The kinetics of the addition of alkyl radicals to carbonyl groups. II. The addition of methyl radicals to trifluoroacetone in the gas phase. The formation reaction of the trifluoro-t-butoxy radical

1984 ◽  
Vol 16 (11) ◽  
pp. 1327-1335 ◽  
Author(s):  
J. Alistair Kerr ◽  
J. Paul Wright
Keyword(s):  
Gas Phase ◽  
Methyl Radicals ◽  
Carbonyl Groups ◽  
Formation Reaction ◽  
Alkyl Radicals ◽  
Butoxy Radical ◽  
Kinetics Of

ChemInform Abstract: FLASH PHOTOLYSIS OF ACETONE IN GAS PHASE, KINETICS OF ETHANE FORMATION FROM METHYL RADICALS

1975 ◽  
Vol 6 (13) ◽  
Author(s):  
MARJA-LIISA POHJONEN ◽  
LEILA LEINONEN ◽  
HELGE LEMMETYINEN ◽  
JOUKO KOSKIKALLIO
Keyword(s):  
Gas Phase ◽  
Flash Photolysis ◽  
Methyl Radicals ◽  
Gas Phase Kinetics ◽  
Ethane Formation ◽  
Kinetics Of

The kinetics of the interaction of atomic hydrogen with olefines. V. Results obtained for a further series of compounds

1950 ◽  
Vol 202 (1069) ◽  
pp. 181-202 ◽  
Keyword(s):  
Double Bond ◽  
Hydrogen Atom ◽  
Atomic Hydrogen ◽  
Methyl Radicals ◽  
Hydrogen Atoms ◽  
Alkyl Radicals ◽  
Kinetics Of ◽  
Interesting Generalization

In this paper the efficiency of interaction of a hydrogen atom with a series of olefines has been determined, the olefines being members of the series obtained by progressively replacing the hydrogen atoms of ethylene by methyl radicals. The interesting generalization which emerges from this is that the efficiency of interaction does not vary very much with the nature of the alkyl substituents in the molecule, and calculations involving the heats of addition of a hydrogen atom to a double bond confirm this generalization. The data presented here are discussed critically in relation to information available on the reaction of CCl 3 radicals with olefines and of alkyl radicals with olefines, complete general agreement being demonstrated.

Sign in / Sign up

Export Citation Format

Share Document