Ba2B5O8(OH)2(NO3)·3H2O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate

The first alkaline earth metal borate-nitrate, namely, Ba2B5O8(OH)2(NO3)·3H2O (BBNOH), has been synthesized by the hydrothermal method. BBNOH crystallizes in the space group of P21/c and exhibits two-dimensional (2D) 2∞[B5O8(OH)2]3-borate anion...

2-Imino-2,3-dihydrobenzoxazole – a Useful Platform for Designing Rare- and Alkaline Earth Complexes with Variable Di- and Trianionic O,N,N, Ligands

The reactions of 2-imino-2,3-dihydrobenzoxazole LH with M[N(SiMe3)2]2(THF)2 (M = Yb, Ca) and Y(CH2SiMe3)3(THF)2 proceed with opening of dihydrobenzoxazol ring and elimination of HN(SiMe3)2 or SiMe4. Besides in the case of...

Alkaline Metal and Alkaline Earth Metal Salts of Di(1H-tetrazol-5-yl)Methanone (DTO): Energetic Catalysts for Ammonium Perchlorate Decomposition

To explore novel coordination complexes for promising energetic materials, alkaline metal (Na+ (1), Na+ (2), K+ (3), and Rb+ (4)) and alkaline earth metal (Mg2+ (5), Ca2+ (6), and Sr2+...