Development of Transition Metal-Catalyzed Asymmetric Reactions Using Chiral Diaminophosphine Oxide Preligands and Their Applications

2011 ◽  
Vol 69 (7) ◽  
pp. 763-774 ◽  
Author(s):  
Tetsuhiro Nemoto ◽  
Yasumasa Hamada
Keyword(s):  
Transition Metal ◽  
Asymmetric Reactions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

scholarly journals P(O)R2-directed Pd-catalyzed C–H functionalization of biaryl derivatives to synthesize chiral phosphorous ligands

2014 ◽  
Vol 10 ◽  
pp. 2071-2076 ◽  
Author(s):  
Rong-Bin Hu ◽  
Hong-Li Wang ◽  
Hong-Yu Zhang ◽  
Heng Zhang ◽  
Yan-Na Ma ◽  
...  
Keyword(s):  
Transition Metal ◽  
Asymmetric Reactions ◽  
Phosphorus Ligands ◽  
New Synthesis ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Synthesis Approach

Chiral phosphorus ligands have been widely used in transition metal-catalyzed asymmetric reactions. Herein, we report a new synthesis approach of chiral biaryls containing a phosphorus moiety using P(O)R2-directed Pd-catalyzed C–H activation; the functionalized products are produced with good enantioselectivity.

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