Enantiodivergent One‐Pot Synthesis of Axially Chiral Biaryls Using Organocatalyst‐Mediated Enantioselective Domino Reaction and Central‐to‐Axial Chirality Conversion

Author(s):  
Seitaro Koshino ◽  
Tohru Taniguchi ◽  
Kenji Monde ◽  
Eunsang Kwon ◽  
Yujiro Hayashi
2020 ◽  
Vol 56 (55) ◽  
pp. 7665-7668 ◽  
Author(s):  
Lu Liu ◽  
Lei Li ◽  
Shukuan Mao ◽  
Xin Wang ◽  
Ming-Dong Zhou ◽  
...  

Various o-alkenyl aromatic isocyanides were prepared from readily available reactants for their double annulation with diazo compounds for a one-pot synthesis of pyrazolo[1,5-c]quinazolines under mild reaction conditions.


ChemInform ◽  
2012 ◽  
Vol 43 (51) ◽  
pp. no-no
Author(s):  
Tianhao Meng ◽  
Wen-Xiong Zhang ◽  
Hui-Jun Zhang ◽  
Yun Liang ◽  
Zhenfeng Xi

2014 ◽  
Vol 16 (13) ◽  
pp. 3600-3603 ◽  
Author(s):  
Xin Feng ◽  
Huiqing Wang ◽  
Bo Yang ◽  
Renhua Fan

ChemInform ◽  
2008 ◽  
Vol 39 (40) ◽  
Author(s):  
Sorour Ramezanpour ◽  
Mehri Seyed Hashtroudi ◽  
Hamid Reza Bijanzadeh ◽  
Saeed Balalaie

2004 ◽  
Vol 45 (7) ◽  
pp. 1373-1375 ◽  
Author(s):  
Nikla Baricordi ◽  
Simonetta Benetti ◽  
Gisella Biondini ◽  
Carmela De Risi ◽  
Gian P. Pollini

RSC Advances ◽  
2016 ◽  
Vol 6 (4) ◽  
pp. 2870-2874 ◽  
Author(s):  
Yaoling Wang ◽  
Xu Cheng ◽  
Zhen Zhan ◽  
Xiaojun Ma ◽  
Ruifang Nie ◽  
...  

A novel and temperature-controlled oxidation of α-hydroxy amides in the presence of IBX is described.


ChemInform ◽  
2016 ◽  
Vol 47 (21) ◽  
Author(s):  
Yaoling Wang ◽  
Xu Cheng ◽  
Zhen Zhan ◽  
Xiaojun Ma ◽  
Ruifang Nie ◽  
...  

2014 ◽  
Vol 10 ◽  
pp. 1308-1316 ◽  
Author(s):  
Marco Caricato ◽  
Silvia Díez González ◽  
Idoia Arandia Ariño ◽  
Dario Pasini

The “one-pot” synthesis of several homochiral macrocycles has been achieved by using π-electron-rich, electron-deficient or extended aromatic dicarboxylic acids in combination with an axially-chiral dibenzylic alcohol, derived from enantiomerically-pure BINOL. Two series of cyclic adducts with average molecular D 2 and D 3 molecular symmetries, respectively, have been isolated in pure forms. Their yields and selectivities deviate substantially from statistical distributions. NMR and CD spectroscopic methods are efficient and functional in order to highlight the variability of shapes of the covalent macrocyclic frameworks. The larger D 3 cyclic adducts exhibit recognition properties towards C60 in toluene solutions (up to log K a = 3.2) with variable stoichiometries and variable intensities of the charge-tranfer band upon complexation.


2013 ◽  
Vol 60 (8) ◽  
pp. 1003-1006 ◽  
Author(s):  
Seyed Sajad Sajadikhah ◽  
Nourallah Hazeri ◽  
Malek Taher Maghsoodlou ◽  
Sayyed Mostafa Habibi-Khorassani

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