Tf2NH-catalyzed, highly regio- and stereo-selective synthesis of trisubstituted alkenes and indane derivatives from benzylic alcohols and alkenes

Chinese Chemical Letters ◽

10.1016/j.cclet.2015.01.028 ◽

2015 ◽

Vol 26 (3) ◽

pp. 320-322 ◽

Author(s):

Hai-Hua Li

Keyword(s):

Selective Synthesis ◽

Benzylic Alcohols ◽

Trisubstituted Alkenes

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ChemInform Abstract: Tf2NH-Catalyzed, Highly Regio- and Stereo-Selective Synthesis of Trisubstituted Alkenes and Indane Derivatives from Benzylic Alcohols and Alkenes.

10.1002/chin.201532096 ◽

2015 ◽

Vol 46 (32) ◽

pp. no-no

Author(s):

Hai-Hua Li

Keyword(s):

Selective Synthesis ◽

Benzylic Alcohols ◽

Trisubstituted Alkenes

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ChemInform Abstract: Arylethyne Bromoboration-Negishi Coupling Route to (E)- or (Z)-Aryl-Substituted Trisubstituted Alkenes of ≥ 98% Isomeric Purity. New Horizon in the Highly Selective Synthesis of Trisubstituted Alkenes.

10.1002/chin.201029063 ◽

2010 ◽

Vol 41 (29) ◽

pp. no-no

Author(s):

Chao Wang ◽

Zhaoqing Xu ◽

Tomas Tobrman ◽

Ei-ichi Negishi

Keyword(s):

Selective Synthesis ◽

Negishi Coupling ◽

Isomeric Purity ◽

Trisubstituted Alkenes

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ChemInform Abstract: Controllable Stereoselective Synthesis of Trisubstituted Alkenes by a Catalytic Three-Component Reaction of Terminal Alkynes, Benzylic Alcohols, and Simple Arenes.

10.1002/chin.201001100 ◽

2010 ◽

Vol 41 (1) ◽

pp. no-no

Author(s):

Hai-Hua Li ◽

Yin-Huan Jin ◽

Jie-Qi Wang ◽

Shi-Kai Tian

Keyword(s):

Stereoselective Synthesis ◽

Terminal Alkynes ◽

Benzylic Alcohols ◽

Three Component Reaction ◽

Trisubstituted Alkenes

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Widely Applicable Pd-Catalyzed trans-Selective Monoalkylation of Unactivated 1,1-Dichloro-1-alkenes and Pd-Catalyzed Second Substitution for the Selective Synthesis of (E)- or (Z)-Trisubstituted Alkenes.

10.1002/chin.200619023 ◽

2006 ◽

Vol 37 (19) ◽

Author(s):

Ze Tan ◽

Ei-ichi Negishi

Keyword(s):

Selective Synthesis ◽

Trisubstituted Alkenes

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Controllable stereoselective synthesis of trisubstituted alkenes by a catalytic three-component reaction of terminal alkynes, benzylic alcohols, and simple arenes

Organic & Biomolecular Chemistry ◽

10.1039/b911954j ◽

2009 ◽

Vol 7 (16) ◽

pp. 3219 ◽

Author(s):

Hai-Hua Li ◽

Yin-Huan Jin ◽

Jie-Qi Wang ◽

Shi-Kai Tian

Keyword(s):

Stereoselective Synthesis ◽

Terminal Alkynes ◽

Benzylic Alcohols ◽

Three Component Reaction ◽

Trisubstituted Alkenes

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A new, highly selective synthesis of aromatic aldehydes by aerobic free-radical oxidation of benzylic alcohols, catalysed by n-hydroxyphthalimide under mild conditions. Polar and enthalpic effects

Chemical Communications ◽

10.1039/b110451a ◽

2002 ◽

pp. 688-689 ◽

Author(s):

Francesco Minisci ◽

Carlo Punta ◽

Francesco Recupero ◽

Francesca Fontana ◽

Gian Franco Pedulli

Keyword(s):

Free Radical ◽

Free Radical Oxidation ◽

Aromatic Aldehydes ◽

Selective Synthesis ◽

Radical Oxidation ◽

Benzylic Alcohols ◽

Mild Conditions

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Widely Applicable Pd-Catalyzedtrans-Selective Monoalkylation of Unactivated 1,1-Dichloro-1-alkenes and Pd-Catalyzed Second Substitution for the Selective Synthesis ofE orZ Trisubstituted Alkenes

Angewandte Chemie International Edition ◽

10.1002/anie.200503519 ◽

2006 ◽

Vol 45 (5) ◽

pp. 762-765 ◽

Author(s):

Ze Tan ◽

Ei-ichi Negishi

Keyword(s):

Selective Synthesis ◽

Trisubstituted Alkenes

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ChemInform Abstract: A New, Highly Selective Synthesis of Aromatic Aldehydes by Aerobic Free-Radical Oxidation of Benzylic Alcohols, Catalyzed by N-Hydroxyphthalimide under Mild Conditions. Polar and Enthalpic Effects.

10.1002/chin.200231091 ◽

2010 ◽

Vol 33 (31) ◽

pp. no-no

Author(s):

Francesco Minisci ◽

Carlo Punta ◽

Francesco Recupero ◽

Francesca Fontana ◽

Gian Franco Pedulli

Keyword(s):

Free Radical ◽

Free Radical Oxidation ◽

Aromatic Aldehydes ◽

Selective Synthesis ◽

Radical Oxidation ◽

Benzylic Alcohols ◽

Mild Conditions

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Widely Applicable Pd-Catalyzedtrans-Selective Monoalkylation of Unactivated 1,1-Dichloro-1-alkenes and Pd-Catalyzed Second Substitution for the Selective Synthesis ofE orZ Trisubstituted Alkenes

Angewandte Chemie ◽

10.1002/ange.200503519 ◽

2006 ◽

Vol 118 (5) ◽

pp. 776-779 ◽

Author(s):

Ze Tan ◽

Ei-ichi Negishi

Keyword(s):

Selective Synthesis ◽

Trisubstituted Alkenes

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Arylethyne Bromoboration-Negishi Coupling Route toE- orZ-Aryl-Substituted Trisubstituted Alkenes of ≥98% Isomeric Purity. New Horizon in the Highly Selective Synthesis of Trisubstituted Alkenes

Advanced Synthesis & Catalysis ◽

10.1002/adsc.200900766 ◽

2010 ◽

Vol 352 (4) ◽

pp. 627-631 ◽

Author(s):

Chao Wang ◽

Zhaoqing Xu ◽

Tomas Tobrman ◽

Ei-ichi Negishi

Keyword(s):

Selective Synthesis ◽

Negishi Coupling ◽

Isomeric Purity ◽

Trisubstituted Alkenes

Download Full-text