Chiral Bidentate NHC Ligands Based on the 1,1′-Binaphthyl Scaffold: Synthesis and Application in Transition-Metal-Catalyzed Asymmetric Reactions

2016 ◽  
Vol 16 (6) ◽  
pp. 2740-2753 ◽  
Author(s):  
Qin Xu ◽  
Peng Gu ◽  
Hanchun Jiang ◽  
Yin Wei ◽  
Min Shi
Keyword(s):  
Transition Metal ◽  
Asymmetric Reactions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

scholarly journals P(O)R2-directed Pd-catalyzed C–H functionalization of biaryl derivatives to synthesize chiral phosphorous ligands

2014 ◽  
Vol 10 ◽  
pp. 2071-2076 ◽  
Author(s):  
Rong-Bin Hu ◽  
Hong-Li Wang ◽  
Hong-Yu Zhang ◽  
Heng Zhang ◽  
Yan-Na Ma ◽  
...  
Keyword(s):  
Transition Metal ◽  
Asymmetric Reactions ◽  
Phosphorus Ligands ◽  
New Synthesis ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Synthesis Approach

Chiral phosphorus ligands have been widely used in transition metal-catalyzed asymmetric reactions. Herein, we report a new synthesis approach of chiral biaryls containing a phosphorus moiety using P(O)R2-directed Pd-catalyzed C–H activation; the functionalized products are produced with good enantioselectivity.

Sign in / Sign up

Export Citation Format

Share Document