ChemInform Abstract: High 1,2-Asymmetric Induction in Radical Reactions: Radical Addition to γ-Hydroxy α,β-Unsaturated Carboxylic Esters and Sulfones.

ChemInform ◽  
2010 ◽  
Vol 29 (18) ◽  
pp. no-no
Author(s):  
K. OGURA ◽  
A. KAYANO ◽  
M. AKAZOME
Keyword(s):  
Radical Addition ◽  
Asymmetric Induction ◽  
Radical Reactions ◽  
Carboxylic Esters

Efficient 1,2-Asymmetric Induction in Radical Reactions: Stereoselective Radical Addition to 3-Hydroxy-1-(methylthio)-1-(p-tolylsulfonyl)-1-alkenes

1995 ◽  
Vol 60 (5) ◽  
pp. 1106-1107 ◽  
Author(s):  
Katsuyuki Ogura ◽  
Akio Kayano ◽  
Naoko Sumitani ◽  
Motohiro Akazome ◽  
Makoto Fujita
Keyword(s):  
Radical Addition ◽  
Asymmetric Induction ◽  
Radical Reactions

Visible-light-facilitated P-center radical addition to C=X (X = C, N) bonds results in cyclizations

2021 ◽  
Author(s):  
Shang-Dong Yang ◽  
Chong Li ◽  
Juan Wang
Keyword(s):  
Visible Light ◽  
Organophosphorus Compounds ◽  
Radical Addition ◽  
Radical Reactions

Visible-light-facilitated phosphorus radical reactions have been developed as a powerful and sustainable tool for the synthesis of various organophosphorus compounds. In general, these reactions require stoichiometric amounts of oxidants, and...

Highly Diastereoselective Radical Reactions of Substituted Methylideneimidazolidinones and Related Systems

2004 ◽  
Vol 57 (7) ◽  
pp. 629 ◽  
Author(s):  
George A. Adamson ◽  
Athelstan L. J. Beckwith ◽  
Christina L. L. Chai
Keyword(s):  
Radical Addition ◽  
Radical Reactions

Stannane-mediated radical addition to methylideneimidazolidinones occurs with good to excellent diastereo-selectivity. The stereochemical outcome of addition is highly dependent on the nature of the N1 substituent on the imidazolidinone ring.

Solid-phase intermolecular radical reactions 1. Sulfonyl radical addition to isolated alkenes and alkynes

1999 ◽  
Vol 40 (40) ◽  
pp. 7285-7288 ◽  
Author(s):  
Stephen Caddick ◽  
Daniel Hamza ◽  
Sjoerd N Wadman
Keyword(s):  
Solid Phase ◽  
Radical Addition ◽  
Radical Reactions
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