Elucidating the Reactivity of Vicinal Dicarbenoids: From Lewis Adduct Formation to B−C Bond Activation

2016 ◽  
Vol 22 (39) ◽  
pp. 13815-13818 ◽  
Author(s):  
Hauke Kelch ◽  
Stephanie Kachel ◽  
Mehmet Ali Celik ◽  
Marius Schäfer ◽  
Benedikt Wennemann ◽  
...  
Keyword(s):  
Bond Activation ◽  
Adduct Formation ◽  
Lewis Adduct

Lewis adduct formation of hydrogen cyanide and nitriles with arsenic and antimony pentafluoride

2019 ◽  
Vol 48 (1) ◽  
pp. 99-106 ◽  
Author(s):  
Thomas Saal ◽  
Karl O. Christe ◽  
Ralf Haiges
Keyword(s):  
Hydrogen Cyanide ◽  
Adduct Formation ◽  
Antimony Pentafluoride ◽  
Lewis Adduct

The reactions of hydrogen cyanide, butyronitrile, cyclopropanecarbonitrile, pivalonitrile and benzonitrile with arsenic pentafluoride and antimony pentafluoride result in the formation of 1 : 1 Lewis adducts, while malononitrile yielded both 1 : 1 and 1 : 2 Lewis adducts.

Mechanistic and Energetic Details of Adduct Formation and σ-Bond Activation in Zr+(H2)nClusters†

2001 ◽  
Vol 105 (11) ◽  
pp. 2216-2224 ◽  
Author(s):  
John E. Bushnell ◽  
Paul R. Kemper ◽  
Petra van Koppen ◽  
Michael T. Bowers
Keyword(s):  
Bond Activation ◽  
Adduct Formation

Diverse reactivity of borenium cations with >N–H compounds

2016 ◽  
Vol 52 (57) ◽  
pp. 8877-8880 ◽  
Author(s):  
Marc Devillard ◽  
Sonia Mallet-Ladeira ◽  
Ghenwa Bouhadir ◽  
Didier Bourissou
Keyword(s):  
Substitution Reaction ◽  
Adduct Formation ◽  
Lewis Adduct

The P-stabilized borenium 1 displays rich reactivity towards >N–H compounds: substitution reaction at a borenium center with Ph2NH, Lewis adduct formation and subsequent deprotonation with NH3, B–Mes cleavage and formation of a dicationic species with HNTf2.

Reactions of a BICAAC with hydroboranes: propensity for Lewis adduct formation and carbene insertion into the B–H bond

2019 ◽  
Vol 48 (47) ◽  
pp. 17472-17478 ◽  
Author(s):  
Krishna K. Manar ◽  
Vishal Kumar Porwal ◽  
Rohit S. Kamte ◽  
Manu Adhikari ◽  
Sandeep Kumar Thakur ◽  
...  
Keyword(s):  
Adduct Formation ◽  
Carbene Insertion ◽  
Lewis Adduct

A BICAAC interacts differently with different boranes: Lewis adducts were formed with simple hydroboranes and insertion of the carbene carbon into the B–H bond was observed with more hydridic boranes.

C−F Bond Activation by a Saturated N‐Heterocyclic Carbene: Mesoionic Compound Formation and Adduct Formation with B(C 6 F 5 ) 3

2019 ◽  
Vol 131 (9) ◽  
pp. 2830-2834 ◽  
Author(s):  
Moumita Pait ◽  
Gargi Kundu ◽  
Srinu Tothadi ◽  
Suvendu Karak ◽  
Shailja Jain ◽  
...  
Keyword(s):  
Bond Activation ◽  
Adduct Formation ◽  
Compound Formation ◽  
Mesoionic Compound

Intrinsic reactivity of metal–hydroxide complexes: O–H bond activation and adduct formation in gas-phase reactions of Cp2ZrOH+

2001 ◽  
Vol 204 (1-3) ◽  
pp. 255-266 ◽  
Author(s):  
David E. Richardson ◽  
G.H.Lisa Lang ◽  
Elisa Crestoni ◽  
Matthew F. Ryan ◽  
John R. Eyler
Keyword(s):  
Gas Phase ◽  
Bond Activation ◽  
Adduct Formation ◽  
Metal Hydroxide ◽  
Gas Phase Reactions ◽  
Intrinsic Reactivity

C−F Bond Activation by a Saturated N‐Heterocyclic Carbene: Mesoionic Compound Formation and Adduct Formation with B(C 6 F 5 ) 3

2019 ◽  
Vol 58 (9) ◽  
pp. 2804-2808 ◽  
Author(s):  
Moumita Pait ◽  
Gargi Kundu ◽  
Srinu Tothadi ◽  
Suvendu Karak ◽  
Shailja Jain ◽  
...  
Keyword(s):  
Bond Activation ◽  
Adduct Formation ◽  
Compound Formation ◽  
Mesoionic Compound
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