution Temp-100A without additives.

Determination of the wetting angle using gas bubble method

Most of the technological processes of coal mining and primary processing (transportation, crushing, and enrichment) depend on the physical and chemical properties of the external surface of coal particles. When determining the wetting angle — the wettability characteristics of the coal surface — the method of preparing the working surface of the sample and the choice of the measurement procedure (a drop of liquid on a solid surface or fixing a gas bubble on the surface of coal placed in water) are of great importance. We present the results of determining the contact angle of wetting using an air bubble. The working surface was prepared by briquetting a powdered sample. Scanning electron microscopy and laser diffraction analysis of the particle size distribution were used for surface characterization and fractional analysis of carbon particles. It is shown that the contact angle of wetting depends on the particle size, mineral composition of coal, and pressing pressure. At the same time, when determining the wetting angle, the optimal particle size and pressing pressure of the briquette are <100 μm and ~500 MPa, respectively. The obtained results can be used to improve technologies for mining, conversion and dressing of coals.

Protective properties of superhydrophobic coatings on copper and steel obtained by electrochemical method

Superhydrophobic coatings are obtained by cathodic deposition of copper or nickel on a copper plate with treatment with an ethanol solution of highest carboxylic acids with a long hydrocarbon radical simultaneously or sequentially. They are characterized by a contact angle of water wetting of the order of 155...160°.These coatings protect the copper substrate from corrosion in conditions of 100% humidity for 100...180 days, while maintaining the contact angle within 152…154°. There is no mass loss. The influence of the reversal of the current during electrolysis on the value of the contact angle of wetting is investigated. SEM images of superhydrophobic coatings are presented, indicating multilevel roughness. Superhydrophobic coating on carbon steel is obtained by cathodic deposition of nickel and subsequent surface treatment in an ethanol solution of myristic acid and annealing at 60° for two hours. The influence of the duration of electrolysis on the value of the contact angle of wetting is estimated. Its value is in the range of 151…154°. Exposure of a coated steel plate for 50 days in conditions of 100% humidity is characterized by the absence of weight loss and maintaining the contact angle up to 154°.

Improving the technology of repair painting with powder-coated paints in agro-industrial complex

The article presents the results of studies to determine the dependence of the degree of adhesion and the separation force of the powder coatings layer on the roughness parameter of the substrate, as well as the contact angle of wetting for various methods of preparing the painted surface by chemical methods. In addition, practical tests for stain resistance were carried out, which showed the absence of corrosion damage, as well as a slight change in color, gloss of coatings, chalking and dirt retention on the studied coating samples.

CONTACT ANGLE OF COAL WETTING WITH WATER

It is known that in the process of coking a compacted coal charge during its ramming in an industrial ramming-loading-pushing machine, the moisture of the charge plays the role of a compaction agent. On the basis of this, the authors put forward a reasonable assumption that the higher the ability of coal grains to hydration, the stronger the contact between them and, accordingly, the greater the density of the formed rammed coal cake. Therefore, the determination of the ability to hydrate the surface of coal used in the charge for ramming is of both theoretical and practical importance. For the numerical determination of this indicator, the authors have chosen the contact angle of wetting, determined by the method of "sessile drop" of water on a carbon substrate. The article presents the results of a study of the ability of various brands of coal to hydrate. The article describes the characteristics of the studied grades of coal and their contact angle of wetting with water (Ɵ) after 1, 2 and 3 minutes of keeping the drop on a polished surface. Since according to the literature data, the organic mass of coal is hydrophobic, and mineral impurities, as a rule, are hydrophilic, the authors investigated the degree of influence of the "ash content of coal" (Аd ) indicator on the value of Ɵ. To determine the influence of the wetting angle and the internal moisture content of coal after 14 hours of moisture saturation in water (Wins) on the strength (ϭss) of the rammed sample, the corresponding graphical dependence was determined. The data obtained indicate that any significant relationship between Аd and Ɵ is absent, the correlation coefficient is insignificant (r = 0.28). Thus, the predominant factor in the hydration of cleaned coal is the properties of its organic matter. The correlation between Ɵ and the yield of volatile substances Vdaf and the content of vitrinite Vt is also insignificant – the correlation coefficient is up to 0,43 and 0,50 respectively. A close relationship of the contact angle was found with the reflection coefficient of vitrinite Ro (r = 0.72), the internal moisture content of coal after 14 hours of saturation in water, Wins (r = 0,65), and the shear strength of the rammed coal sample ϭss (r = 0,68). Keywords: coal, ability to hydration, contact angle of wetting, organic mass of coal, mineral impurities, density, strength. Corresponding author V.M. Kuznichenko, e-mail: : [email protected]

USE OF A PENETRATING ADDITIVE TO INCREASE THE WATER RESISTANCE OF CONCRETE

The penetration of moisture into the capillary-porous structure of concrete leads to the development of corrosion processes, the formation of efflorescence, the decrease in strength and the subsequent destruction of the cement-sand composite. At the same time, the increased humidity of the structure is a favorable environment for the development of various biological damages (mold, fungi, lichens), which, in turn, leads to both decrease in the operational characteristics of the structure and loss of the aesthetic appearance of the building facade. In this regard, the study of possibility of increasing the waterproofing of concrete by compaction of its structure is of great interest. The paper discusses the effect of penetrating additives on the physicomechanical characteristics of fine-grained concrete and fiber-reinforced concrete. It has been established that the introduction of a penetrating additive into the composition of cement-sand composites leads to the filling of the capillary-porous structure of materials with needle-like new formations, which makes it possible to increase their resistance to moisture influence, namely, to increase the waterproof grade, reduce the depth of water penetration into the concrete structure, increase the contact angle of wetting the surface of the material. It was also noted that the simultaneous introduction of a penetrating additive and fiber into the concrete composition allows not only to increase the waterproofness of the composite, but also to improve hydrophobic performance by imparting a hierarchical surface structure to the material.