Hydrido Complexes of Calcium: A New Family of Molecular Alkaline-Earth-Metal Compounds

2018 ◽  
Vol 57 (31) ◽  
pp. 9590-9602 ◽  
Author(s):  
Debabrata Mukherjee ◽  
Danny Schuhknecht ◽  
Jun Okuda
Keyword(s):  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Metal Compounds ◽  
New Family

scholarly journals Mechanochemistry of fluoride solids: from mechanical activation to mechanically stimulated synthesis

ChemTexts ◽  
2021 ◽  
Vol 7 (2) ◽  
Author(s):  
Gudrun Scholz
Keyword(s):  
Mechanical Activation ◽  
Mechanochemical Synthesis ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Technical Equipment ◽  
Metal Compounds ◽  
Potential Applications ◽  
The Given ◽  
Mechanochemical Reactions

Abstract This lecture text is focused on the comparatively young field of mechanochemistry of fluoride solids, considering both their mechanical activation and their mechanochemical synthesis. Beside a literature survey, the mechanochemical synthesis of binary fluorides MF2, MF3, of complex fluorides MMgF4, of solid solutions MaxMb1−xF2 or M1−xLnxF2+x (Ln: Y, Eu) and of fluorine-containing coordination polymers is presented. Owing to their interesting potential applications in the field of fluoride ion conductivity or luminescence properties when doped, most of the given examples are alkaline earth metal compounds. A short historical survey, remarks on peculiarities and consequences of mechanical activation as well as the necessary technical equipment for mechanochemical reactions precede the section. Graphic abstract

Über Erdalkalimetallverbindungen des 1,1-Dicyanoethylen-2,2-dithiolats, II+ Die Kristallstruktur von BaS2C4N2 • 3 H2O / On Alkaline-Earth Metal Compounds of 1,1-D icyanoethylene-2,2-dithiolate, II+ Crystal Structure of BaS2C4N2 • 3 H2O

1985 ◽  
Vol 40 (12) ◽  
pp. 1638-1643 ◽  
Author(s):  
Hans-U. Hummel ◽  
C. Wolf
Keyword(s):  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Barium Salt ◽  
Metathesis Reaction ◽  
Metal Compounds ◽  
Crystal Water ◽  
Trigonal Prismatic Coordination ◽  
Trigonal Prismatic ◽  
Packing Effects

Abstract By reaction of CS2 with maleonitrile in the presence of sodium-ethanolate in ethanol Na2S2C4N2 is obtained. It reacts with Ba(NCS)2 · 3 H2O in a metathesis reaction to give BaS2C4N2 ·3 H2O. The space group of the barium salt is C 2/c with Z = 8. The structure consists of Ba2+ and [S2C -C(CN)2]2- ions, and crystal water. Barium has a distorted tricapped trigonal prismatic coordination: four O, three N and two S atoms. There are considerable deviations from planarity for the [S2C4N2]2- anion due to packing effects

Heavy Grignard Reagents: Challenges and Possibilities of Aryl Alkaline Earth Metal Compounds

ChemInform ◽  
2007 ◽  
Vol 38 (41) ◽  
Author(s):  
Matthias Westerhausen ◽  
Martin Gaertner ◽  
Reinald Fischer ◽  
Jens Langer ◽  
Lian Yu ◽  
...  
Keyword(s):  
Alkaline Earth ◽  
Earth Metal ◽  
Grignard Reagents ◽  
Alkaline Earth Metal ◽  
Metal Compounds

scholarly journals Linear trinuclear copper(II)-alkali/alkaline earth metal compounds derived from a compartmental ligand

2018 ◽  
Vol 482 ◽  
pp. 612-620 ◽  
Author(s):  
Shuvankar Mandal ◽  
Shuvayan Roy ◽  
Suraj Mondal ◽  
Hazel A. Sparkes ◽  
Sasankasekhar Mohanta
Keyword(s):  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Metal Compounds
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