ChemInform Abstract: Organophosphorus Compounds. Part 153. New Phosphorus-Carbon Cage Compounds by Diels-Alder and Homo Diels-Alder Reactions of 1,3,5-Triphosphabenzenes with Alkynes.

ChemInform ◽  
2010 ◽  
Vol 31 (29) ◽  
pp. no-no
Author(s):  
Christoph Peters ◽  
Stefanie Stutzmann ◽  
Hendrik Disteldorf ◽  
Stefan Werner ◽  
Uwe Bergstraesser ◽  
...  
Keyword(s):  
Organophosphorus Compounds ◽  
Diels Alder ◽  
Cage Compounds ◽  
Carbon Cage

ChemInform Abstract: Organophosphorus Compounds. Part 161. New Phosphorus-Carbon Cage Compounds by Diels-Alder and Homo Diels-Alder Reactions of 1,3,5-Triphosphabenzenes with Alkenes.

ChemInform ◽  
2010 ◽  
Vol 33 (17) ◽  
pp. no-no
Author(s):  
Christoph Peters ◽  
Hendrik Disteldorf ◽  
Evelyn Fuchs ◽  
Stefan Werner ◽  
Stefanie Stutzmann ◽  
...  
Keyword(s):  
Organophosphorus Compounds ◽  
Diels Alder ◽  
Cage Compounds ◽  
Carbon Cage

Organophosphorus Compounds, Part 153; New Phosphorus-Carbon Cage Compounds by Diels - Alder and Homo Diels - Alder Reactions of 1,3,5-Triphosphabenzenes with Alkynes

Synthesis ◽  
2000 ◽  
Vol 2000 (04) ◽  
pp. 529-536 ◽  
Author(s):  
Christoph Peters ◽  
Stefanie Stutzmann ◽  
Hendrik Disteldorf ◽  
Stefan Werner ◽  
Uwe Bergsträßer ◽  
...  
Keyword(s):  
Organophosphorus Compounds ◽  
Diels Alder ◽  
Cage Compounds ◽  
Carbon Cage

Organophosphorus Compounds, 103. Thermal Transformation of Kinetically Stabilized Phosphaalkynes with Phosphinidene Precursors. Synthesis of Phosphorus-Carbon Cage Compounds by Cocyclooligomerization Processes

1995 ◽  
Vol 128 (10) ◽  
pp. 991-997 ◽  
Author(s):  
Markus Julino ◽  
Michael Slany ◽  
Uwe Bergsträßer ◽  
Françlois Merçier ◽  
Françlois Mathey ◽  
...  
Keyword(s):  
Organophosphorus Compounds ◽  
Thermal Transformation ◽  
Cage Compounds ◽  
Carbon Cage

New Phosphorus−Carbon Cage Compounds by Diels−Alder and Homo Diels−Alder Reactions of 1,3,5-Triphosphabenzenes with Alkenes

2001 ◽  
Vol 2001 (18) ◽  
pp. 3425-3435 ◽  
Author(s):  
Christoph Peters ◽  
Hendrik Disteldorf ◽  
Evelyn Fuchs ◽  
Stefan Werner ◽  
Stefanie Stutzmann ◽  
...  
Keyword(s):  
Diels Alder ◽  
Cage Compounds ◽  
Carbon Cage

ChemInform Abstract: Organophosphorus Compounds. Part 108. Directed Synthesis of Phosphorus- Carbon Cage Compounds - A Challenge in Organophosphorus Chemistry

ChemInform ◽  
2010 ◽  
Vol 28 (11) ◽  
pp. no-no
Author(s):  
M. REGITZ ◽  
T. WEITLING ◽  
R. FAESSLER ◽  
B. BREIT ◽  
B. GEISSLER ◽  
...  
Keyword(s):  
Organophosphorus Compounds ◽  
Cage Compounds ◽  
Carbon Cage ◽  
Directed Synthesis ◽  
Organophosphorus Chemistry

Organophosphorus Compounds; 124. Phosphorus-Phosphorus Bond Cleavage in Phosphorus-Carbon Cage Compounds Containing a Diphosphirane Moiety

Synthesis ◽  
1998 ◽  
Vol 1998 (04) ◽  
pp. 427-430 ◽  
Author(s):  
Anja Nachbauer ◽  
Uwe Bergsträßer ◽  
Stefan Leininger ◽  
Manfred Regitz
Keyword(s):  
Organophosphorus Compounds ◽  
Bond Cleavage ◽  
Cage Compounds ◽  
Carbon Cage

Ring-Closing Metathesis Approach to Cage Propellanes Containing Oxepane and Tetrahydrofuran Hybrid System

Synthesis ◽  
2017 ◽  
Vol 49 (24) ◽  
pp. 5339-5350 ◽  
Author(s):  
Sambasivarao Kotha ◽  
Subba Cheekatla ◽  
Darshan Mhatre
Keyword(s):  
Claisen Rearrangement ◽  
Alder Reaction ◽  
Diels Alder ◽  
Ring Closing Metathesis ◽  
Cage Compounds ◽  
Transannular Cyclization ◽  
Diels Alder Reaction ◽  
Grignard Addition ◽  
Key Steps ◽  
First Time

The preparation of a variety of structurally interesting oxygenated cage compounds involving atom-economic processes such as Claisen rearrangement, Diels–Alder reaction, [2+2] photocycloaddition, and ring-closing metathesis (RCM) as key steps is reported. For the first time, oxepane ring system is introduced in cage framework using olefin metathesis as a key step. These cage systems assembled here are difficult to prepare by traditional methods. The synthetic sequence described here opens up new routes to higher order polycycles containing heteroatoms without the involvement of protecting groups. Transannular cyclization observed during Grignard addition and the RCM protocol used here may be applicable to generate unknown oxygenated cage systems.

Sign in / Sign up

Export Citation Format

Share Document