ChemInform Abstract: Phosphorus-Carbon Cage Compounds Derived from Di- and Triphosphacyclopentadienyl Ring Systems

ChemInform ◽  
2010 ◽  
Vol 30 (46) ◽  
pp. no-no
Author(s):  
John F. Nixon
Keyword(s):  
Cage Compounds ◽  
Carbon Cage ◽  
Ring Systems

ChemInform Abstract: Organophosphorus Compounds. Part 161. New Phosphorus-Carbon Cage Compounds by Diels-Alder and Homo Diels-Alder Reactions of 1,3,5-Triphosphabenzenes with Alkenes.

ChemInform ◽  
2010 ◽  
Vol 33 (17) ◽  
pp. no-no
Author(s):  
Christoph Peters ◽  
Hendrik Disteldorf ◽  
Evelyn Fuchs ◽  
Stefan Werner ◽  
Stefanie Stutzmann ◽  
...  
Keyword(s):  
Organophosphorus Compounds ◽  
Diels Alder ◽  
Cage Compounds ◽  
Carbon Cage

Directed Synthesis of Phosphorus-Carbon Cage Compounds—A Challenge in Organophosphorus Chemistry [1]

1996 ◽  
Vol 109 (1-4) ◽  
pp. 425-428 ◽  
Author(s):  
M. Regitz ◽  
T. Weitling ◽  
R. Fässler ◽  
B. Breit ◽  
B. Geissler ◽  
...  
Keyword(s):  
Cage Compounds ◽  
Carbon Cage ◽  
Directed Synthesis ◽  
Organophosphorus Chemistry

Organophosphorus Compounds, 103. Thermal Transformation of Kinetically Stabilized Phosphaalkynes with Phosphinidene Precursors. Synthesis of Phosphorus-Carbon Cage Compounds by Cocyclooligomerization Processes

1995 ◽  
Vol 128 (10) ◽  
pp. 991-997 ◽  
Author(s):  
Markus Julino ◽  
Michael Slany ◽  
Uwe Bergsträßer ◽  
Françlois Merçier ◽  
Françlois Mathey ◽  
...  
Keyword(s):  
Organophosphorus Compounds ◽  
Thermal Transformation ◽  
Cage Compounds ◽  
Carbon Cage

ChemInform Abstract: Solvolysis and Rearrangement in Unsaturated Carbon Cage Compounds

ChemInform ◽  
2010 ◽  
Vol 30 (50) ◽  
pp. no-no
Author(s):  
Andrew James Bennet
Keyword(s):  
Cage Compounds ◽  
Carbon Cage

Phosphaalkynes– Starting Point for the Synthesis of Phosphorus-Carbon Cage Compounds

2007 ◽  
pp. 173-201 ◽  
Author(s):  
Manfred Regitz ◽  
A. Hoffmann ◽  
U. Bergstrbter
Keyword(s):  
Cage Compounds ◽  
Carbon Cage ◽  
Starting Point

In,out-Isomerism of Phosphorus Bridgehead Cage Compounds. A Review

2004 ◽  
Vol 69 (6) ◽  
pp. 1195-1230 ◽  
Author(s):  
Ingmar Bauer ◽  
Wolf D. Habicher
Keyword(s):  
Ring Size ◽  
Macrocyclic Compounds ◽  
Cage Compounds ◽  
Polycyclic Compounds ◽  
Ring Systems ◽  
Specific Modification ◽  
The Third ◽  
The Way

The chemistry and stereochemical peculiarities, especially the phenomenon of in,out-isomerism of bi- and polycyclic compounds with one or more phosphorus bridgehead atoms, are reviewed in the present paper. The appearance of in,out-isomers depends on the ring size of the bi- and polycycles. In general graphic in,out-isomerism becomes only possible in medium sized ring systems and in particular in macrocyclic compounds. However even bicyclic systems containing small rings can be trans-configured if the third chain is long and flexible enough hence giving rise to pseudo-in,out-isomerism. In-phosphorus atoms exhibit a low reactivity in comparison to their out-counterparts. Nevertheless some few examples of reactions at in-positioned phosphorus atoms have been presented. This will potentially open the way to a specific modification of the cavity of such macrobi- and polycyclic compounds. A review with 53 references.

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