Kinetics of ruthenium(III)-catalysed oxidation of aromatic aldehydes by alkaline ferricyanide

1979 ◽  
Vol 88 (3) ◽  
pp. 163-170
Author(s):  
P. S. Radhakrishnamurti ◽  
B. R. K. Swamy
Keyword(s):  
Aromatic Aldehydes ◽  
Catalysed Oxidation ◽  
Alkaline Ferricyanide ◽  
Kinetics Of

Kinetics and Mechanism of Os(VIII) Catalysed Oxidation of Mandelate Ion by Alkaline Ferricyanide

1972 ◽  
Vol 27 (8) ◽  
pp. 908-910 ◽  
Author(s):  
G. C. Soni ◽  
G. D. Menghani
Keyword(s):  
Mandelic Acid ◽  
Kinetics And Mechanism ◽  
Acid Anion ◽  
Catalysed Oxidation ◽  
Hydroxyl Ion ◽  
Anion Complex ◽  
Mechanism Of Oxidation ◽  
Alkaline Ferricyanide ◽  
Kinetics Of

The kinetics of the reaction between alkaline ferricyanide and mandelic acid catalysed by [Os (VIII) ] has beeen studied. The rate of ferricyanide disappearance was found to be proportional to the concentration of mandelate ion and Os (VIII), but independent of the concentration of ferricyanide. Within a limited concentration range of hydroxyl ion [ [OH-1] < 0.25 M] the rate varies directly as the [OH⁻]. Effects of SO4-2, ΝO3-1NO3-1 and temperature on the rate were studied. ΔΕ, PZ, AS* etc. were evaluated. Mechanism of oxidation of mandelic acid based on the formation of Os (VIII) acid anion complex is suggested.

Kinetics of the Reaction of Aromatic Aldehydes with Ammonia

1964 ◽  
Vol 29 (7) ◽  
pp. 1985-1988 ◽  
Author(s):  
Yoshiro Ogata ◽  
Atsushi Kawasaki ◽  
Nobuya Okumura
Keyword(s):  
Aromatic Aldehydes ◽  
Kinetics Of

scholarly journals Kinetics of Eucalypt Lignosulfonate Oxidation to Aromatic Aldehydes by Oxygen in Alkaline Medium

2011 ◽  
Vol 50 (1) ◽  
pp. 291-298 ◽  
Author(s):  
Sonia G. Santos ◽  
Ana P. Marques ◽  
Diana L. D. Lima ◽  
Dmitry V. Evtuguin ◽  
Valdemar I. Esteves
Keyword(s):  
Alkaline Medium ◽  
Aromatic Aldehydes ◽  
Kinetics Of
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