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Published By The Royal Society Of Chemistry

1477-9234, 1477-9226

2022 ◽  
Author(s):  
Emmanuel Blas Patricio-Rangel ◽  
Verónica Salazar ◽  
Omar Cortezano-Arellano ◽  
Daniel Mendoza-Espinosa

The chemistry of multinuclear metal complexes bearing by N-heterocyclic carbene (NHC) ligands, is an area of fast growing interest in modern organometallic chemistry. In particular, complexes supported by mesoionic (MIC)...


2022 ◽  
Author(s):  
Ahmed K. Abogosh ◽  
Meshal Alghanem ◽  
Saeed Ahmad ◽  
Abdullah Alasmari ◽  
Homood M. As Sobeai ◽  
...  

A new dinuclear cyclic gold(I) complex [Au2(DCyPA)2](PF6)2, 1 based on bis[2-(dicyclohexylphosphano)ethyl]amine (DCyPA) has been synthesized and characterized by elemental analysis, IR and NMR spectroscopies, and X-ray crystallography. In the dinuclear...


2022 ◽  
Author(s):  
Fengfeng Han ◽  
Qi Jin ◽  
Junpeng Xiao ◽  
Lili Wu ◽  
Xitian Zhang

Lithium–sulfur batteries (LBSs) have potential to become the future energy storage system, yet they are plagued by the sluggish redox kinetics. Therefore, enhancing the redox kinetics of polysulfide is a...


2022 ◽  
Author(s):  
David M. Stanbury

The iron-catalyzed disproportionation of H2O2 has been investigated for over a century, as has been its ability to induce the oxidation of other species present in the system (Fenton reaction)....


2022 ◽  
Author(s):  
Xiaoqiang Du ◽  
Jiaxin Li ◽  
Xiaoshuang Zhang

Transition metal materials with high efficiency and durable electrocatalytic water splitting activity have aroused widespread concern among scientists. In this work, two cation co-doped Ni3S4 nanoarrays grown on Ni foam...


2022 ◽  
Vol 51 (2) ◽  
pp. 387-387
Keyword(s):  

2022 ◽  
Author(s):  
Yunqiong Gu ◽  
Yu-Jun Zhong ◽  
Mei-Qi Hu ◽  
Huan-Qing Li ◽  
Kun Yang ◽  
...  

Four mononuclear terpyridine complexes [Cu(H-La)Cl2]·CH3OH (1), [Cu(H-La)Cl]ClO4 (2), [Cu(H-Lb)Cl2]·CH3OH (3), and [Cu(H-Lb)(CH3OH)(DMSO)](ClO4)2 (4) were prepared and fully characterized. Complexes 14 exhibited higher cytotoxic activity against several tested cancer cell lines...


2022 ◽  
Author(s):  
Lowie Henderick ◽  
Ruben Blomme ◽  
Matthias Marcus Minjauw ◽  
Jonas Keukelier ◽  
Johan Meersschaut ◽  
...  

A plasma-enhanced ALD process has been developed to deposit nickel phosphate. The process combines a trimethylphosphate (TMP) plasma with an oxygen plasma and nickelocene at a substrate temperature of 300°C....


2022 ◽  
Author(s):  
Aleksandra Mrzygłód ◽  
Maciej Kubicki ◽  
Beata Dudziec
Keyword(s):  

This is the first report on the synthesis of dendritic systems with double-decker SQs used as cores. A two-step synthetic protocol is presented to obtain G1.5 dendrimers with –SiCH2Cl reactive moieties for easy modification in the next stages.


2022 ◽  
Author(s):  
Paulo Pérez-Lourido ◽  
Eniko Madarasi ◽  
Fanni Antal ◽  
David Esteban-Gómez ◽  
Gaoji Wang ◽  
...  

We report the synthesis of the macrocyclic ligands 3,9 PC2AMH (2,2’-(3,6,9-triaza-1(2,6)-pyridinacyclodecaphane-3,9-diyl)diacetamide) and 3,9-PC2AMtBu (2,2’-(3,6,9-triaza-1(2,6)-pyridinacyclodecaphane-3,9-diyl)bis(N-tert-butyl)acetamide) which contain a pyclen platform functionalized with acetamide or tert-butylacetamide pendant arms at positions 3 and...


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