The Influence of the Magmatic to Postmagmatic Evolution of the Parent Rock on the Co Deportment in Lateritic Systems: The Example of the Santa Fé Ni-Co Deposit (Brazil)

The Santa Fé Ni-Co deposit is a major undeveloped lateritic deposit located in the Goiás State of Central Brazil. The deposit comprises two properties that together have indicated resources of 35.7 million tonnes (Mt), grading 1.14% Ni and 0.083% Co, and inferred resources of 104.3 Mt at 1.03% Ni and 0.054% Co. The laterite was derived from Late Cretaceous alkaline ultramafic lithologies that experienced an initial silicification from Eocene to Oligocene, followed by lateritization and partial reworking in Miocene-Pliocene. The deposit is characterized both by oxide- and phyllosilicate-dominated ore zones. In the former, Ni- and Co-bearing hematite and goethite dominate the supergene mineralogical assemblage, while ore-bearing Mn oxyhydroxides occur as minor components. In the phyllosilicate-dominated horizons the major Ni-carrying phase is chlorite. Multivariate statistical analyses (factor analysis and principal components analysis) conducted on the drill core assay database (bulk-rock chemical analyses) showed that significant differences exist between Ni and Co distributions. The Ni distribution is not controlled by any clear geochemical correlation. This is because the highest Ni concentrations have been measured in the ferruginous and in the ochre saprolite zones, where Ni-bearing minerals (chlorite and goethite) are mostly associated with reworked material and only in a limited way, with zones affected by in situ ferrugination. Cobalt has an atypical statistical distribution at Santa Fé if compared with other laterites, correlated not only with Mn but also with Cr in the majority of the laterite facies. From microchemical analyses on several potential Co-bearing minerals, it was found that the Co-Cr association is related to elevated Co contents in residual spinels, representing unweathered phases of the original parent rock now included in the laterite. This element distribution is atypical for Ni-Co laterite deposits, where Co is normally associated with Mn in supergene oxyhydroxides. In the case of the Santa Fé laterite, the Co concentration in spinels is likely related to magmatic and postmagmatic processes that affected the original parent rock before lateritization, specifically (1) orthomagmatic enrichment of Co in chromite, due to its high affinity to spinels in alkaline melts, and (2) trace elements (i.e., Co, Mn, Ni, and Zn) redistribution during the hydrothermal alteration of chromite into ferritchromite. The Santa Fé deposit represents a good example of how the prelateritic evolution of a parent rock strongly affects the efficiency of Co mobilization and enrichment during supergene alteration. Based on the interpretation of metallurgical test work, a fraction of total Co between 20 and 50% is locked in spinels.

Fingerprinting molecular and isotopic biosignatures on different hydrothermal scenarios of Iceland, an acidic and sulfur-rich Mars analog

Detecting signs of potential extant/extinct life on Mars is challenging because the presence of organics on that planet is expected to be very low and most likely linked to radiation-protected refugia and/or preservative strategies (e.g., organo-mineral complexes). With scarcity of organics, accounting for biomineralization and potential relationships between biomarkers, mineralogy, and geochemistry is key in the search for extraterrestrial life. Here we explored microbial fingerprints and their associated mineralogy in Icelandic hydrothermal systems analog to Mars (i.e., high sulfur content, or amorphous silica), to identify potentially habitable locations on that planet. The mineralogical assemblage of four hydrothermal substrates (hot springs biofilms, mud pots, and steaming and inactive fumaroles) was analyzed concerning the distribution of biomarkers. Molecular and isotopic composition of lipids revealed quantitative and compositional differences apparently impacted by surface geothermal alteration and environmental factors. pH and water showed an influence (i.e., greatest biomass in circumneutral settings with highest supply and turnover of water), whereas temperature conditioned the mineralogy that supported specific microbial metabolisms related with sulfur. Raman spectra suggested the possible coexistence of abiotic and biomediated sources of minerals (i.e., sulfur or hematite). These findings may help to interpret future Raman or GC–MS signals in forthcoming Martian missions.

Leka Ophiolite Complex as analogy to the serpentinization-carbonation system on Mars

<p>Jezero Crater is the landing site of the Mars2020 NASA rover. The crater in its early history hosted a paleolake with at least two deltas remaining. The Jezero lake belongs to a larger system - the Nili Fossae region – which exposes a mineralogical assemblage interpreted as a serpentinization/carbonation system [1].  While the main alteration minerals in Jezero are identified, little is known about the accessory minerals. The latter could reveal critical information about the conditions of serpentinization/carbonation [2; 3]. Moreover, several aspects are yet to be solved: Are the carbonates resulting of primary alteration or reworked origin [4]? Is the mineralogical assemblage modified after deposition in the lake (weathering)? What is the nature of the protolith that could contains up to 30% of olivine [5]?</p><p>The Nili Fossae-Jezero system has its potential analogue in terrestrial serpentinized and carbonated rocks, such as the Leka Ophiolite Complex, Leka Island, Norway, (PTAL collection, https://www.ptal.eu), which records complex weathering of serpentinite formed from mafic to ultramafic rock [6].</p><p>We perform petrological and mineralogical analyses on thin sections to characterize the weathering products in Leka samples, and combine with Near Infrared Spectroscopy measurements. We study the significance of the mineralogical assemblages including solid solution composition and nature of accessory minerals. The consequence for habitability potential might be important. Indeed, the amount of H<sub>2</sub>/CH<sub>4</sub> production in mafic or ultramafic system vary significantly [2; 7]. This could represent crucial information that could guide future in-situ operations but could also help for a better interpretation of the remote sensing data.</p><p><strong> </strong></p><p>References:</p><ol><li>Brown, A. J., et al. EPSL297.1-2 (2010): 174-182.</li> <li>Klein, F., et al. Lithos178 (2013): 55-69.</li> <li>Gysi, A. P., & A. Stefánsson. GCA75.17 (2011): 4728-4751.</li> <li>Horgan, B., et al. Second International Mars Sample Return. Vol. 2071. 2018.</li> <li>Ody, A., et al. JGR: Planets118.2 (2013): 234-262.</li> <li>Bjerga, A., et al. Lithos227 (2015): 21-36.</li> <li>Bultel, B. (Doctoral dissertation, Lyon). (2016).</li> </ol>

An Integrated Study of the Serpentinite-Hosted Hydrothermal System in the Pollino Massif (Southern Apennines, Italy)

A comprehensive study of the serpentinite and associated veins belonging to the Frido Unit in the Pollino Massif (southern Italy) is presented here with the aim to provide new constraints about the hydrothermal system hosted by the accretionary wedge of the southern Apennines. The studied serpentinites are from two different sites: Fosso Arcangelo and Pietrapica. In both sites, the rocks show mylonitic-cataclastic structures and pseudomorphic and patch textures and are traversing by pervasive carbonate and quartz-carbonate veins. The mineralogical assemblage of serpentinites consists of serpentine group minerals (with a predominance of lizardite), amphiboles, pyroxene, chlorite, titanite, magnetite, and talc. In some samples, hydro-garnet was also detected and documented here for the first time. As for cutting veins, different mineralogical compositions were observed in the two sites: calcite characterizes the veins from Fosso Arcangelo, whereas quartz and dolomite are the principal minerals of the Pietrapica veins infill, suggesting a different composition of mineralizing fluids. Stable isotopes of C and O also indicate such a different chemistry. In detail, samples from the Pietrapica site are characterized by δ13C fluctuations coupled with a δ18O shift documenting calcite formation in an open-system where mixing between deep and shallow fluids occurred. Conversely, δ13C and δ18O of the Fosso Arcangelo veins show a decarbonation trend, suggesting their developing in a closed-system at deeper crustal conditions. Precipitation temperature calculated for both sites indicates a similar range (80 °C to 120 °C), thus suggesting carbonate precipitation within the same thermal system.

Monazite-(Ce) and xenotime-(Y) microinclusions in fluorapatite of the pegmatites from the Volta Grande mine, Minas Gerais state, southeast Brazil, as witnesses of the dissolution–reprecipitation process

Fluorapatite with monazite-(Ce) and xenotime-(Y) microinclusions occurs in the lithium–caesium–tantalum pegmatite body A of the Volta Grande mine, Minas Gerais state, Southeast Brazil. The fluorapatite displays faint zoning, detected mainly by cathodoluminescence. Electron probe and laser ablation analyses indicate that zoning in the fluorapatite corresponds to variation in Mn and rare-earth element (REE) content. Such compositional variation is attributed to partial removal of the REE from the fluorapatite structure during a dissolution–reprecipitation process, forming monazite-(Ce) and xenotime-(Y) microinclusions in the REE-depleted zones of the fluorapatite. These inclusions exhibit an inherited geochemical signature, manifested by low Th and U concentrations when compared to monazite and xenotime crystallised from melts. Rhodochrosite and calcite inclusions are also associated with monazite-(Ce) and xenotime-(Y) and are probably products of the same process, recycling Ca, Mn, and CO32− from the fluorapatite through the following reaction: [Ca(5–2a–b–½x),Naa,(Y + REE)a,Mnb][(PO4)3–x(CO3)x(F)] + Fluid[a(2Ca2+ + P5+) + (x–b)(Ca2+) + H2O)] → [Ca5(PO4)3(F,OH)] + a[(Y + REE)PO4] + b[Mn(CO3)] + (x–b)[Ca(CO3)] + Fluid a[Na+].On the basis of new fluid-inclusion analyses, we propose that a hot (T > 204.5°C), salty (16 wt.% eq. NaCl, attributed to LiCl), hydrous fluid mediated the dissolution–reprecipitation of the fluorapatite. This fluid corresponds to similarly described Li-rich fluids which were suggested to have re-equilibrated the mineralogical assemblage at the Volta Grande mine.

Inclusions in an isoferroplatinum nugget from the Freetown Layered Complex, Sierra Leone

ABSTRACTInclusions of platinum-group minerals (PGM) within alluvial isoferroplatinum nuggets from the Freetown Peninsula, Sierra Leone, are aligned with their shape determined by the structure of their host. The edges of the majority of the inclusions lie at 0°, 45° or 90° to external crystal edges of the nugget which shows that the inclusions are not randomly oriented earlier minerals incorporated within their host. The inclusions are later infills, probably formed at the surface of the nugget during growth and subsequently enclosed by the growing nugget. PGM on the present surface of the nugget represent the last stage of this partnership. A single nugget containing abundant inclusions is described here but similar features are observed in other nuggets from the same area. The inclusions contain laurite (RuS2), irarsite–hollingworthite (IrAsS–RhAsS), Pd–Te–Bi–Sb phases, Ir-alloy, Os-alloy, Pd-bearing Au, an Rh–Te phase, Pd–Au alloy and Pd–Pt–Cu alloy. PGM found on the nugget surface include laurite, irarsite and cuprorhodsite (CuRh2S4). The Pd–Te–Bi–Sb phases may include Sb-rich keithconnite (Pd20S7) and compositions close to the kotulskite–sobolevskite solid-solution series (PdTe–BiTe). Textural evidence suggests that formation of the nuggets began with the isoferroplatinum host and the voids were filled starting intergrowths of laurite and irarsite–hollingworthite with both laurite and irarsite–hollingworthite often showing compositional zonation and each of them replacing the other. Filling of the voids probably continued with Pd-Cu-bearing gold, Sb-rich keithconnite (Pd,Pt)20.06(Te,Sb,Bi)6.94, keithconnite, telluropalladinite Pd9(Te,Bi)4, RhTe and finally Ir-alloy and then Os-alloy. The nuggets are thought to be neoform growths in the organic- and bacterial-rich soils of the tropical rain forest cover of the Freetown intrusion. The mineralogical assemblage in the layered gabbros of the intrusion has been previously shown to differ from the alluvial assemblage in the rivers and these inclusions, not seen in Pt3Fe in the unaltered rocks, add a further item to the catalogue of differences.

THE KONDAROS-KATSIMOUTI INTERMEDIATESULFIDATION EPITHERMAL PB-ZN-AG-MN MINERALIZATION, WESTERN MILOS, GREECE: NEW MINERALOGICAL AND GEOCHEMICAL DATA

The metallic mineralization in Kontaros-Katsimouti area is an epithermal Pb-Zn Ag mineralization located along the NW-trending Kondaros-Katsimouti-Vani fault, NW Milos Island, Greece. It is hosted within propylitically and argillically altered dacitic flow dome and volcaniclastic sandstone and shows features typical of intermediate sulfidation deposits like colloform banding, cockade breccias and gangue adularia, Mnrich carbonates and amethystine quartz. The Kondaros-Katsimouti system evolves at higher elevation into the Vani Ag-Pb mineralization, which occurs proximal to the Vani manganese deposit. The metallic mineralogical assemblage at Kondaros-Katsimouti includes mainly galena and sphalerite and minor pyrite. Silver is present in the form of Ag-(Cd) rich tetrahedrite (up to 23.1 wt. % Ag) and polybasite included in galena. Bulk ore analyses indicate enrichment in W (up to 424 mg/kg) and Mo (up to 24 mg/kg), similarly to the other neighboring mineralizations in western Milos (e.g. Vani, TriadesGalana). This enrichment suggests a magmatic-hydrothermal contribution to the ore fluids, probably from a buried granitoid at depth. Boiling, in addition to mixing processes between magmatic- and seawater, resulted in pH increase, oxidation and temperature decrease, and resulted into ore deposition.